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DYNAMIC NUCLEAR POLARIZATION OF ORGANIC COMPOUND DOPED WITH FREE RADICALS
YANG BAO-LIAN (杨保联), FENG JI-WEN (冯继文), ZHOU JIAN-WEI (周建威), LI LI-YUN (李丽云), YE CHAO-HUI (叶朝辉), HU JIAN-ZHI (胡建治), RONALD J.PUGMIRE, DAVID M.GRANT
Acta Physica Sinica (Overseas Edition), 1998, 7 (2):
106-114.
DOI: 10.1088/1004-423X/7/2/003
For those organic compounds which lack free radicals, a doping approach named melting-liquid-nitrogen-quench was developed in order to perform dynamic nuclear polarization(DNP)-nuclear magnetic resonance experiments. By using this method, the 1H, 13C, 15N DNP enhancements were observed with free-radical-doped dibenzofuran and benzamide. The enhancement mechanism and relation between the concentration of unpaired electrons and the maximum DNP enhancement are discussed.
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