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Chin. Phys. B, 2020, Vol. 29(12): 124209    DOI: 10.1088/1674-1056/abb3ef
ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS Prev   Next  

Effect of the distance between focusing lens and target surface on quantitative analysis of Mn element in aluminum alloys by using filament-induced breakdown spectroscopy

Xue-Tong Lu(陆雪童)1, Shang-Yong Zhao(赵上勇)1, Xun Gao(高勋)1,†, Kai-Min Guo(郭凯敏)2,‡, and Jing-Quan Lin(林景全)1
1 School of Science, Changchun University of Science and Technology, Changchun 130012, China; 2 School of Physical Science and Technology, Baotou Teachers' College, Baotou 014030, China
Abstract  Ultrafast laser filament-induced breakdown spectroscopy (FIBS) is a potential technique for quantitative analysis of trace elements. In this work, we investigate the effect of the distance between focusing lens and target surface on the FIBS quantitative analysis of Mn element in aluminum alloys, and several major parameters are calculated such as the linear correlation coefficient (R2), limits of detection (LOD), relative standard deviation (RSD), and root-mean-square error of cross-validations (RMSECV). The results show that the quantitative analysis parameter values before and after filament position are different. The optimal value can be obtained at the filament region, the average values of total 23 positions of R2, LOD, RSD, and RMAECV were 99.45%, 1.41 mg/kg, 7.12%, and 0.56%, respectively. Besides, the spatial distributions of quantitative analysis parameter values in filament region are noticeable, and this is essentially due to intensity clamping effect in a filament.
Keywords:  filament-induced breakdown spectroscopy      limits of detection      relative standard deviation      root-mean-square error of cross-validations  
Received:  17 June 2020      Revised:  13 July 2020      Accepted manuscript online:  01 September 2020
PACS:  42.62.Fi (Laser spectroscopy)  
  52.38.Hb (Self-focussing, channeling, and filamentation in plasmas)  
Fund: Project supported by the National Natural Science Foundation of China (Grant No. 61575030), the Natural Science Foundation of Jilin Province, China (Grant Nos. 20180101283JC and 20200301042RQ), and the Fund from the Department of Education of Jilin Province, China (Grant No. JJKH20190539KJ).
Corresponding Authors:  Corresponding author. E-mail: lasercust@163.com Corresponding author. E-mail: guokm@163.com   

Cite this article: 

Xue-Tong Lu(陆雪童), Shang-Yong Zhao(赵上勇), Xun Gao(高勋), Kai-Min Guo(郭凯敏), and Jing-Quan Lin(林景全) Effect of the distance between focusing lens and target surface on quantitative analysis of Mn element in aluminum alloys by using filament-induced breakdown spectroscopy 2020 Chin. Phys. B 29 124209

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