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Chin. Phys. B, 2023, Vol. 32(8): 083101    DOI: 10.1088/1674-1056/ac9e98
ATOMIC AND MOLECULAR PHYSICS Prev   Next  

High-order Hamiltonian obtained by Foldy-Wouthuysen transformation up to the order of mα8

Tong Chen(陈彤)1, Xuesong Mei(梅雪松)2, Wanping Zhou(周挽平)3,‡, and Haoxue Qiao(乔豪学)1,†
1. School of Physics and Technology, Wuhan University, Wuhan 430072, China;
2. Wuhan Maritime Communication Research Institute, Wuhan 430072, China;
3. School of Physics and Telecommunications, Huanggang Normal University, Huanggang 438000, China
Abstract  Complete relativistic corrections of an effective Hamiltonian for a single-particle system in an external electromagnetic field and their unitary equivalent form up to the order of 8 are obtained. The derivation is based on two approaches applying Foldy-Wouthuysen (FW) transformation to the Dirac Hamiltonian for a particle in an external electromagnetic field. The results are consistent with the previous work at the 6 and 8 order correction [Phys. Rev. A 71 012503 (2005); Phys. Rev. A 100 012513 (2019)]. We also further consider the effect of anomalous magnetic moments, namely, the Dirac-Pauli equation, and obtain FW-Hamiltonians at the same order. The results obtained can be used for the subsequent calculation of relativistic and radiation effects in simple atomic and molecular systems.
Keywords:  high-order correction      relativistic corrections      Foldy-Wouthuysen (FW) transformation      effective Hamiltonians  
Received:  31 July 2022      Revised:  19 October 2022      Accepted manuscript online:  31 October 2022
PACS:  31.15.ac (High-precision calculations for few-electron (or few-body) atomic systems)  
  31.15.aj (Relativistic corrections, spin-orbit effects, fine structure; hyperfine structure)  
  31.30.jy (Higher-order effective Hamiltonians)  
Fund: This work was supported by the National Natural Science Foundation of China (Grant Nos.12074295 and 12104420).
Corresponding Authors:  Haoxue Qiao, Wanping Zhou     E-mail:  qhx@whu.edu.cn;zhouwp@whu.edu.cn

Cite this article: 

Tong Chen(陈彤), Xuesong Mei(梅雪松), Wanping Zhou(周挽平), and Haoxue Qiao(乔豪学) High-order Hamiltonian obtained by Foldy-Wouthuysen transformation up to the order of mα8 2023 Chin. Phys. B 32 083101

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