Abstract The molar volume isotherms of trans-decahydronaphthalene (C$_{10}$H$_{18}$) between 293 and 446 K and at pressures from 10 to 200 MPa have been determined. A modified Tait equation of state is used to fit each experimental molar volume isotherm with a maximum average deviation of 0.029%. The thermal expansivity (cubic expansion coefficient) $\alpha$ and isothermal compressibility $\kappa$ were determined by fitting the slopes of the isobaric curves and isotherms, respectively. The coefficients in the equation $V_m=C_1+C_2 T+C_3 T^2 - C_4 p - C_5 pT$ have been fitted with an average deviation of 1.03%.
Received: 28 April 2005
Revised: 24 August 2005
Accepted manuscript online:
Zhu Hu-Gang (朱虎刚), Liu Zhi-Hua (刘志华), Tian Yi-Ling (田宜灵), Xue Yuan (薛源), Yin Liang (阴亮) Molar volume, thermal expansivity and isothermal compressibility of trans-decahydronaphthalene up to 200MPa and 446K 2005 Chinese Physics 14 2433
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