Please wait a minute...
Chin. Phys. B, 2014, Vol. 23(5): 057802    DOI: 10.1088/1674-1056/23/5/057802
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES Prev   Next  

Up-conversion luminescence properties and energy transfer of Er3+/Yb3+ co-doped oxyfluoride glass ceramic containing CaF2 nano-crystals

Ma Chen-Shuo (马辰硕)a, Jiao Qing (焦清)a, Li Long-Ji (李龙基)a, Zhou Da-Cheng (周大成)a, Yang Zheng-Wen (杨正文)a b, Song Zhi-Guo (宋志国)a b, Qiu Jian-Bei (邱建备)a b
a College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China;
b Key Laboratory of Advanced Materials of Yunnan Province, Kunming 650093, China
Abstract  The Er3+/Yb3+ co-doped transparent oxyfluoride glass-ceramics containing CaF2 nano-crystals were successfully prepared. After heat treatments, transmission electron microscopy (TEM) images showed that CaF2 nano-crystals of 20-30 nm in diameter precipitated uniformly in the glass matrix. Comparing with the host glass, high efficiency upconversion luminescence of Er3+ at 540 nm and 658 nm was observed in the glass ceramics under the excitation of 980 nm. Moreover, the size of the precipitated nano-crystals can be controlled by heat-treatment temperature and time. With the increase of the nano-crystal size, the intensity of the red emission increased more rapidly than that of the green emission. The energy transfer process of Er3+ and Yb3+ was convinced and the possible mechanism of Er3+ up-conversion was discussed.
Keywords:  nano-crystals      up-conversion luminescence      Er3+/Yb3+ co-doped glass ceramics  
Received:  21 August 2013      Revised:  26 November 2013      Accepted manuscript online: 
PACS:  78.40.-q (Absorption and reflection spectra: visible and ultraviolet)  
  42.70.-a (Optical materials)  
  78.66.Jg (Amorphous semiconductors; glasses)  
  78.67.Bf (Nanocrystals, nanoparticles, and nanoclusters)  
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 61265004, 51272097, and 11204113) and the Nature and Science Fund from Yunnan Province Ministry of Education, China (Grant No. 2011C13211708).
Corresponding Authors:  Qiu Jian-Bei     E-mail:  qiu@kmust.edu.cn
About author:  78.40.-q; 42.70.-a; 78.66.Jg; 78.67.Bf

Cite this article: 

Ma Chen-Shuo (马辰硕), Jiao Qing (焦清), Li Long-Ji (李龙基), Zhou Da-Cheng (周大成), Yang Zheng-Wen (杨正文), Song Zhi-Guo (宋志国), Qiu Jian-Bei (邱建备) Up-conversion luminescence properties and energy transfer of Er3+/Yb3+ co-doped oxyfluoride glass ceramic containing CaF2 nano-crystals 2014 Chin. Phys. B 23 057802

[1] Qiao X S, Fan X P, Wang J and Wang M Q 2005 J. Non-Cryst. Solids 351 357
[2] Xu W, Li C R, Cao B S and Dong B 2010 Chin. Phys. B 19 127804
[3] Li C R, Xu W, Dong B, Li S F, Ding J H, Cheng Y Q and Yin H T 2010 Chin. Phys. B 19 047801
[4] Dai S X, Yu C L, Zhou G, Wang G N and Hu L L 2006 J. Lumin. 117 39
[5] Hu Y B, Qiu J B, Zhou D L, Song Z G and Yang Z W 201 J. Wuhan University of Technology Mater. Sci. Ed. 26 393
[6] Auzel F, Lipinska-Kalita K E and Santa-Cruz P 1996 Opt. Mater. 5 75
[7] Wang Y H and Ohwaki J 1993 Appl. Phys. Lett. 63 3268
[8] Lisiecki R, Augustyn E, Ryba-Romanowski W and Zelechower M 2011 Opt. Mater. 33 1630
[9] Wang D F, Zhang X D, Liu Y J, Wu C Y, Zhang C S, Wei C C and Zhao Y 2013 Chin. Phys. B 22 027801
[10] Zhao S L, Xu S Q, Jia G H, Deng D G, Huang L H and Wang H P 2011 Mater. Lett. 65 2407
[11] Ping H, Chen D Q, Yu Y L and Wang Y S 2010 J. Alloys Compd. 490 74
[12] Ye Y X, Hu X Y, Yan Z Y, Liu E Z, Fan J, Zhang D K, Miao H, Shang Y B and Yang J 2011 Chin. Phys. B 20 087803
[13] Lou K, Song Z G, Shang J H, Yang Z W and Qiu J B 2011 J. Non-Cryst. Solids 357 2251
[14] Zhao S L, Xu S Q, Deng D G and Fan X P 2010 J. Rare Earth 28 903
[15] Hu Z J, Wang Y S, Ma E, Chen D Q and Bao F 2007 Mater. Chem. Phys. 101 234
[16] Chen D Q, Wang Y S, Ma E, Yu Y L and Liu F 2007 Opt. Mater. 29 1693
[17] del-Castillo J, Yanes A C, Méndez-Ramos J, Tikhomirov V K and Rodríguez V D 2009 Opt. Mater. 32 104
[18] Chen D Q, Wang Y S, Zheng K L and Guo T L 2007 Appl. Phys. Lett. 91 251903
[19] Chen D Q, Wang Y S, Yu Y L and Huang P 2007 Appl. Phys. Lett. 91 051920
[20] Chen D Q, Yu Y L, Huang P, Wang F Y, Lin H and Wang Y S 2009 Appl. Phys. Lett. 94 041909
[21] Chen D Q, Yu Y L, Huang P, Lin H, Shan Z F and Wang Y S 2010 Acta Mater. 58 3035
[22] Chen D Q, Yu Y L, Lin H, Huang P, Wang F Y, Shan Z F and Wang Y S 2009 Opt. Lett. 34 2882
[23] Lucca A, Jacquemet M, Druon F, Balembois F, Georges P, Camy P, Doualan J L and Moncorge R 2004 Opt. Lett. 29 1879
[24] Chen D Q, Lei L, Xu J, Yang A P and Wang Y S 2013 Nanotech. 24 085708
[1] Up-conversion luminescence tuning in Er3+-doped ceramic glass by femtosecond laser pulse at different laser powers
Wen-Jing Cheng(程文静), Guo Liang(梁果), Ping Wu(吴萍), Shi-Hua Zhao(赵世华), Tian-Qing Jia(贾天卿), Zhen-Rong Sun(孙真荣), Shi-An Zhang(张诗按). Chin. Phys. B, 2018, 27(12): 123201.
[2] Up-conversion luminescence polarization control in Er3+-doped NaYF4 nanocrystals
Hui Zhang(张晖), Yun-Hua Yao(姚云华), Shi-An Zhang(张诗按), Chen-Hui Lu(卢晨晖), Zhen-Rong Sun(孙真荣). Chin. Phys. B, 2016, 25(2): 023201.
[3] Krypton ion irradiation-induced amorphization and nano-crystal formation in pyrochlore Lu2Ti2O7 at room temperature
Xie Qiu-Rong (谢秋荣), Zhang Jian (张建), Yin Dong-Min (尹东明), Guo Qi-Xun (郭奇勋), Li Ning (李宁). Chin. Phys. B, 2015, 24(12): 126103.
[4] Spectroscopic properties and mechanism of Tm3+/Er3+/Yb3+ co-doped oxyfluorogermanate glass ceramics containing BaF2 nanocrystals
Hu Yue-Bo (胡曰博), Qiu Jian-Bei (邱建备), Zhou Da-Cheng (周大成), Song Zhi-Guo (宋志国), Yang Zheng-Wen (杨正文), Wang Rong-Fei (王荣飞), Jiao Qing (焦清), Zhou Da-Li (周大利). Chin. Phys. B, 2014, 23(2): 024205.
[5] Preparation of NaYF4:Er3+/TiO2 composite and up-conversion luminescence properties under visible light excitation
Ye Yan-Xi(叶岩溪), Hu Xiao-Yun(胡晓云), Yan Zhi-Yun(闫志云), Liu En-Zhou(刘恩周), Fan Jun(樊君), Zhang De-Kai(张德恺), Miao Hui(苗慧), Shang Yi-Bo(商毅博), and Yang Juan(杨娟) . Chin. Phys. B, 2011, 20(8): 087803.
[6] Up-conversion luminescence research of Er(0.5):ZBLAN material for volumetric display application when excited by 1520 nm laser
Chen Xiao-Bo (陈晓波), Zhang Fu-Chu (张福初), Chen Luan (陈鸾). Chin. Phys. B, 2003, 12(12): 1451-1458.
[7] BLUE COOPERATIVE UP-CONVERSION LUMINESCENCE OF Yb3+ IONS IN OXYFLUORIDE GLASS EXCITED BY 960 nm LASER
Chen Xiao-bo (陈晓波), Song Zeng-fu (宋增福), N. Sawanobori. Chin. Phys. B, 2001, 10(6): 564-567.
No Suggested Reading articles found!