Effects of deuteration on the structure of NH4H2PO4 crystals characterized by neutron diffraction

doi:10.1088/1674-1056/28/1/016103

Abstract

A series of deuterated ammonium dihydrogen phosphate (DADP) crystals were grown and their structures were investigated by using powder neutron diffraction method. In the entire composition range, the deuterated level in the crystals is lower compared with the aqueous growth solution. The deuterium segregation coefficient in the crystals decreases with increasing deuterium content of the solution. The deuterium content in the NH₄⁺ group is higher than that in H₂PO₄^- group. In addition, the variations of lattice parameters are shown here.

Keywords: DADP crystal neutron diffraction deuteration level

Received: 18 October 2018
Revised: 11 November 2018
Accepted manuscript online:

PACS:	61.05.F-	(Neutron diffraction and scattering)
	61.50.-f	(Structure of bulk crystals)
	81.10.Dn	(Growth from solutions)

Fund:

Project supported by the National Natural Science Foundation of China (Grant No. 51402173), Shandong Provincial Natural Science Joint Foundation with Universities and Scientific Research Institution, China (Grant No. ZR2017LEM006), the Neutron Physics Laboratory, China Academy of Engineering Physics (Grant No. 2014BB07), and the Fundamental Research Funds for Central Universities, China (Grant No. FRF-TP-15-099A1).

Corresponding Authors: Lili Zhu
E-mail: zhullcrys@163.com

Cite this article:

Baoan Liu(刘宝安), Lili Zhu(朱丽丽), Fafu Liu(刘发付), Xun Sun(孙洵), Xiping Chen(陈喜平), Lei Xie(谢雷), Yuanhua Xia(夏元华), Guangai Sun(孙光爱), Xin Ju(巨新) Effects of deuteration on the structure of NH₄H₂PO₄ crystals characterized by neutron diffraction 2019 Chin. Phys. B 28 016103

[1]	Boyd G D, Ashkin A, Dziedzic J M and Kleinman D A 1965 Phys. Rev. 137 A1305
[2]	Dmitriev V G, Gurzadyan G G and Nikogosyan D N 1999 Handbook of Nonlinear Optical Crystals, 3rd edn. (Berlin: Springer-Verlag Berlin Heidelberg) p. 90
[3]	Dhanaraj G, Byrappa K, Prasad V and Dudley M 2010 Handbook of Crystal Growth (Part C) (Berlin: Springer-Verlag Berlin Heidelberg) p. 759
[4]	Ji S H, Li F Q, Wang F, Xu X G, Wang Z P and Sun X 2014 Opt. Mater. Express 4 997
[5]	Liu B A, Hu G H, Zhao Y A, Xu M X, Ji S H, Zhu L L, Zhang L S, Sun X, Wang Z P and Xu X G 2013 Opt. Laser Technol. 45 469
[6]	Loiacono G M, Balascio J F and Osborne W 1974 Appl. Phys. Lett. 24 455
[7]	Miyoshi T, Mashiyama H, Asahi T, Kimura H and Noda Y 2011 J. Phys. Soc. Jpn. 80 044709
[8]	Frazer B C and Pepinsky R 1953 Acta Cryst. 6 273
[9]	Fukami T, Akahoshi S, Hukuda K and Yagi T 1987 J. Phys. Soc. Jpn. 56 4388
[10]	Fukami T, Akahoshi S, Hukuda K and Yagi T 1987 J. Phys. Soc. Jpn. 56 2223
[11]	Endo S, Chino T, Tsuboi S and Koto K 1989 Nature 340 452
[12]	Tenzer L, Frazer B C and Pepinsky R 1958 Acta Cryst. 11 505
[13]	Tun Z, Nelmes R J, Kuhs W F and Stansfield R F D 1988 J. Phys. C-Solid State Phys. 21 245
[14]	Boukhris A, Souhassou M, Lecomte C, Wyncke B and Thalal A 1998 J. Phys. -Condens. Mat. 10 1621
[15]	Momtaz R S and Rashkovich L N 1976 Phys. Stat. Sol. (a) 38 401
[16]	Yakshin M A, Kim D W, Kim Y S, Broslavets Y Y, Sidoryuk O E and Goldstein S 1997 Laser Phys. 7 941
[17]	Huser T, Hollars C W, Siekhaus W J, De Yoreo J J, Suratwala T I and Land T A 2004 Appl. Spectrosc. 58 349
[18]	Ji S H, Wang F, Xu M M, Zhu L L, Xu X G, Wang Z P and Sun X 2013 Opt. Lett. 38 1679
[19]	Feng L H, Hu Q W, Lei L, Fang L M, Qi L, Zhang L L, Pu M F, Kou Z L, Peng F, Chen X P, Xia Y H, Kojima Y, Ohfuji H, He D W, Chen B and Irifune T 2018 Chin. Phys. B 27 026201
[20]	Rietveld H M 1967 Acta Cryst. 22 151
[21]	Rietveld H M 1969 J. Appl. Cryst. 2 65
[22]	McCusker L B, Von Dreele R B, Cox D E, Louër D and Scardi P 1999 J. Appl. Cryst. 32 36
[23]	Sun C T and Xue D F 2014 J. Mol. Struct. 1059 338

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Effects of deuteration on the structure of NH4H2PO4 crystals characterized by neutron diffraction

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Effects of deuteration on the structure of NH₄H₂PO₄ crystals characterized by neutron diffraction