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DYNAMIC NUCLEAR POLARIZATION OF ORGANIC COMPOUND DOPED WITH FREE RADICALS
YANG BAO-LIAN, FENG JI-WEN, ZHOU JIAN-WEI, LI LI-YUN, YE CHAO-HUI, HU JIAN-ZHI, RONALD J.PUGMIRE, DAVID M.GRANT
1998, 7 (2):
106-114.
doi: 10.1088/1004-423X/7/2/003
Abstract
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PDF (247KB)
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For those organic compounds which lack free radicals, a doping approach named melting-liquid-nitrogen-quench was developed in order to perform dynamic nuclear polarization(DNP)-nuclear magnetic resonance experiments. By using this method, the 1H, 13C, 15N DNP enhancements were observed with free-radical-doped dibenzofuran and benzamide. The enhancement mechanism and relation between the concentration of unpaired electrons and the maximum DNP enhancement are discussed.
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