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The second dissociation threshold bound levels of hydrogen molecule
Zhang Yan-Peng, Song Jian-Ping, Gan Chen-Li, Yan Xiang-An, Nie Zhi-Qiang, Jiang Tong, Li Ling, Du Kai, Zhang Xiang-Chen, Lu Ke-Qing, Eyler E.E.
2006, 15 (10):
2288-2296.
doi: 10.1088/1009-1963/15/10/017
Abstract
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PDF (215KB)
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The near-threshold highly bound states of all three stable isotopic
variants of molecular hydrogen have been studied. Numerous
perturbations and unexpected transitions are observed as far as
1cm\sj{-1} just below the second dissociation threshold. This
complex structure may arise from a combination of nonadiabatic
coupling between B, B', C electronic states, perturbations due to
fine and hyperfine interactions, and strong shape resonances. The
perturbed near-threshold states and vibrational continuum exhibit
finegrained structure, differing greatly between isotopes because of
varying nonadiabatic coupling.
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