Please wait a minute...
Chin. Phys. B, 2008, Vol. 17(4): 1501-1505    DOI: 10.1088/1674-1056/17/4/058
CROSS DISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY Prev   Next  

Multi-reference calculations of the photodissociation of HSCH3 molecule

Yan Bing(闫冰) and Pan Shou-Fu(潘守甫)
Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012, China
Abstract  This paper performs multi-reference second-order perturbation theory calculations on the ground state and a number of low-lying excited states of HSCH$_{3}$ molecule, and calculates the vertical excitation energies and low-energy potential-energy curves, based on which the photodissociation channels of HSCH$_{3}$ at 193,222,248 nm are clarified.
Keywords:  photodissociation      potential-energy curve      HSCH$_{3}$ molecule  
Received:  10 June 2007      Revised:  22 August 2007      Accepted manuscript online: 
PACS:  31.15.xp (Perturbation theory)  
  31.15.xr (Self-consistent-field methods)  
  31.50.Df (Potential energy surfaces for excited electronic states)  
  33.80.Gj (Diffuse spectra; predissociation, photodissociation)  
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos 10604022 and 60278009).

Cite this article: 

Yan Bing(闫冰) and Pan Shou-Fu(潘守甫) Multi-reference calculations of the photodissociation of HSCH3 molecule 2008 Chin. Phys. B 17 1501

[1] Direct Coulomb explosion of N2O2+ induced by monochromatic extreme ultraviolet photons at 38.5 eV
Min Zhang(张敏), B Najjari, Bang Hai(海帮), Dong-Mei Zhao(赵冬梅), Jian-Ting Lei(雷建廷), Da-Pu Dong(董达谱), Shao-Feng Zhang(张少锋), Xin-Wen Ma(马新文). Chin. Phys. B, 2020, 29(6): 063302.
[2] Production of cold CN molecules by photodissociating ICN precursors in brute-force field
Wen-Xia Xu(徐文霞), Yong-Cheng Yang(杨永成), Lian-Zhong Deng(邓联忠). Chin. Phys. B, 2017, 26(5): 053702.
[3] Coulomb explosion of CS2 molecule under an intense femtosecond laser field
Xiao Wang(王潇), Jian Zhang(张健), Shi-An Zhang(张诗按), Zhen-Rong Sun(孙真荣). Chin. Phys. B, 2016, 25(5): 053301.
[4] Photostop of iodine atoms from electrically oriented ICl molecules
Bao Da-Xiao (暴大小), Deng Lian-Zhong (邓联忠), Xu Liang (许亮), Yin Jian-Ping (印建平). Chin. Phys. B, 2015, 24(11): 113702.
[5] Production of CH (A2Δ) by multi-photon dissociation of (CH3)2CO, CH3NO2, CH2Br2, and CHBr3 at 213 nm
Li Sheng-Qiang (李胜强), Xu Liang (许亮), Chen Yang-Qin (陈扬骎), Deng Lian-Zhong (邓联忠), Yin Jian-Ping (印建平). Chin. Phys. B, 2014, 23(8): 083701.
[6] Control of the photoionization/photodissociation processes of cyclopentanone with trains of femtosecond laser pulses
Song Yao-Dong (宋耀东), Chen Zhou (陈洲), Yang Xue (杨雪), Sun Chang-Kai (孙长凯), Zhang Cong-Cong (张丛丛), Hu Zhan (胡湛). Chin. Phys. B, 2013, 22(10): 103301.
[7] Interference of dissociating wave packets in the I2 molecule driven by femtosecond laser pulses
Han Yong-Chang(韩永昌), Hu Wen-Hui(胡文辉), Yu Jie(于杰),andCong Shu-Lin(丛书林). Chin. Phys. B, 2009, 18(11): 4834-4839.
No Suggested Reading articles found!