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Chin. Phys. B, 2015, Vol. 24(8): 083301    DOI: 10.1088/1674-1056/24/8/083301
ATOMIC AND MOLECULAR PHYSICS Prev   Next  

Study on the A2Π3/2u, B2Δ3/2u, and X2Π3/2g states of Cl2+ including its isotopologues

Wu Ling (吴玲)a, You Su-Ping (尤素萍)a, Shao Xu-Ping (邵旭萍)b, Chen Gang-Jin (陈钢进)a, Ding Ning (丁宁)a, Wang You-Mei (汪友梅)a, Yang Xiao-Hua (杨晓华)b
a School of Science, Hangzhou Dianzi University, Hangzhou 310018, China;
b School of Science, Nantong University, Nantong 226019, China
Abstract  Adopting the experimentally available vibrational constants in a recent analysis of the strong perturbation between the A2Π3/2u and B2Δ3/2u states of Cl2+ in the A–X band system [Gharaibeh et al. 2012 J. Chem. Phys. 137 194317], an unambiguous vibrational assignment of the bands reported previously is carried out. The equilibrium rotational constants Be and αe of the X2Π3/2g and A2Π3/2u states for 35Cl2+ and 35Cl37Cl+ and those of the B2Δ3/2u state for 35Cl2+ are obtained by fitting the experimental values of Bv. In addition, the values of Be and αe of these three states for the minor isotopologues 35Cl37Cl+ and 37Cl2+ are predicted by employing the isotopic effect. The values of equilibrium internuclear distance Re of the three states for the three isotopologues are calculated as well.
Keywords:  Cl2+      isotopic effect      molecular constants  
Received:  01 February 2015      Revised:  30 March 2015      Accepted manuscript online: 
PACS:  33.15.Mt (Rotation, vibration, and vibration-rotation constants)  
  33.20.Vq (Vibration-rotation analysis)  
Fund: Project supported by the Natural Science Foundation of Zhejiang Province, China (Grant Nos. Y6110524 and Y1111085), the Scientific Research Foundation of the Department of Education of Zhejiang Province, China (Grant No. Y201430970), the National Nature Science Foundation of China (Grant No. 11247007), and the QingLan Project of Jiangsu Province, China.
Corresponding Authors:  Yang Xiao-Hua     E-mail:  xhyang@ntu.edu.cn

Cite this article: 

Wu Ling (吴玲), You Su-Ping (尤素萍), Shao Xu-Ping (邵旭萍), Chen Gang-Jin (陈钢进), Ding Ning (丁宁), Wang You-Mei (汪友梅), Yang Xiao-Hua (杨晓华) Study on the A2Π3/2u, B2Δ3/2u, and X2Π3/2g states of Cl2+ including its isotopologues 2015 Chin. Phys. B 24 083301

[1] Uchida Y and Ota Y 1928 Jpn. J. Phys. 5 53
[2] Elliot A and Cameron W H B 1937 Proc. Roy. Soc. A 158 681
[3] Elliot A and Cameron W H B 1938 Proc. Roy. Soc. A 164 531
[4] Haranath P B V and Rao P T 1958 India J. Phys. 32 401
[5] Rao V V and Rao P T 1958 Can. J. Phys. 36 1557
[6] Huberman F P 1966 J. Mol. Spectrosc. 20 29
[7] Tuckett R P and Peyerimhoff S D 1984 Chem. Phys. 83 203
[8] Choi J C and Hardwick J L 1989 J. Mol. Spectrosc. 137 138
[9] Choi J C and Hardwick J L 1991 J. Mol. Spectrosc. 145 371
[10] Gharaibeh M A, Clouthier D J, Kalemos A, Lefebvre-Brion H and Field R W 2012 J. Chem. Phys. 137 194317
[11] Bramble S K and Hamilton P A 1990 J. Chem. Soc., Faraday Trans. 86 2009
[12] Li J, Hao Y, Yang J, Zhou C and Mo Y 2007 J. Chem. Phys. 127 104307
[13] Mollet S and Merkt F 2013 J. Chem. Phys. 139 034302
[14] Lefebvre-Brion H and Field R W 2004 The Spectra and Dynamics of Diatomic Molecules (Amsterdam: Elsevier)
[15] Le Roy R J 2004 RKR1 2.0: A computer program implementing the first-order RKR method for determining diatomic molecule potential energy functions (University of Waterloo Chemical Physics Research Report No. CP-657R)
[16] Le Roy R J 2007 LEVEL 8.0: A computer program for solving the radial Schrödinger equation for bound and quasibound levels (University of Waterloo Chemical Physics Research Report No. CP-663)
[17] Herzberg G 1950 Molecular Spectra and Molecular Structure I: Spectra of Diatomic Molecules (New York: van Nostrand)
[18] Shao X, Wang Q, Wu Y, Wu L and Yang X 2014 Chin. Phys. Lett. 31 113301
[19] Wu L, Yang X and Chen Y 2009 Chin. Phys. B 18 2724
[20] Wu L, Yang X, Guo Y, Zheng L, Liu Y and Chen Y 2005 J. Mol. Spectrosc. 230 72
[21] Wu L, Yang X and Chen Y 2008 J. Quantum Spectros. Radiat. Transfer 109 1586
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