中国物理B ›› 2010, Vol. 19 ›› Issue (3): 36802-036802.doi: 10.1088/1674-1056/19/3/036802

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Effects of switching pulse width and stress on properties of Bi3.25La0.75Ti3O12 thin films

吕笑梅1, 刘云飞1, 朱劲松1, 吴秀梅2, 陈华2, 翟亚2   

  1. (1)National Laboratory of Solid State Microstructures, Physics Department, Nanjing University, Nanjing 210093, China; (2)Physics Department, Southeast University, Nanjing 211189, China
  • 收稿日期:2009-06-03 修回日期:2009-07-28 出版日期:2010-03-15 发布日期:2010-03-15
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant No.~50871029), the National Basic Research Program of China (Grant Nos.~2010CB923401 and 2009CB929501) and the Cyanine-Project Foundation of Jiangsu Province of China (Grant No.~1107020060).

Effects of switching pulse width and stress on properties of Bi3.25La0.75Ti3O12 thin films

Wu Xiu-Mei(吴秀梅)a)†, Chen-Hua(陈华) a), Zhai-Ya(翟亚)a), Lu Xiao-Mei(吕笑梅)b), Liu Yun-Fei(刘云飞)b), and Zhu Jin-Song(朱劲松)b)   

  1. a Physics Department, Southeast University, Nanjing 211189, China; b National Laboratory of Solid State Microstructures, Physics Department, Nanjing University, Nanjing 210093, China
  • Received:2009-06-03 Revised:2009-07-28 Online:2010-03-15 Published:2010-03-15
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No.~50871029), the National Basic Research Program of China (Grant Nos.~2010CB923401 and 2009CB929501) and the Cyanine-Project Foundation of Jiangsu Province of China (Grant No.~1107020060).

摘要: Polycrystalline ferroelectric Bi3.25La0.75Ti3O12 thin films are prepared on Pt/Ti/SiO2/Si substrates by the conventional metalorganic decomposition method. It is observed that with the increase of switching pulse width, the remnant polarisation and the coercive field increase. A wider switching pulse can result in poorer fatigue properties, which comes from more charged defects diffusing to and being trapped on domain walls. On the other hand, when the compressive stress is applied to films, the fatigue properties can be improved. This phenomenon is due to the reorientation of domains under stress.

Abstract: Polycrystalline ferroelectric Bi3.25La0.75Ti3O12 thin films are prepared on Pt/Ti/SiO2/Si substrates by the conventional metalorganic decomposition method. It is observed that with the increase of switching pulse width, the remnant polarisation and the coercive field increase. A wider switching pulse can result in poorer fatigue properties, which comes from more charged defects diffusing to and being trapped on domain walls. On the other hand, when the compressive stress is applied to films, the fatigue properties can be improved. This phenomenon is due to the reorientation of domains under stress.

Key words: ferroelectric films, polarisation, domains

中图分类号: 

  • 77.55.+f
77.80.Dj (Domain structure; hysteresis) 77.22.Ej (Polarization and depolarization) 68.60.Bs (Mechanical and acoustical properties) 81.15.Gh (Chemical vapor deposition (including plasma-enhanced CVD, MOCVD, ALD, etc.))