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A single dual-mode gas sensor for early safety warning of Li-ion batteries: Micro-scale Li dendrite and electrolyte leakage |
| Wenjun Yan(闫文君)1,2,†, Zhishen Jin(金志燊)1, Zhengyang Lin(林政扬)1, Shiyu Zhou(周诗瑜)2, Yonghai Du(杜永海)1, Yulong Chen(陈宇龙)3,‡, and Houpan Zhou(周后盘)1 |
1 School of Automation, Hangzhou Dianzi University, Hangzhou 310018, China;
2 Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
3 Institute of Microelectronics, University of Macau, Avenida da Universidade, Taipa, Macau, China |
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Abstract Li dendrites and electrolyte leakage are common causes of Li-ion battery failure. H2, generated by Li dendrites, and electrolyte vapors have been regarded as gas markers of the early safety warning of Li-ion batteries. SnO2-based gas sensors, widely used for a variety of applications, are promising for the early safety detection of Li-ion batteries, which are necessary and urgently required for the development of Li-ion battery systems. However, the traditional SnO2 sensor, with a single signal, cannot demonstrate intelligent multi-gas recognition. Here, a single dual-mode (direct and alternating current modes) SnO2 sensor demonstrates clear discrimination of electrolyte vapors and H2, released in different states of Li-ion batteries, together with principal component analysis (PCA) analysis. This work provides insight into the intelligent technology of single gas sensors.
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Received: 17 August 2022
Revised: 29 September 2022
Accepted manuscript online: 10 October 2022
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PACS:
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07.07.Df
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(Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing)
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85.30.-z
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(Semiconductor devices)
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84.37.+q
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(Measurements in electric variables (including voltage, current, resistance, capacitance, inductance, impedance, and admittance, etc.))
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89.60.Ec
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(Environmental safety)
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| Fund: This research was supported by the Zhejiang Science and Technology Foundation (Grant No. LQ20F040006). |
Corresponding Authors:
Wenjun Yan, Yulong Chen
E-mail: yanwenjun@hdu.edu.cn;yulongchen@um.edu.mo
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Cite this article:
Wenjun Yan(闫文君), Zhishen Jin(金志燊), Zhengyang Lin(林政扬), Shiyu Zhou(周诗瑜), Yonghai Du(杜永海), Yulong Chen(陈宇龙), and Houpan Zhou(周后盘) A single dual-mode gas sensor for early safety warning of Li-ion batteries: Micro-scale Li dendrite and electrolyte leakage 2022 Chin. Phys. B 31 110704
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