中国物理B ›› 2013, Vol. 22 ›› Issue (2): 27803-027803.doi: 10.1088/1674-1056/22/2/027803

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇    下一篇

A novel Dy3+-doped Gd(PO3)3 white-light phosphors under VUV excitation for Hg-free lamps application

张锂a, 韩国才b   

  1. a Department of Basic Course, Lanzhou Institute of Technology, Lanzhou 730050, China;
    b Department of Material Engineering, Lanzhou Institute of Technology, Lanzhou 730050, China
  • 收稿日期:2012-04-26 修回日期:2012-07-07 出版日期:2013-01-01 发布日期:2013-01-01
  • 基金资助:
    Project supported by the National Natural Science Foundation for Young Scientists of China (Grant No. 502041032).

A novel Dy3+-doped Gd(PO3)3 white-light phosphors under VUV excitation for Hg-free lamps application

Zhang Li (张锂)a, Han Guo-Cai (韩国才)b   

  1. a Department of Basic Course, Lanzhou Institute of Technology, Lanzhou 730050, China;
    b Department of Material Engineering, Lanzhou Institute of Technology, Lanzhou 730050, China
  • Received:2012-04-26 Revised:2012-07-07 Online:2013-01-01 Published:2013-01-01
  • Contact: Han Guo-Cai E-mail:hgclzu@163.com
  • Supported by:
    Project supported by the National Natural Science Foundation for Young Scientists of China (Grant No. 502041032).

摘要: Novel Dy3+-doped Gd(PO3)3 white light phosphors each with an orthorhombic system are successfully synthesized by solid-state reaction. The luminescence properties of white-light Gd1-x(PO3)3:xDy3+ (0<x≤ 0.25) under vacuum ultraviolet (VUV) excitation are investigated. The strong absorption at around 147 nm in excitation spectrum energy can be transferred to the energy levels of Dy3+ ion from the host absorption. Additionally, the white light phosphor is activated by a single Dy3+ ion. Therefore, the luminescence of Gd1-x(PO3)3:xDy (0<x≤ 0.25) under VUV excitation is effective, and it has the promise of being applied to mercury-free lamp.

关键词: vacuum ultraviolet, white light, phosphors

Abstract: Novel Dy3+-doped Gd(PO3)3 white light phosphors each with an orthorhombic system are successfully synthesized by solid-state reaction. The luminescence properties of white-light Gd1-x(PO3)3:xDy3+ (0<x≤ 0.25) under vacuum ultraviolet (VUV) excitation are investigated. The strong absorption at around 147 nm in excitation spectrum energy can be transferred to the energy levels of Dy3+ ion from the host absorption. Additionally, the white light phosphor is activated by a single Dy3+ ion. Therefore, the luminescence of Gd1-x(PO3)3:xDy (0<x≤ 0.25) under VUV excitation is effective, and it has the promise of being applied to mercury-free lamp.

Key words: vacuum ultraviolet, white light, phosphors

中图分类号:  (Photoluminescence, properties and materials)

  • 78.55.-m
78.66.-w (Optical properties of specific thin films)