Effect of sintering temperature on luminescence properties of borosilicate matrix blue-green emitting color conversion glass ceramics

doi:10.1088/1674-1056/ab3f97

中国物理B ›› 2019, Vol. 28 ›› Issue (10): 108102-108102.doi: 10.1088/1674-1056/ab3f97

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

Effect of sintering temperature on luminescence properties of borosilicate matrix blue-green emitting color conversion glass ceramics

Qiao-Yu Zheng(郑巧瑜), Yang Li(李杨), Wen-Juan Wu(吴文娟), Ming-Ming Shi(石明明), Bo-Bo Yang(杨波波), Jun Zou(邹军)

1 School of Science, Shanghai Institute of Technology, Shanghai 201418, China;
2 School of Material Science and Engineering, Shanghai Institute of Technology, Shanghai 201418, China;
3 Institute of Beyond Lighting, Academy for Engineering and Technology, Fudan University, Shanghai 200433, China;
4 Institute of New Materials & Industrial Technology, Wenzhou University, Wenzhou 325024, China

收稿日期:2019-06-04 修回日期:2019-08-09 出版日期:2019-10-05 发布日期:2019-10-05
通讯作者: Yang Li, Wen-Juan Wu E-mail:liyang123@sit.edu.cn;wuwj0k@163.com
基金资助:
Project supported by the Science and Technology Planning Project of Zhejiang Province, China (Grant No. 2018C01046) and Enterprise-funded Latitudinal Research Projects, China (Grant Nos. J2016-141, J2017-171, J2017-293, and J2017-243).

Effect of sintering temperature on luminescence properties of borosilicate matrix blue-green emitting color conversion glass ceramics

Qiao-Yu Zheng(郑巧瑜)¹, Yang Li(李杨)², Wen-Juan Wu(吴文娟)¹, Ming-Ming Shi(石明明)¹, Bo-Bo Yang(杨波波)^1,3, Jun Zou(邹军)^1,4

1 School of Science, Shanghai Institute of Technology, Shanghai 201418, China;
2 School of Material Science and Engineering, Shanghai Institute of Technology, Shanghai 201418, China;
3 Institute of Beyond Lighting, Academy for Engineering and Technology, Fudan University, Shanghai 200433, China;
4 Institute of New Materials & Industrial Technology, Wenzhou University, Wenzhou 325024, China

Received:2019-06-04 Revised:2019-08-09 Online:2019-10-05 Published:2019-10-05
Contact: Yang Li, Wen-Juan Wu E-mail:liyang123@sit.edu.cn;wuwj0k@163.com
Supported by:
Project supported by the Science and Technology Planning Project of Zhejiang Province, China (Grant No. 2018C01046) and Enterprise-funded Latitudinal Research Projects, China (Grant Nos. J2016-141, J2017-171, J2017-293, and J2017-243).

摘要/Abstract

摘要： The color conversion glass ceramics which were made of borosilicate matrix co-doped (SrBaSm)Si₂O₂N₂:(Eu³⁺Ce³⁺) blue-green phosphors were prepared by two-step method in co-sintering. The change in luminescence properties and the drift of chromaticity coordinates (CIE) of the (SrBaSm)Si₂O₂N₂:(Eu³⁺Ce³⁺) blue-green phosphors and the color conversion glass ceramics were studied in the sintering temperature range from 600 ℃ to 800 ℃. The luminous intensity and internal quantum yield (QY) of the blue-green phosphors and glass ceramics decreased with the sintering temperature increasing. When the sintering temperature increased beyond 750 ℃, the phosphors and the color conversion glass ceramics almost had no peak in photoluminescence (PL) and excitation (PLE) spectra. The results showed that the blue-green phosphors had poor thermal stability at higher temperature. The lattice structure of the phosphors was destroyed by the glass matrix and the Ce³⁺ in the phosphors was oxidized to Ce⁴⁺, which further caused a decrease in luminescent properties of the color conversion glass ceramics.

关键词: (SrBaSm)Si₂O₂N₂: (Eu³⁺Ce³⁺) phosphors, blue-green color conversion glass ceramic, luminescent intensity, thermal quenching effects, sintering temperature

Abstract: The color conversion glass ceramics which were made of borosilicate matrix co-doped (SrBaSm)Si₂O₂N₂:(Eu³⁺Ce³⁺) blue-green phosphors were prepared by two-step method in co-sintering. The change in luminescence properties and the drift of chromaticity coordinates (CIE) of the (SrBaSm)Si₂O₂N₂:(Eu³⁺Ce³⁺) blue-green phosphors and the color conversion glass ceramics were studied in the sintering temperature range from 600 ℃ to 800 ℃. The luminous intensity and internal quantum yield (QY) of the blue-green phosphors and glass ceramics decreased with the sintering temperature increasing. When the sintering temperature increased beyond 750 ℃, the phosphors and the color conversion glass ceramics almost had no peak in photoluminescence (PL) and excitation (PLE) spectra. The results showed that the blue-green phosphors had poor thermal stability at higher temperature. The lattice structure of the phosphors was destroyed by the glass matrix and the Ce³⁺ in the phosphors was oxidized to Ce⁴⁺, which further caused a decrease in luminescent properties of the color conversion glass ceramics.

Key words: (SrBaSm)Si₂O₂N₂: (Eu³⁺Ce³⁺) phosphors, blue-green color conversion glass ceramic, luminescent intensity, thermal quenching effects, sintering temperature

中图分类号: (Glasses (including metallic glasses))

81.05.Kf

42.70.Ce (Glasses, quartz)

郑巧瑜, 李杨, 吴文娟, 石明明, 杨波波, 邹军. Effect of sintering temperature on luminescence properties of borosilicate matrix blue-green emitting color conversion glass ceramics[J]. 中国物理B, 2019, 28(10): 108102-108102.

Qiao-Yu Zheng(郑巧瑜), Yang Li(李杨), Wen-Juan Wu(吴文娟), Ming-Ming Shi(石明明), Bo-Bo Yang(杨波波), Jun Zou(邹军). Effect of sintering temperature on luminescence properties of borosilicate matrix blue-green emitting color conversion glass ceramics[J]. Chin. Phys. B, 2019, 28(10): 108102-108102.

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Effect of sintering temperature on luminescence properties of borosilicate matrix blue-green emitting color conversion glass ceramics

Effect of sintering temperature on luminescence properties of borosilicate matrix blue-green emitting color conversion glass ceramics

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