1 Hangzhou Dianzi University, Hangzhou 310018, China; 2 National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China; 3 Center for Crystal Research and Development, Key Laboratory of Functional Crystals and Laser Technology, Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China; 4 Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China; 5 Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China; 6 School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
Abstract The barocaloric effect is considered as one of the most promising refrigeration with the potential to replace traditional gas compression refrigeration. One of the main obstacles to the application of barocaloric materials lies in the requirement for high driving pressures. In this paper, we report on the barocaloric effect of Pb(VO), which exhibits a ferroelastic transition from a high-temperature trigonal structure to a low-temperature monoclinic structure at 357 K, accompanied by a substantial volume change. The entropy change induced by hydrostatic pressure can reach up 14 JkgK under a relatively low pressure of 80 MPa. This work is expected to expand the selection range of barocaloric materials.
(Cryogenics; refrigerators, low-temperature detectors, and other low-temperature equipment)
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 52301241 and 52271175).
Corresponding Authors:
Dunhui Wang
E-mail: wangdh@hdu.edu.cn
Cite this article:
Pengtao Cheng(程鹏涛), Zuhua Chen(陈祖华), Chengliang Zhang(张成亮), Zhengming Zhang(张正明), Bing Li(李昺), and Dunhui Wang(王敦辉) Barocaloric effect in ferroelastic Pb3(VO4)2 2025 Chin. Phys. B 34 036801
[1] Franco V, Blázquez J, Ipus J, Law J, Moreno-Ramírez L and Conde A 2018 Prog. Mater. Sci. 93 112 [2] Gschneidner K A, Pecharsky V K and Tsokol A O 2005 Rep. Prog. Phys. 68 1479 [3] Kumar A, Thakre A, Jeong D Y and Ryu J 2019 J. Mater. Chem. C 7 6836 [4] Shi J, Han D, Li Z, Yang L, Lu S G, Zhong Z, Chen J, Zhang Q and Qian X 2019 Joule 3 1200 [5] Chen J, Lei L and Fang G 2021 Mater. Today Commun. 28 102706 [6] Imran M and Zhang X 2020 Mater. Design 195 109030 [7] Cirillo L, Greco A and Masselli C 2022 Therm. Sci. Eng. Prog. 33 101380 [8] Mañosa L and Planes A 2017 Adv. Mater. 29 1603607 [9] Mañosa L, González A D, Planes A, Bonnot E, Barrio M, Tamarit J L, Aksoy S and Acet M 2010 Nat. Mater. 9 478 [10] Mañosa L, González A D, Planes A, Barrio M, Tamarit J L, Titov I S, Acet M, Bhattacharyya A and Majumdar S 2011 Nat. Commun. 2 595 [11] Yuce S, Barrio M, Emre B, Stern-Taulats E, Planes A, Tamarit J L, Mudryk Y, Jr. K A G, Pecharsky V K and Mañosa L 2012 Appl. Phys. Lett. 101 071906 [12] Wu R R, Bao L F, Hu F X, Wu H, Huang Q Z, Wang J, Dong X L, Li G N, Sun J R, Shen F R, Zhao T Y, Zheng X Q, Wang L C, Liu Y, Zuo W L, Zhao Y Y, Zhang M, Wang X C, Jin C Q, Rao G H, Han X F and Shen B G 2015 Sci. Rep. 5 18027 [13] Bermúdez-García J M, Sánchez-Andújar M, Castro-García S, López- Beceiro J, Artiaga R and Señarís-Rodríguez M A 2017 Nat. Commun. 8 15715 [14] Bermúdez-García J M, Yáñez-Vilar S, García-Fernández A, Sánchez- Andújar M, Castro-García S, López-Beceiro J, Artiaga R, Dilshad M, Moya X and Señarís-Rodríguez M A 2018 J. Mater. Chem. C 6 9867 [15] Lloveras P, Stern-Taulats E, Barrio M, Tamarit J L, Crossley S, Li W, Pomjakushin V, Planes A, Mañosa L, Mathur N D and Moya X 2015 Nat. Commun. 6 8801 [16] Gorev M V, Mikhaleva E A, Flerov I N and Bogdanov E V 2019 J. Alloys Compd. 806 1047 [17] Aznar A, Lloveras P, Romanini M, Barrio M, Tamarit J L, Cazorla C, Errandonea D, Mathur N D, Planes A, Moya X and Mañosa L 2017 Nat. Commun. 8 1851 [18] Sagotra A K, Chu D and Cazorla C 2018 Nat. Commun. 9 3337 [19] Flerov I N, Kartashev A V, Gorev M V, Bogdanov E V, Mel’nikova S V, Molokeev M S, Pogoreltsev E I and Laptash N M 2016 J. Fluorine Chem. 183 1 [20] Kartashev A V, Gorev M V, Bogdanov E V, Flerov I N and Laptash N M 2016 J. Solid State Chem. 237 269 [21] Gorev M V, Bogdanov E V and Flerov I N 2017 Scr. Mater. 139 53 [22] Boldrin D, Mendive-Tapia E, Zemen J, Staunton J B, Hansen T, Aznar A, Tamarit J L, Barrio M, Lloveras P, Kim J, Moya X and Cohen L F 2018 Phys. Rev. X 8 041035 [23] Matsunami D, Fujita A, Takenaka K and Kano M 2015 Nat. Mater. 14 73 [24] Li B, Kawakita Y, Ohira-Kawamura S, Sugahara T, Wang H, Wang J, Chen Y, Kawaguchi S I, Kawaguchi S and Ohara K 2019 Nature 567 506 [25] Lloveras P, Aznar A, Barrio M, Negrier P, Popescu C, Planes A, Mañosa L, Stern-Taulats E, Avramenko A, Mathur N D, Moya X and Tamarit J L 2019 Nat. Commun. 10 1803 [26] He X, Kang Y, Wei S, Zhang Y, Cao Y, Xu K, Li Z, Jing C and Li Z 2018 J. Alloys Compd. 741 821 [27] Ren Q, Qi J, Yu D, Zhang Z, Song R, Song W, Yuan B, Wang T, Ren W, Zhang Z, Tong X and Li B 2022 Nat. Commun. 13 2293 [28] Zhang Z, Jiang X, Hattori T, Xu X, Li M, Yu C, Zhang Z, Yu D, Mole R, Yano S, Chen J, He L, Wang C W, Wang H, Li B and Zhang Z 2023 Mater. Horiz. 10 977 [29] Mandal S and Ghosh A 1993 Phys. Rev. B 48 9388 [30] Mandal S and Ghosh A 1994 Phys. Rev. B 49 3131 [31] Hirofumi K, Talashi U and Hikaru T 1992 J. Phys. Soc. Jpn. 61 2309 [32] Michio M, Hidetoshi K and Yoshihiro I 1981 J. Phys. Soc. Jpn. 50 1592 [33] Hirofumi K, Talashi U, Hikaru T and Yoshihiro I 1991 J. Phys. Soc. Jpn. 60 1169 [34] Hafner J and Kresse G 1997 Properties of Complex Inorganic Solids [35] Perdew J P, Chevary J, Vosko S, Jackson K A, Pederson M R, Singh D and Fiolhais C 1993 Phys. Rev. B 48 4978 [36] Denisova L T, Izotov A D, Irtyugo L A, Kargin Y F, Denisov V M and Beletskii V V 2016 Dokl. Phys. Chem. 466 4
Altmetric calculates a score based on the online attention an article receives. Each coloured thread in the circle represents a different type of online attention. The number in the centre is the Altmetric score. Social media and mainstream news media are the main sources that calculate the score. Reference managers such as Mendeley are also tracked but do not contribute to the score. Older articles often score higher because they have had more time to get noticed. To account for this, Altmetric has included the context data for other articles of a similar age.
