Abstract The laser-induced vibrational state-selectivity of product HF in photoassociation reaction H+F$\rightarrow$HF is theoretically investigated by using the time-dependent quantum wave packet method. The population transfer process from the continuum state down to the bound vibrational states can be controlled by the driving laser. The effects of laser pulse parameters and the initial momentum of the two collision atoms on the vibrational population of the product HF are discussed in detail. Photodissociation accompanied with the photoassociation process is also described.
Received: 26 December 2006
Revised: 11 January 2007
Accepted manuscript online:
Fund: Project supported by the
National Natural Science Foundation of China (Grant Nos~10674022
and 20633070).
Cite this article:
Liu Li(刘俐), Niu Ying-Yu(牛英煜), Yuan Kai-Jun(元凯军), and Cong Shu-Lin(丛书林) Control of photoassociation reaction F+H→HF with ultrashort laser pulse 2007 Chinese Physics 16 2957
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