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LOCAL MODE SPECTROSCOPIC STUDY OF THE AsH3 MOLECULE: THE PERTURBED (500) LOCAL MODE OVERTONE
Lin Hai (林海), Oleg N. Ulenikov, Igor M. Olekhnovitch, Wang Dong (王冬), Chen Xi-yi (陈习意), Hao Lu-yuan (郝绿原), Zhu Qing-shi (朱清时),
Chinese Physics, 2000, 9 (2):
113-118.
DOI: 10.1088/1009-1963/9/2/007
The high resolution Fourier transform spectra of AsH3 in the region of 9720-9900 cm-1, which had been recorded at a resolution of 0.015 cm-1, were assigned to the (500; A1) and (500; E) local mode overtones and rotationally analyzed. The effective spectroscopic parameters were obtained by nonlinear least-squares fitting the vibration-rotational Hamiltonian with the rotational energy levels up to J=6 (98 levels in all) included. The evolution of the rotational energy patterns from v=1 to v=6 shows that the tendency of normal mode to local mode vibration evolution has been stopped by perturbations in relatively high energy region.
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