中国物理B ›› 2008, Vol. 17 ›› Issue (4): 1371-1376.doi: 10.1088/1674-1056/17/4/036
张涛1, 陈之战1, 宋力昕1, 施尔畏1, 刘学超2, 张华伟2, 陈博源2
Liu Xue-Chao(刘学超)a)b), Zhang Hua-Wei(张华伟)a)b), Zhang Tao(张涛)a), Chen Bo-Yuan(陈博源)a)b), Chen Zhi-Zhan(陈之战)a)†, Song Li-Xin(宋力昕)a), and Shi Er-Wei(施尔畏)a)
摘要: A series of Mn-doped ZnO films have been prepared in different sputtering plasmas by using the inductively coupled plasma enhanced physical vapour deposition. The films show paramagnetic behaviour when they are deposited in an argon plasma. The Hall measurement indicates that ferromagnetism cannot be realized by increasing the electron concentration. However, the room-temperature ferromagnetism is obtained when the films are deposited in a mixed argon-nitrogen plasma. The first-principles calculations reveal that antiferromagnetic ordering is favoured in the case of the substitution of Mn$^{2 + }$ for Zn$^{2 + }$ without additional acceptor doping. The substitution of N for O (N$_{\rm O}^{ - })$ is necessary to induce ferromagnetic couplings in the Zn-Mn-O system. The hybridization between N 2p and Mn 3d provides an empty orbit around the Fermi level. The hopping of Mn 3d electrons through the empty orbit can induce the ferromagnetic coupling. The ferromagnetism in the N-doped Zn-Mn-O system possibly originates from the charge transfer between Mn$^{2 + }$ and Mn$^{3 + }$ via N$_{\rm O}^{ - }$. The key factor is the empty orbit provided by substituting N for O, rather than the conductivity type or the carrier concentration.
中图分类号: (III-V and II-VI semiconductors)