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Chinese Physics, 2004, Vol. 13(12): 2158-2161    DOI: 10.1088/1009-1963/13/12/032
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES Prev   Next  

Mössbauer study and magnetic properties of electrochemical material LiFePO4

Luo Zhi (罗志)ab, Di Nai-Li (邸乃力)a, Kou Zhi-Qi (寇志起)a, Cheng Zhao-Hua (成昭华)a, Liu Li-Jun (刘立君)c, Chen Li-Quan (陈立泉)c, Huang Xue-Jie (黄学杰)c 
a State Key Laboratory of Magnetism, Institute of Physics and Centre for Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100080, China; b Department of Physics, Shantou University, Shantou 515063, China; c Institute of Physics and Centre for Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100080, China
Abstract  Magnetic properties and crystal symmetry of electrochemical material LiFePO4 have been investigated by M?ssbauer spectroscopy and magnetization measurement. Magnetization reveals the antiferromagnetic nature of LiFePO4. Temperature dependence of inverse susceptibility and that of hyperfine field confirm that there is an antiferromagnetic-paramagnetic transition at about 50K.
Keywords:  lithium-polymer battery      Mössbauer spectroscopy      lithium iron phosphates  
Received:  14 May 2004      Revised:  17 August 2004      Accepted manuscript online: 
PACS:  76.80.+y (M?ssbauer effect; other γ-ray spectroscopy)  
  75.60.Ej (Magnetization curves, hysteresis, Barkhausen and related effects)  
  75.30.Kz (Magnetic phase boundaries (including classical and quantum magnetic transitions, metamagnetism, etc.))  
  75.50.Ee (Antiferromagnetics)  
  75.30.Cy  
Fund: Project supported by the State Key Development Programme for Basic Research of China (Grand No 2001CB610605) and the National Natural Sciences Foundation of China (Grand No10274014).

Cite this article: 

Luo Zhi (罗志), Di Nai-Li (邸乃力), Kou Zhi-Qi (寇志起), Cheng Zhao-Hua (成昭华), Liu Li-Jun (刘立君), Chen Li-Quan (陈立泉), Huang Xue-Jie (黄学杰) Mössbauer study and magnetic properties of electrochemical material LiFePO4 2004 Chinese Physics 13 2158

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