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Chin. Phys. B, 2016, Vol. 25(6): 065201    DOI: 10.1088/1674-1056/25/6/065201
PHYSICS OF GASES, PLASMAS, AND ELECTRIC DISCHARGES Prev   Next  

Laser-induced breakdown spectroscopy applied to the characterization of rock by support vector machine combined with principal component analysis

Hong-Xing Yang(杨洪星)1, Hong-Bo Fu(付洪波)1,2, Hua-Dong Wang(王华东)1,2, Jun-Wei Jia(贾军伟)1,2, Markus W Sigrist3, Feng-Zhong Dong(董凤忠)1, 2
1 Anhui Provincial Key Laboratory of Photonic Devices and Materials, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;
2 University of Science and Technology of China, Hefei 230026, China;
3 ETH Zürich, Institute for Quantum Electronics, Otto-Stern-Weg 1, CH-8093 Zurich, Switzerland
Abstract  

Laser-induced breakdown spectroscopy (LIBS) is a versatile tool for both qualitative and quantitative analysis. In this paper, LIBS combined with principal component analysis (PCA) and support vector machine (SVM) is applied to rock analysis. Fourteen emission lines including Fe, Mg, Ca, Al, Si, and Ti are selected as analysis lines. A good accuracy (91.38% for the real rock) is achieved by using SVM to analyze the spectroscopic peak area data which are processed by PCA. It can not only reduce the noise and dimensionality which contributes to improving the efficiency of the program, but also solve the problem of linear inseparability by combining PCA and SVM. By this method, the ability of LIBS to classify rock is validated.

Keywords:  laser-induced breakdown spectroscopy (LIBS)      principal component analysis (PCA)      support vector machine (SVM)      lithology identification  
Received:  08 January 2016      Revised:  01 March 2016      Accepted manuscript online: 
PACS:  52.25.Kn (Thermodynamics of plasmas)  
  52.50.Jm (Plasma production and heating by laser beams (laser-foil, laser-cluster, etc.))  
Fund: 

Project supported by the National Natural Science Foundation of China (Grant No. 11075184), the Knowledge Innovation Program of the Chinese Academy of Sciences (CAS) (Grant No. Y03RC21124), and the CAS President's International Fellowship Initiative Foundation (Grant No. 2015VMA007).

Corresponding Authors:  Feng-Zhong Dong     E-mail:  fzdong@aiofm.ac.cn

Cite this article: 

Hong-Xing Yang(杨洪星), Hong-Bo Fu(付洪波), Hua-Dong Wang(王华东), Jun-Wei Jia(贾军伟), Markus W Sigrist, Feng-Zhong Dong(董凤忠) Laser-induced breakdown spectroscopy applied to the characterization of rock by support vector machine combined with principal component analysis 2016 Chin. Phys. B 25 065201

[1] Cao Y, Liu X L, Xian W D, Sun S H, Sun M Z, Ding P J, Shi Y C, Liu Z Y and Hu B T 2015 Chin. Phys. Lett. 32 035203
[2] Chen H, Lan H, Chen Z Q, Liu L N, Wu T, Zuo D L, Lu P X and Wang X B 2015 Acta Phys. Sin. 64 075202 (in Chinese)
[3] Zhang Z M, Zhang B, Wu F J, Hong W, Teng J, He S K and Gu Y Q 2014 Acta Phys. Sin. 64 105201 (in Chinese)
[4] Zhang L, Dong Q L, Wang S J, Sheng Z M and Zhang J 2010 Chin. Phys. B 19 078701
[5] Yu J, Ma Q L, Motto-Ros V, Lei W Q, Wang X C and Bai X S 2012 Front. Phys. 7 649
[6] Li Z C, Zheng J, Jiang X H, Wang Z B, Yang D, Zhang H, Li S W, Wang F, Peng X S and Yin Q 2011 Chin. Phys. Lett. 28 125202
[7] Li Z C, Zheng J, Ding Y K, Yin Q, Jiang X H, Li S W, Guo L, Yang D, Wang Z B and Zhang H 2010 Chin. Phys. B 19 125202
[8] Zhao Y, Zhu T, Wei M X, Xiong G, Song T M, Hu Z M, Huang C W, Shang W L, Yang G H and Zhang J Y 2012 Chin. Phys. Lett. 29 085202
[9] Noll R 2012 Laser-Induced Breakdown Spectroscopy: Fundamentals and Applications (Berlin: Springer) p. 7
[10] Lorenzen C J, Carlhoff C, Hahn U and Jogwich M 1992 J. Anal. Atom. Spectrom. 7 1029
[11] Palanco S and Laserna J 2000 J. Anal. Atom. Spectrom. 15 1321
[12] Kurihara M, Ikeda K, Izawa Y, Deguchi Y and Tarui H 2003 Appl. Opt. 42 6159
[13] Noll R, Mönch I, Klein O and Lamott A 2005 Spectrochim. Acta B 60 1070
[14] Tran M, Smith B W, Hahn D W and Winefoner J D 2001 Appl. Spectrosc. 55 1455
[15] Hettinger B, Hohreiter V, Swingle M and Hahn D W 2006 Appl. Spectrosc. 60 237
[16] Bossu M, Hao Z Q, Baudelet M, Yu J, Zhang Z and Zhang J 2007 Chin. Phys. Lett. 24 3466
[17] Zhu G Z, Guo L B, Hao Z Q, Li C M, Shen M S, Li K H, Li X Y, Liu J G, Zeng X Y and Lu Y F 2015 Acta Phys. Sin. 64 024212 (in Chinese)
[18] Sirven J B, Bousquet B, Canioni L, Sarger L, Tellier S, Potin-Gautier M and Le Hecho I 2006 Anal. Bioanal. Chem. 385 256
[19] Bousquet B, Sirven J B and Canioni L 2007 Spectrochim. Acta B 62 1582
[20] Senesi G, Dell'Aglio M, Gaudiuso R, De Giacomo A, Zaccone C, De Pascale O, Miano T and Capitelli M 2009 Environmental Research 109 413
[21] Morel S, Leone N, Adam P and Amouroux J 2003 Appl. Opt. 42 6184
[22] Corsi M, Cristoforetti G, Hidalgo M, Legnaioli S, Palleschi V, Salvetti A, Tognoni E and Vallebona C 2003 Appl. Opt. 42 6133
[23] Burgio L, Melessanaki K, Doulgeridis M, Clark R J H and Anglos D 2001 Spectrochim. Acta B 56 905
[24] Giakoumaki A, Melessanaki K and Anglos D 2007 Anal. Bioanal. Chem. 387 749
[25] Kaszewska E A, Sylwestrzak M, Marczak J, Skrzeczanowski W, Iwanicka M, Szmit-Naud E, Anglos D and Targowski P 2013 Appl. Spectrosc. 67 960
[26] Wang S H, Li Z L, Sun C L, Li Z W and Men Z W 2014 Acta Phys. Sin. 63 205204 (in Chinese)
[27] Zhang N, Bao W X, Yang J H and Zhu X N 2013 Chin. Phys. B 22 054209
[28] Sirven J B, Salle B, Mauchien P, Lacour J L, Maurice S and Manhes G 2007 J. Anal. Atom. Spectrom. 22 1471
[29] Yueh F Y, Zheng H B, Singh J P and Burgess S 2009 Spectrochim. Acta B 64 1059
[30] Cisewski J, Snyder E, Hannig J and Oudejans L 2012 J. Chemometr. 26 143
[31] De Lucia F C and Gottfried J L 2012 Appl. Opt. 51 B83
[32] Yu Y, Hao Z Q, Li C M, Guo L B, Li K H, Zeng Q D, Li X Y, Ren Z and Zeng X Y 2013 Acta Phys. Sin. 62 215201 (in Chinese)
[33] Tian Y, Wang Z N, Hou H M, Zhai X W, Ci X H and Zheng R E 2012 Spectrosc. Spect. Anal. 32 2027
[34] Wang Q Q, Liu K and Zhao H 2012 Chin. Phys. Lett. 29 044206
[35] Chen X L, Dong F Z, Tao G Q, Li Y J, She M J, Fu H B, Ni Z B and Wang J G 2013 Chin. J. Lasers 40 1215001
[36] Cristoforetti G, De Giacomo A, Dell'Aglio M, Legnaioli S, Tognoni E, Palleschi V and Omenetto N 2010 Spectrochim. Acta B 65 86
[37] Sun L X, Yu H B, Xin Y and Cong Z B 2010 Spectrosc. Spect. Anal. 30 3186
[38] Stipe C B, Hensley B D, Boersema J L and Buckley S G 2010 Appl. Spectrosc. 64 154
[39] Clegg S M, Sklute E, Dyar M D, Barefield J E and Wiens R C 2009 Spectrochim. Acta B 64 79
[40] Laville S, Sabsabi M and Doucet F R 2007 Spectrochim. Acta B 62 1557
[41] Bredice F, Borges F O, Sobral H, Villagran-Muniz M, Di Rocco H O, Cristoforetti G, Legnaioli S, Palleschi V, Pardini L, Salvetti A and Tognoni E 2006 Spectrochim. Acta B 61 1294
[42] Bulajic D, Corsi M, Cristoforetti G, Legnaioli S, Palleschi V, Salvetti A and Tognoni E 2002 Spectrochim. Acta B 57 339
[43] Cristianini N and Shawe-Taylor J 2000 An introduction to support vector machines and other kernel-based learning methods (Cambridge: Cambridge University Press) p. 93
[44] Liu Y F, Ding Y J, Peng Z M, Huang Y and Du Y J 2014 Acta Phys. Sin. 63 205205 (in Chinese)
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