|
Special Issue:
SPECIAL TOPIC — Celebrating the 70th Anniversary of the Physics of Jilin University
|
| SPECIAL TOPIC—Celebrating the 70th Anniversary of the Physics of Jilin University |
Prev
Next
|
|
|
Effect of the codoping of N—H—O on the growth characteristics and defects of diamonds under high temperature and high pressure |
| Zhenghao Cai(蔡正浩)1, Bowei Li(李博维)1, Liangchao Chen(陈良超)2,†, Zhiwen Wang(王志文)1, Shuai Fang(房帅)1, Yongkui Wang(王永奎)1, Hongan Ma(马红安)1,‡, and Xiaopeng Jia(贾晓鹏)1,§ |
1. State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China;
2. Key Laboratory of Material Physics of Ministry of Education, School of Physics and Microelectronics, Zhengzhou University, Zhengzhou 450052, China |
|
|
|
|
Abstract Diamond crystals were synthesized with different doping proportions of N—H—O at 5.5 GPa—7.1 GPa and 1370 °C—1450 °C. With the increase in the N—H—O doping ratio, the crystal growth rate decreased, the temperature and pressure conditions required for diamond nucleation became increasingly stringent, and the diamond crystallization process was affected. [111] became the dominant plane of diamonds; surface morphology became block-like; and growth texture, stacking faults, and etch pits increased. The diamond crystals had a two-dimensional growth habit. Increasing the doping concentration also increased the amount of N that entered the diamond crystals as confirmed via Fourier transform infrared spectroscopy. However, crystal quality gradually deteriorated as verified by the red-shifting of Raman peak positions and the widening of the Raman full width at half maximum. With the increase in the doping ratio, the photoluminescence property of the diamond crystals also drastically changed. The intensity of the N vacancy center of the diamond crystals changed, and several Ni-related defect centers, such as the NE1 and NE3 centers, appeared. Diamond synthesis in N—H—O-bearing fluid provides important information for deepening our understanding of the growth characteristics of diamonds in complex systems and the formation mechanism of natural diamonds, which are almost always N-rich and full of various defect centers. Meanwhile, this study proved that the type of defect centers in diamond crystals could be regulated by controlling the N—H—O impurity contents of the synthesis system.
|
Received: 25 April 2022
Revised: 01 June 2022
Accepted manuscript online:
|
|
PACS:
|
81.05.ug
|
(Diamond)
|
| |
07.35.+k
|
(High-pressure apparatus; shock tubes; diamond anvil cells)
|
| |
74.62.Dh
|
(Effects of crystal defects, doping and substitution)
|
|
| Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51772120, 11604246, 51872112, and 11804305); the Project of Jilin Science and Technology Development Plan (Grant No. 20180201079GX); the Fundamental Research Funds for the Central Universities, the Natural Science Foundation of Chongqing, China (Grant No. cstc2019jcyj-msxmX0391); and the Science and Technology Research Program of Chongqing Municipal Education Commission (Grant No. KJQN201901405). |
Corresponding Authors:
Liangchao Chen, Hongan Ma, Xiaopeng Jia
E-mail: chenlc@zzu.edu.cn;maha@jlu.edu.cn;jiaxp@jlu.edu.cn
|
Cite this article:
Zhenghao Cai(蔡正浩), Bowei Li(李博维), Liangchao Chen(陈良超), Zhiwen Wang(王志文), Shuai Fang(房帅), Yongkui Wang(王永奎), Hongan Ma(马红安), and Xiaopeng Jia(贾晓鹏) Effect of the codoping of N—H—O on the growth characteristics and defects of diamonds under high temperature and high pressure 2022 Chin. Phys. B 31 108104
|
[1] Ashfold M N R, Goss J P, Green B L, May P W, Newton M E and Peaker C V 2020 Chem. Rev. 120 5745
[2] Stachel T and Luth R W 2015 Lithos 220—223 200
[3] Shatsky V S, Ragozin A L, Logvinova A M, Wirth R, Kalinina V V and Sobolev N V 2020 Lithos 364—365 105514
[4] Cartigny P, Palot M, Thomassot E and Harris J W 2014 Annu. Rev. Earth Planet. Sci. 42 699
[5] Frezzotti M L 2019 Nat. Commun. 10 1
[6] Hudson. P R W and Tsong I S T 1977 J. Mater. Sci. 12 2389
[7] Kaminsky F V and Wirth R 2011 Can. Mineral. 49 555
[8] Gunnlaugsson H P, Weyer G, Dietrich M, Fanciulli M, Bharuth-Ram K and Sielemann R 2003 Phys. B 340—342 537
[9] Nestola F, Cerantola V, Milani S, Anzolini C, McCammon C, Novella D, Kupenko I, Chumakov A, Rüfer R and Harris J W 2016 Lithos 265 328
[10] Chrenko R M, Mcdonald R S and Darrow K A 1967 Nature 474 1
[11] Zhang C and Duan Z 2009 Geochim. Cosmochim. Acta 73 2089
[12] Surovtsev N V and Kupriyanov I N 2017 Crystals 7 239
[13] Chen L, Shen W, Fang C, Zhang Y, Mu P, Zhou G, Wang Q, Zhang Z and Jia X 2020 Cryst. Growth Des. 20 3257
[14] Acosta V M, Bauch E, Ledbetter M P, Santori C, Fu K M C, Barclay P E, Beausoleil R G, Linget H, Roch J F, Treussart F, Chemerisov S, Gawlik W and Budker D 2009 Phys. Rev. B 80 115202
[15] Pezzagna S, Rogalla D, Wildanger D, Meijer J and Zaitsev A 2011 New J. Phys. 13 035024
[16] Rakhmanova M I, Nadolinny V A and Yuryeva O P 2013 Phys. Solid State 55 127
[17] Lindblom J 2005 Am. Mineral. 90 428
[18] Chen C, Mei Y, Cui J, Li X, Jiang M, Lu S and Hu X 2018 Carbon 139 982
[19] Chen N, Ma H, Yan B, Chen L, Chen L, Guo L, Miao X, Fang C and Jia X 2018 Cryst. Growth Des. 18 3870
[20] Isoya J, Kanda H and Uchida Y 1990 Phys. Rev. B 42 9843
[21] Collinss A T, Kanda H and Burns R C 2006 Philos. Mag. B 61 797
[22] Dory C, Vercruysse D, Yang K Y, Sapra N V, Rugar A E, Sun S, Lukin D M, Piggott A Y, Zhang J L, Radulaski M, Lagoudakis K G, Su L and Vuckovic J 2019 Nat. Commun. 10 3309
[23] Kempkes M, Zier T, Singer K and Garcia M E 2021 Carbon 174 524
[24] Fazeli Jadidi M, Özer H Ö, Goel S, Kilpatrick J I, McEvoy N, McCloskey D, Donegan J F and Cross G L W 2020 Carbon 167 114
[25] Palyanov Y N, Khokhryakov A F, Borzdov Y M and Kupriyanov I N 2013 Cryst. Growth Des. 13 5411
[26] Lowther J E 2003 Phys. Rev. B 67 115206
[27] Kiflawi I, Mayer A E, Spear P M, Van Wyk J A and Woods G S 2006 Philos. Mag. B 69 1141
[28] Boyd S R, Kiflawi I and Woods G S 1995 Philos. Mag. B 72 351
[29] Goss J P, Briddon P R, Papagiannidis S and Jones R 2004 Phys. Rev. B 70 235208
[30] Guo L, Ma H, Chen L, Chen N, Miao X, Wang Y, Fang S, Yang Z, Fang C and Jia X 2018 CrystEngComm 20 5457
[31] Guo L, Ma H, Chen L, Chen N, Miao X, Wang Y, Wang Z, Yang Z, Fang C and Jia X 2019 Int. J. Refract. Metals Hard Mater. 79 47
[32] Kazuchits V N, Kazuchits N M, Rusetskiy M S, Korolik O V, Konovalova A V and Ignatenko O V 2021 Carbon 174 180
[33] Prawer S and Nemanich R J 2004 Philosophical Transactions of the Royal Society of London 362 2537
[34] Chen L, Shen W, Fang C, Mu P, Zhou G, Zhang Z, Wang Q, Zhang Y and Jia X 2021 Diam. Relat. Mater. 117 108493
[35] Huang W, Ni P, Shui T and Shi G 2019 Gems Gemol. 55 398
[36] Chen L, Miao X, Ma H, Guo L, Wang Z, Yang Z, Fang C and Jia X 2018 CrystEngComm 20 7164
[37] Hainschwang T, Notari F and Pamies G 2020 Diam. Relat. Mater. 110 108151 |
| No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
Altmetric
|
|
blogs
Facebook pages
Wikipedia page
Google+ users
|
Online attention
Altmetric calculates a score based on the online attention an article receives. Each coloured thread in the circle represents a different type of online attention. The number in the centre is the Altmetric score. Social media and mainstream news media are the main sources that calculate the score. Reference managers such as Mendeley are also tracked but do not contribute to the score. Older articles often score higher because they have had more time to get noticed. To account for this, Altmetric has included the context data for other articles of a similar age.
View more on Altmetrics
|
|
|
