Holographic property of photopolymers with different amine photoinitiators

doi:10.1088/1674-1056/19/2/024212

Abstract Holographic parameters and photobleaching kinetics of the photopolymers with five different amine photoinitiators are studied. The maximum values of diffraction efficiency, photobleaching coefficient and quantum yield follow the sequence: Triethanolamine (TEA)> Diethanolamine (DEA)> Ethanolamine (EA)> Triethylamine (TETN)> Diethylamine (DETN). The holographic capabilities of photopolymer performances are determined by the number of functional groups in the amine molecular structure. There is an optimum proportion of the photoinitiator, the photosensitizer and the monomer in the test of holographic parameters with different amine concentrations. The maximum diffraction efficiency is 59.26\%, sensitivity is

1.72 \times 10^{- 3}

cm

^{2}

/mJ, and the maximum refractive modulation index is

4.64 \times 10^{- 4}

.

Keywords: photopolymer amine holographic recording photoinitiator

Received: 28 July 2007
Revised: 22 July 2009
Accepted manuscript online:

PACS:	42.70.Jk	(Polymers and organics)
	42.50.Gy	(Effects of atomic coherence on propagation, absorption, and Amplification of light; electromagnetically induced transparency and Absorption)
	42.40.Lx	(Diffraction efficiency, resolution, and other hologram characteristics)
	42.70.Ln	(Holographic recording materials; optical storage media)
	42.40.Ht	(Hologram recording and readout methods)

Fund: Project supported by the Natural Science Foundation of Henan University, China (Grant No. 06ZDZR002).

Cite this article:

Lu Hai(路海),Li Ruo-Ping(李若平), Sun Cai-Xia(孙彩霞), Xiao Yong(肖勇), Tang Dao-Guang(唐道广), and Huang Ming-Ju(黄明举) Holographic property of photopolymers with different amine photoinitiators 2010 Chin. Phys. B 19 024212

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Holographic property of photopolymers with different amine photoinitiators

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