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Laser scattering, transmittance and low thermal expansion behaviors in Y2-x(ZnLi)xMo3O12 by forming regular grains |
| Xian-Sheng Liu(刘献省)1, Yong-Guang Cheng(程永光)2, Bao-He Yuan(袁保合)3, Er-Jun Liang(梁二军)4, Wei-Feng Zhang(张伟风)1 |
1 Henan Key Laboratory of Photovoltaic Materials and Low Dimensional Materials Science Laboratory, Henan University, Kaifeng 475004, China;
2 College of Science, Center of Analysis and Testing of Henan Institute of Engineering, Zhengzhou 451191, China;
3 North China University of Water Resources and Electric Power, Zhengzhou 450011, China;
4 School of Physical Science & Engineering and Key Laboratory of Materials Physics of Ministry of Education of China, Zhengzhou University, Zhengzhou 450052, China |
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Abstract Ceramics usually have irregular grains, cracking, or porosity, which result in their lightproof. Y2Mo3O12 ceramics have more porosity due to the heavy hygroscopicity. Introducing ZnLi to Y2Mo3O12 could form regular grains, reduce cracking and porosity. With increasing the content of ZnLi, the grain shapes self-assembly gradually and then the laser scattering and transmittance improve. The laser scattering property and transmittance of diverging rays become the best in ceramics Y2-x(ZnLi)xMo3O12 (x=1.0 and 1.2) with regular grains and low thermal expansion. The formation mechanism of regular grains is ascribed to the substitutions of Zn2+ and Li+ for Y3+ in Y2Mo3O12 resulting in the preferential growth. The investigation in laser scattering, transmittance and low thermal expansion behaviors of Y2-x(ZnLi)xMo3O12 could pave a way to weaken the strong-laser attack from the high-power laser weapon and the other.
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Received: 08 June 2019
Revised: 10 July 2019
Accepted manuscript online:
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PACS:
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65.40.De
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(Thermal expansion; thermomechanical effects)
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78.20.Ek
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(Optical activity)
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81.05.Je
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(Ceramics and refractories (including borides, carbides, hydrides, nitrides, oxides, and silicides))
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81.10.Jt
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(Growth from solid phases (including multiphase diffusion and recrystallization))
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| Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 60976016, 61350012, and 11574276), the Key Scientific Research Projects of Henan Province, China (Grant No. 15B140004), Henan Science and Technology Development Project, China (Grant No. 182102210241), Key Projects of Science and Technology Research of Henan Provincial Department of Education, China (Grant No. 18A140014), and Industrial Science and Technology Research Projects of Kaifeng, Henan Province, China (Grant No. 1501049). |
Corresponding Authors:
Er-Jun Liang, Wei-Feng Zhang
E-mail: ejliang@zzu.edu.cn;wfzhang@henu.edu.cn
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Cite this article:
Xian-Sheng Liu(刘献省), Yong-Guang Cheng(程永光), Bao-He Yuan(袁保合), Er-Jun Liang(梁二军), Wei-Feng Zhang(张伟风) Laser scattering, transmittance and low thermal expansion behaviors in Y2-x(ZnLi)xMo3O12 by forming regular grains 2019 Chin. Phys. B 28 096501
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