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SPECIAL TOPIC — Recent progress on kagome metals and superconductors
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Superconductivity in kagome metal ThRu
3
Si
2
Yi Liu(刘艺), Jing Li(厉静), Wu-Zhang Yang(杨武璋), Jia-Yi Lu(卢佳依), Bo-Ya Cao(曹博雅), Hua-Xun Li(李华旬), Wan-Li Chai(柴万力), Si-Qi Wu(武思祺), Bai-Zhuo Li(李佰卓), Yun-Lei Sun(孙云蕾), Wen-He Jiao(焦文鹤), Cao Wang(王操), Xiao-Feng Xu(许晓峰), Zhi Ren(任之), and Guang-Han Cao(曹光旱)
Chin. Phys. B, 2024, 33 (
5
): 057401. DOI:
10.1088/1674-1056/ad1c5e
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247
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We report the physical properties of ThRu$_3$Si$_2$ featured with distorted Ru kagome lattice. The combined experiments of resistivity, magnetization and specific heat reveal bulk superconductivity with $T_{\rm{c}}= 3.8$ K. The specific heat jump and calculated electron-phonon coupling indicate a moderate coupled BCS superconductor. In comparison with LaRu$_3$Si$_2$, the calculated electronic structure in ThRu$_3$Si$_2$ shows an electron-doping effect with electron filling lifted from 100 meV below flat bands to 300 meV above it. This explains the lower superconducting transition temperature and weaker electron correlations observed in ThRu$_3$Si$_2$. Our work suggests the $T_{\rm{c}}$ and electronic correlations in the kagome superconductor could have an intimate connection with the flat bands.
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Enhanced anomalous Hall effect in kagome magnet YbMn
6
Sn
6
with intermediate-valence ytterbium
Longfei Li(李龙飞), Shengwei Chi(迟晟玮), Wenlong Ma(马文龙), Kaizhen Guo(郭凯臻), Gang Xu(徐刚), and Shuang Jia(贾爽)
Chin. Phys. B, 2024, 33 (
5
): 057501. DOI:
10.1088/1674-1056/ad322d
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205
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We report on the magnetization and anomalous Hall effect (AHE) in the high-quality single crystals of the kagome magnet YbMn$_{6}$Sn$_{6}$, where the spins of the Mn atoms in the kagome lattice order ferromagnetically and the intermediate-valence Yb atoms are nonmagnetic. The intrinsic mechanism plays a crucial role in the AHE, leading to an enhanced anomalous Hall conductivity (AHC) compared with the other rare-earth $R$Mn$_{6}$Sn$_{6}$ compounds. Our band structure calculation reveals a strong hybridization between the 4f electrons of Yb and conduction electrons.
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Two-fold symmetry of the in-plane resistance in kagome superconductor Cs(V
1-
x
Ta
x
)
3
Sb
5
with enhanced superconductivity
Zhen Zhao(赵振), Ruwen Wang(王汝文), Yuhang Zhang(张宇航), Ke Zhu(祝轲), Weiqi Yu(余维琪), Yechao Han(韩烨超), Jiali Liu(刘家利), Guojing Hu(胡国静), Hui Guo(郭辉), Xiao Lin(林晓), Xiaoli Dong(董晓莉), Hui Chen(陈辉), Haitao Yang(杨海涛), and Hong-Jun Gao(高鸿钧)
Chin. Phys. B, 2024, 33 (
7
): 077406. DOI:
10.1088/1674-1056/ad4ffa
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197
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The kagome superconductor CsV$_{3}$Sb$_{5}$ has attracted widespread attention due to its rich correlated electron states including superconductivity, charge density wave (CDW), nematicity, and pair density wave. Notably, the modulation of the intertwined electronic orders by the chemical doping is significant to illuminate the cooperation/competition between multiple phases in kagome superconductors. In this study, we have synthesized a series of tantalum-substituted Cs(V$_{1-x}$Ta$_{x}$)$_{3}$Sb$_{5}$ by a modified self-flux method. Electrical transport measurements reveal that CDW is suppressed gradually and becomes undetectable as the doping content of $ x$ is over 0.07. Concurrently, the superconductivity is enhanced monotonically from $T_{\rm c} \sim 2.8 $ K at $x =0$ to 5.2 K at $x = 0.12$. Intriguingly, in the absence of CDW, Cs(V$_{1-x}$Ta$_{x}$)$_{3}$Sb$_{5}$ ($x = 0.12$) crystals exhibit a pronounced two-fold symmetry of the in-plane angular-dependent magnetoresistance (AMR) in the superconducting state, indicating the anisotropic superconducting properties in the Cs(V$_{1-x}$Ta$_{x}$)$_{3}$Sb$_{5}$. Our findings demonstrate that Cs(V$_{1-x}$Ta$_{x}$)$_{3}$Sb$_{5}$ with the non-trivial band topology is an excellent platform to explore the superconductivity mechanism and intertwined electronic orders in quantum materials.
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Pairing correlation of the kagome-lattice Hubbard model with the nearest-neighbor interaction
Chen Yang(杨晨), Chao Chen(陈超), Runyu Ma(马润宇), Ying Liang(梁颖), and Tianxing Ma(马天星)
Chin. Phys. B, 2024, 33 (
10
): 107404. DOI:
10.1088/1674-1056/ad7578
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181
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A recently discovered family of kagome lattice materials, ${A}\mathrm{V}_{3}\mathrm{Sb}_{5}$ (${A}=\mathrm{K,Rb,Cs}$), has attracted great interest, especially in the debate over their dominant superconducting pairing symmetry. To explore this issue, we study the superconducting pairing behavior within the kagome-lattice Hubbard model through the constrained path Monte Carlo method. It is found that doping around the Dirac point generates a dominant next-nearest-neighbor-d pairing symmetry driven by on-site Coulomb interaction $U$. However, when considering the nearest-neighbor interaction $V$, it may induce nearest-neighbor-p pairing to become the preferred pairing symmetry. Our results provide useful information to identify the dominant superconducting pairing symmetry in the ${A}\mathrm{V}_{3}\mathrm{Sb}_{5}$ family.
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Magnetoresistance hysteresis in the superconducting state of kagome CsV
3
Sb
5
Tian Le(乐天), Jinjin Liu(刘锦锦), Zhiwei Wang(王秩伟), and Xiao Lin(林效)
Chin. Phys. B, 2024, 33 (
10
): 107402. DOI:
10.1088/1674-1056/ad6423
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198
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The hysteresis of magnetoresistance observed in superconductors is of great interest due to its potential connection with unconventional superconductivity. In this study, we perform electrical transport measurements on kagome superconductor CsV$_3$Sb$_5$ nanoflakes and uncover unusual hysteretic behavior of magnetoresistance in the superconducting state. This hysteresis can be induced by applying either a large DC or AC current at temperatures ($T$) well below the superconducting transition temperature ($T_{\rm c}$). As $T$ approaches $T_{\rm c}$, similar weak hysteresis is also detected by applying a small current. Various scenarios are discussed, with particular focus on the effects of vortex pinning and the presence of time-reversal-symmtery-breaking superconducting domains. Our findings support the latter, hinting at chiral superconductivity in kagome superconductors.
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Surface-sensitive electronic structure of kagome superconductor CsV
3
Sb
5
Zhisheng Zhao(赵志生), Jianghao Yao(姚江浩), Rui Xu(徐瑞), Yuzhe Wang(王禹喆), Sen Liao(廖森), Zhengtai Liu(刘正太), Dawei Shen (沈大伟), Shengtao Cui(崔胜涛), Zhe Sun(孙喆), Yilin Wang(王义林), Donglai Feng(封东来), and Juan Jiang(姜娟)
Chin. Phys. B, 2024, 33 (
10
): 107403. DOI:
10.1088/1674-1056/ad7016
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181
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We systematically study the electronic structure of a kagome superconductor ${\rm Cs}{\rm V}_{{\rm 3}}{{\rm Sb}}_{{\rm 5}}$ at different temperatures covering both its charge density wave state and normal state with angle-resolved photoemission spectroscopy. We observe that the V-shaped band around $\bar{\varGamma }$ shows three different behaviors, referred to as $\alpha /\alpha '$, $\beta $ and $\gamma $, mainly at different temperatures. Detailed investigations confirm that these bands are all from the same bulk Sb-p$_{z}$ origin, but they are quite sensitive to the sample surface conditions mainly modulated by temperature. Thus, the intriguing temperature dependent electronic behavior of the band near $\bar{\varGamma }$ is affected by the sample surface condition, rather than intrinsic electronic behavior originating from the phase transition. Our result systematically reveals the confusing electronic structure behavior of the energy bands around $\bar{\varGamma }$, facilitating further exploration of the novel properties in this material.
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Anomalous Hall effect and electronic correlation in a spin-reoriented kagome antiferromagnet LuFe
6
Sn
6
Meng Lyu(吕孟), Yang Liu(刘洋), Shen Zhang(张伸), Junyan Liu(刘俊艳), Jinying Yang(杨金颖), Yibo Wang(王一博), Yiting Feng(冯乙婷), Xuebin Dong(董学斌), Binbin Wang(王彬彬), Hongxiang Wei(魏红祥), and Enke Liu(刘恩克)
Chin. Phys. B, 2024, 33 (
10
): 107507. DOI:
10.1088/1674-1056/ad6f93
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190
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The kagome lattice system has been identified as a fertile ground for the emergence of a number of new quantum states, including superconductivity, quantum spin liquids, and topological electronic states. This has attracted significant interest within the field of condensed matter physics. Here, we present the observation of an anomalous Hall effect in an iron-based kagome antiferromagnet LuFe$_{6}$Sn$_{6}$, which implies a non-zero Berry curvature in this compound. By means of extensive magnetic measurements, a high Neel temperature, $T_{\rm N} = 552 $ K, and a spin reorientation behavior were identified and a simple temperature-field phase diagram was constructed. Furthermore, this compound was found to exhibit a large Sommerfeld coefficient of $\gamma = 87 $ mJ$\cdot $mol$^{-1}\cdot$K$^{-2}$, suggesting the presence of a strong electronic correlation effect. Our research indicates that LuFe$_{6}$Sn$_{6}$ is an intriguing compound that may exhibit magnetism, strong correlation, and topological states.
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Emergent 3×3 charge order on the Cs reconstruction of kagome superconductor CsV
3
Sb
5
Xianghe Han(韩相和), Zhongyi Cao(曹钟一), Zihao Huang(黄子豪), Zhen Zhao(赵振), Haitao Yang(杨海涛), Hui Chen(陈辉), and Hong-Jun Gao(高鸿钧)
Chin. Phys. B, 2025, 34 (
1
): 016801. DOI:
10.1088/1674-1056/ad8fa1
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282
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The alkali adatoms with controlled coverage on the surface have been demonstrated to effectively tune the surface band of quantum materials through
in situ
electron doping. However, the interplay of orderly arranged alkali adatoms with the surface states of quantum materials remains unexplored. Here, by using low-temperature scanning tunneling microscopy/spectroscopy (STM/S), we observed the emergent 3$\times$3 super modulation of electronic states on the $\sqrt 3\times\sqrt 3R30^\circ$ (R3) Cs ordered surface of kagome superconductor CsV$_{3}$Sb$_{5}$. The nondispersive 3$\times$3 superlattice at R3 ordered surface shows contrast inversion in positive and negative differential conductance maps, indicating a charge order origin. The 3$\times$3 charge order is suppressed with increasing temperature and undetectable at a critical temperature of $\sim 62$ K. Furthermore, in the Ta substituted sample CsV$_{2.6}$Ta$_{0.4}$Sb$_{5}$, where long-range 2$\times$2$\times$2 charge density wave is significantly suppressed, the 3$\times$3 charge order on the R3 ordered surface becomes blurred and much weaker than that in the undoped sample. It indicates that the 3$\times$3 charge order on the R3 ordered surface is directly correlated to the bulk charge density waves in CsV$_{3}$Sb$_{5}$. Our work provides a new platform for understanding and manipulating the cascade of charge orders in kagome superconductors.
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Electronic band structures of topological kagome materials
Man Li(李满), Huan Ma(马欢), Rui Lou(娄睿), and Shancai Wang(王善才)
Chin. Phys. B, 2025, 34 (
1
): 017101. DOI:
10.1088/1674-1056/ad925d
Abstract
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322
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The kagome lattice has garnered significant attention due to its ability to host quantum spin Fermi liquid states. Recently, the combination of unique lattice geometry, electron-electron correlations, and adjustable magnetism in solid kagome materials has led to the discovery of numerous fascinating quantum properties. These include unconventional superconductivity, charge and spin density waves (CDW/SDW), pair density waves (PDW), and Chern insulator phases. These emergent states are closely associated with the distinctive characteristics of the kagome lattice's electronic structure, such as van Hove singularities, Dirac fermions, and flat bands, which can exhibit exotic quasi-particle excitations under different symmetries and magnetic conditions. Recently, various quantum kagome materials have been developed, typically consisting of kagome layers stacked along the $z$-axis with atoms either filling the geometric centers of the kagome lattice or embedded between the layers. In this topical review, we begin by introducing the fundamental properties of several kagome materials. To gain an in-depth understanding of the relationship between topology and correlation, we then discuss the complex phenomena observed in these systems. These include the simplest kagome metal $T_3X$, kagome intercalation metal $TX$, and the ternary compounds $AT_6X_6$ and $RT_3X_5$ ($A = {\rm Li}$, Mg, Ca, or rare earth; $T = {\rm V}$, Cr, Mn, Fe, Co, Ni; $X = {\rm Sn}$, Ge; $R = {\rm K}$, Rb, Cs). Finally, we provide a perspective on future experimental work in this field.
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High-throughput discovery of kagome materials in transition metal oxide monolayers
Renhong Wang(王人宏), Cong Wang(王聪), Ruixuan Li(李睿宣), Deping Guo(郭的坪), Jiaqi Dai(戴佳琦), Canbo Zong(宗灿波), Weihan Zhang(张伟涵), and Wei Ji(季威)
Chin. Phys. B, 2025, 34 (
4
): 046801. DOI:
10.1088/1674-1056/adb265
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167
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Kagome materials are known for hosting exotic quantum states, including quantum spin liquids, charge density waves, and unconventional superconductivity. The search for kagome monolayers is driven by their ability to exhibit neat and well-defined kagome bands near the Fermi level, which are more easily realized in the absence of interlayer interactions. However, this absence also destabilizes the monolayer forms of many bulk kagome materials, posing significant challenges to their discovery. In this work, we propose a strategy to address this challenge by utilizing oxygen vacancies in transition metal oxides within a "1$+$3" design framework. Through high-throughput computational screening of 349 candidate materials, we identified 12 thermodynamically stable kagome monolayers with diverse electronic and magnetic properties. These materials were classified into three categories based on their lattice geometry, symmetry, band gaps, and magnetic configurations. Detailed analysis of three representative monolayers revealed kagome band features near their Fermi levels, with orbital contributions varying between oxygen 2p and transition metal d states. This study demonstrates the feasibility of the "1$+$3" strategy, offering a promising approach to uncovering low-dimensional kagome materials and advancing the exploration of their quantum phenomena.
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Scanning tunneling microscopy study on symmetry breaking of charge density wave in FeGe
Jiakang Zhang(张嘉康), Ziyuan Chen(陈子元), Xueliang Wu(吴学良), Mingzhe Li(李明哲), Yuanji Li(李元骥), Ruotong Yin(尹若彤), Jiashuo Gong(巩佳硕), Shiyuan Wang(王适源), Aifeng Wang(王爱峰), Dong-Lai Feng(封东来), and Ya-Jun Yan(闫亚军)
Chin. Phys. B, 2025, 34 (
4
): 047303. DOI:
10.1088/1674-1056/adb389
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The complex symmetry breaking states in $A$V$_{3}$Sb$_{5}$ family have attracted extreme research attention, but controversy still exists, especially in the question of time reversal symmetry breaking of the charge density wave (CDW). Most recently, a chiral CDW has been suggested in kagome magnet FeGe, but the related study is very rare. Here, we use a scanning tunneling microscope to study the symmetry breaking behavior of both the short- and long-range CDWs in FeGe. Different from previous studies, our study reveals an isotropic long-range CDW without obvious symmetry breaking, while local rotational symmetry breaking appears in the short-range CDW, which may be related to the existence of strong structural disorders. Moreover, the charge distribution of the short-range CDW is inert to the applied external magnetic fields and the detailed spin arrangements of FeGe, inconsistent with the expectation of a chiral CDW associated with chiral flux. Our results rule out the existence of spontaneous chiral and rotational symmetry breaking in the CDW state of FeGe, putting strong constraints on the further understanding of CDW mechanism.
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Angle-resolved photoemission spectroscopy study on transition-metal kagome materials
Jiangang Yang(杨鉴刚), Jianwei Huang(黄建伟), Lin Zhao(赵林), and X. J. Zhou(周兴江)
Chin. Phys. B, 2025, 34 (
4
): 047101. DOI:
10.1088/1674-1056/adb689
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Angle-resolved photoemission spectroscopy (ARPES) has become a cornerstone technique for elucidating the electronic structures of emergent quantum materials. Among these, kagome materials - distinguished by their two-dimensional lattice of corner-sharing triangles - provide a fertile ground for investigating exotic quantum phenomena, driven by geometric frustration, electronic correlation, and topology. In this review, we present an overview of recent ARPES studies on transition-metal kagome materials. We first outline the fundamental features of their electronic structures, including van Hove singularities, Dirac points, and flat bands, and discuss the novel quantum states that arise from many-body interactions within the kagome lattice. We then highlight key ARPES investigations into these unique electronic structures, detailing their manifestation and associated quantum states in representative kagome materials. Finally, we offer a forward-looking perspective on the potential of ARPES to uncover new quantum phenomena and its broader implications for the study of underlying physics in kagome materials.