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X-shape oligo(thiophene)s as donor materials for vacuum-deposited organic photovoltaic cells
王亚楠, 周印华, 徐跃, 孙晓波, 吴伟才, 田文晶, 刘云圻
2008 (4):
1448-1453.
doi: 10.1088/1674-1056/17/4/050
摘要
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The films of two $x$-shape oligo(thiophene)s, 3, 4-dibithienyl-2,
5-dithienylthiophene (7T) and 2, 5-dibithienyl-3,
4-ditrithienylthiophene (11T), which are prepared by vacuum
evaporation, have been investigated as novel electron donor layers in
two-layer photovoltaic cells. UV--Vis absorptions show red-shifted
and broadened absorptions of the vacuum-evaporated films as compared
with those of the corresponding solutions and spin-coating films,
which is beneficial for photovoltaic properties. X-ray diffraction
(XRD) and differential scanning calorimetry (DSC) measurements show
that the vacuum-evaporated films are almost amorphous. Two-layer
photovoltaic cells have been realized by the thermal evaporation of
7T and 11T as donors and $N$, $N'-$bis(1-ethylpropyl)-3,
4:9,10-perylene bis(tetracarboxyl diimide) (EP-PTC) as an acceptor.
An energy conversion efficiency (ECE) of 0.18{\%} of the cell based
on 7T with an irradiation of white light at 100\,mw/cm$^{2}$ has been
demonstrated by the measurements of current ($I$)- voltage ($V$)
curves of the cells to be higher than the ECE of the reference system
based on donor dihexylterthienyl (H3T) that is linear and without
$\alpha $, $\beta $ linkage.
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