中国物理B ›› 2011, Vol. 20 ›› Issue (12): 127102-127102.doi: 10.1088/1674-1056/20/12/127102
• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇 下一篇
李世帅, 张仲, 黄金昭, 冯秀鹏, 刘如喜
Li Shi-Shuai(李世帅), Zhang Zhong(张仲)†, Hang Jin-Zhao(黄金昭), Feng Xiu-Peng(冯秀鹏), and Liu Ru-Xi(刘如喜)
摘要: In:ZnO nanoparticles are prepared by the sol-gel process. The ratios of In/(Zn+In) are 0%, 5%, 8%, 10%, and 15%, respectively. Crystal phase structures and optoelectronic properties of these samples are characterized and the chromaticity coordinates of different samples are also calculated in CIE-XYZ colour system. The results show that preferred growth direction of ZnO changes from (002) plane to (001) plane and interplanar distance becomes shorter. When the doping amount of In is 5%, Zn atoms are completely replaced by In atoms. The resistivities of the samples first decrease, then increase afterwards with the increase of the amount of In. With the increase of In, the ultraviolet emission is redshifted and new peaks occur at 465 nm, 535 nm, and 630 nm. The sample with 10% indium has white-light emission. The band structures of samples with 0% and 12.5% indium are investigated by the first principle method. The mechanism of white emission is discussed from the viewpoint of additional energy levels.
中图分类号: (II-VI semiconductors)