Abstract This paper performs multi-reference second-order perturbation theory calculations on the ground state and a number of low-lying excited states of HSCH$_{3}$ molecule, and calculates the vertical excitation energies and low-energy potential-energy curves, based on which the photodissociation channels of HSCH$_{3}$ at 193,222,248 nm are clarified.
Received: 10 June 2007
Revised: 22 August 2007
Accepted manuscript online:
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