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SPECIAL TOPIC — Ion beam modification of materials and applications
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| SPECIAL TOPIC—Ion beam modification of materials and applications |
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Corrosion behavior of high-level waste container materials Ti and Ti-Pd alloy under long-term gamma irradiation in Beishan groundwater |
| Qianglin Wei(魏强林)1,2, Yuhong Li(李玉红)1,†, Yanliang Huang(黄彦良)3, Dongyan Yang(杨冬燕)1, Bo Yang(杨波)2, and Yibao Liu(刘义保)2,‡ |
1 School of Nuclear Science and Technology, Lanzhou University, Lanzhou 730000, China;
2 State Key Laboratory of Nuclear Resources and Environment, East China University of Technology, Nanchang 330013, China;
3 Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China |
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Abstract Titanium and titanium-palladium alloys are important potential materials for nuclear waste container, which will endure both intense γ-irradiation and groundwater erosion. Therefore, it is very important to investigate the corrosion behavior of the container materials. In this research, the cumulative dose effect of TA8-1 type titanium-palladium alloy (TA8-1) and TA2-type pure titanium (TA2) under γ-irradiation was studied based on the geological disposal of nuclear wastes. The irradiation experiments were performed at room temperature using 60Co gamma sources with a 5.0-kGy·h-1 intensity for 40, 80 or 160 days, respectively. The pH value and conductivity of Beishan groundwater were investigated. The results showed that the pH value changed from alkaline (8.22) to acidic (2.46 for TA8-1 and 2.44 for TA2), while the un-irradiated solution remained alkaline (8.17 for TA8-1 and 8.20 for TA2) after 160 days. With the increase of irradiation dose, the conductivity increases rapidly and then tends to become stable, which indicates that the titanium dioxide corrosion layer formed on the surface of the sample surface effectively prevents further corrosion. Meanwhile, XRD and SEM-EDS analysis results show that the main components of corrosion products are TiO2 and TiO. The titanium on the surface of the sample is oxidized, resulting in slight uneven local corrosion. The results show that TA8-1 and TA2 are suitable to be used as candidate materials for high-level waste (HLW) disposal containers due to their excellent performance under long-term and high-dose irradiation corrosion.
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Received: 21 December 2020
Revised: 23 January 2021
Accepted manuscript online: 19 March 2021
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PACS:
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81.40.Wx
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(Radiation treatment)
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61.80.-x
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(Physical radiation effects, radiation damage)
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61.82.Bg
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(Metals and alloys)
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| Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51471160, 11775102, and 11965001) and the Fundamental Research Funds for the Central Universities, China (Lanzhou University, Grant No. lzujbky-2018-19). |
Corresponding Authors:
Yuhong Li, Yibao Liu
E-mail: liyuhong@lzu.edu.cn;ybliu@ecut.edu.cn
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Cite this article:
Qianglin Wei(魏强林), Yuhong Li(李玉红), Yanliang Huang(黄彦良), Dongyan Yang(杨冬燕), Bo Yang(杨波), and Yibao Liu(刘义保) Corrosion behavior of high-level waste container materials Ti and Ti-Pd alloy under long-term gamma irradiation in Beishan groundwater 2021 Chin. Phys. B 30 056109
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[1] World Nuclear Association 2016 Storage and Disposal Options, Radioactive Waste Management Appendix 2
[2] Wang J, Chen L, Su R and Zhao X 2018 J. Rock Mech. Geotech. Eng. 10 411
[3] Bennett D G and Gens R 2008 J. Nucl. Mater. 379 1
[4] Zhang Q, Zheng M, Huang Y L, Kunte H J, Wang X, Liu Y and Zheng C 2019 Sci. Rep. 9 1
[5] Norrfors K K, Björkbacka Å, Kessler A, Wold S and Jonsson M 2018 Rad. Phys. Chem. 144 8
[6] Qin Z, Daljeet R, Ai M, Farhangi N, Noël J J, Ramamurthy S, Shoesmith D, King F and Keech P 2017 Corros. Eng. Sci. Technol. 52 45
[7] Sano Y, Ambai H, Takeuchi M, Iijima S and Uchida N 2017 J. Mater. Sci. Technol. 493 200
[8] Raiman S S and Was G S 2017 J. Mater. Sci. Technol. 493 207
[9] King F, Kolář M and Keech P G 2014 Corros. Eng. Sci. Technol. 49 45
[10] Frankel G S, Vienna J D, Lian J, Scully J R, Gin S, Ryan J V, Wang J, Kim S H, Windl W and Du J 2018 npj Mat. Deg. 2 1
[11] Frankel G S, Vienna J and Lian J 2017 npj Mat. Deg. 1 1
[12] Feng X, Lei J, Gu H and Zhou S 2019 Chin. Phys. B 28 26802
[13] Raj B and Mudali U K 2016 Progress in Nuclear Energy 48 283
[14] Science C, Britain G and Pre P 1990 Corros. Sci. 31 275
[15] Robin A, Rosa J L and Sandim H R Z 2001 J. Appl. Electrochem. 31 455
[16] Brossia C S and Cragnolino G A 2004 Corros. Sci. 46 1693
[17] Michaelis A, Kudelka S and Schultze J W 1998 Electrochimica Acta. 43 119
[18] Ningshen S, Mudali U K, Mukherjee P, Sarkar A, Barat P, Padhy N and Raj B 2008 Corros. Sci. 50 2124
[19] Hua F, Mon K, Pasupathi P, Gordon G and Shoesmith D 2005 Corrosion 61 987
[20] Cheng C, Wang X, Sun J X, Cao C M, Ma Y L and Liu Y X 2018 Acta Phys. Sin. 67 197101 (in Chinese)
[21] Bignon Q, Martin F, Auzoux Q, Miserque F, Tabarant M, Latu-Romain L and Wouters Y 2019 Corros. Sci. 150 32
[22] Rodrigues D C, Valderrama P, Wilson T G, Palmer K, Thomas A, Sridhar S, Adapalli A, Burbano M and Wadhwani C 2013 Materials 6 5258
[23] King F, Lilja C, Pedersen K, Pitkänen P and Vähänen M S Supply Company Report SKB TR-10-67, Posiva Oy Report POSIVA 2011
[24] Marsh G P and Taylor K J 1988 Corros. Sci. 28 289
[25] Liu C, Wang J, Zhang Z and Han E H 2017 Corros. Eng. Sci. Tech. 52 136
[26] Liu C, Wang J, Zhang Z, Han E, Liu W, Liang D, Yang Z and Cao X 2018 J. Mat. Sci. Tech. 34 2131
[27] Shoesmith D W, Ikeda B M and King F 1991 MRS Proc. 257
[28] Padovani C, King F, Lilja C, Féron D, Necib S, Crusset D, Deydier V, Diomidis N, Gaggiano R, Ahn T, Keech P G, Macdonald D D, Asano H, Smart N, Hall D S, Hänninen H, Engelberg D, Noël J J and Shoesmith D W 2017 Corros. Eng. Sci. Technol. 52 227
[29] Björkbacka Å, Hosseinpour S, Johnson M, Leygraf C and Jonsson M 2013 Radiat. Phys. Chem. 92 80
[30] Ollila K 1992 J. Nucl. Mater. 190 70
[31] Liu X and Millero F J 1999 Geochim. Cosmochim. Acta 63 3487
[32] Ningshen S, Mudali U K, Mukherjee P, Barat P and Raj B 2011 J. Nucl. Mater. 408 1
[33] Yamada R, Nagaishi R, Hatano and Yoshida Y Z 2008 Int. J. Hydrogen Energy. 33 929
[34] Zhang QC, Zheng M and Huang Y L 2017 Corros. Eng. Sci. Technol. 52 425
[35] Zheng M, Zhang Q C and Huang Y L 2016 J. Chin. Soc. Corros. Prot. 36 185 (in Chinese)
[36] Bishay A M 1962 J. Am. Cera. Soc. 45 8
[37] Mal D, Puspalata R and Rangarajan S and Velmurugan S 2017 Radiat. Phys. Chem. 138 1
[38] Das S 2013 J. Chem. 66 522
[39] Noël J J, Ebrahimi N and Shoesmith D W 2017 Reference Module in Chemistry, Molecular Sciences and Chemical Engineering (Washington: Princeton) 192
[40] Gray W J and McVay G L 1985 89 257
[41] Václav Č, Mú V, Pospíšil M, Čba V and Múčka V 2012 Adv. Nucl. Fuel. Tech. 27
[42] Macdonald D 1992 J. Electrochem. Soc. 12 34
[43] Noël J J, Ebrahimi N and Shoesmith D W 2018 Elsevier
[44] Shimogori K, Sato H, Tomari H and Ooki A 1976 in: Williams J C and Belov A F (edt.) Titanium and Titanium Alloys (New York: Plenum Press) p. 881
[45] Reyes-Coronado D, Rodriguez-Gattorno G, Espinosa-Pesqueira M E, Aab C, de Coss R and Oskam G 2008 Nanotechnology 19 145605
[46] Thamaphat K, Limsuwan P and Ngotawornchai B 2008 Kasetsart J. Nat. Sci. 361 357
[47] Nelson F S, Westerman J L and Gerber R E 1984 Mater. Res. Soc. Symp. Proc. 26 121 |
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