中国物理B ›› 2016, Vol. 25 ›› Issue (2): 27702-027702.doi: 10.1088/1674-1056/25/2/027702

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇    下一篇

Improvement in electrical properties of high-κfilm on Ge substrate by an improved stress relieved pre-oxide method

Ji-Bin Fan(樊继斌), Xiao-Fu Ding(丁晓甫), Hong-Xia Liu(刘红侠), Peng-Fei Xie(谢鹏飞), Yuan-Tao Zhang(张袁涛), Qing-Liang Liao(廖清良)   

  1. 1. School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China;
    2. School of Microelectronics, Key Laboratory of Wide Band-Gap Semiconductor Materials and Devices, Xidian University, Xi'an 710071, China
  • 收稿日期:2015-07-11 修回日期:2015-09-28 出版日期:2016-02-05 发布日期:2016-02-05
  • 通讯作者: Ji-Bin Fan E-mail:jbfan@chd.edu.cn

Improvement in electrical properties of high-κfilm on Ge substrate by an improved stress relieved pre-oxide method

Ji-Bin Fan(樊继斌)1,2, Xiao-Fu Ding(丁晓甫)1, Hong-Xia Liu(刘红侠)2, Peng-Fei Xie(谢鹏飞)1, Yuan-Tao Zhang(张袁涛)1, Qing-Liang Liao(廖清良)1   

  1. 1. School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China;
    2. School of Microelectronics, Key Laboratory of Wide Band-Gap Semiconductor Materials and Devices, Xidian University, Xi'an 710071, China
  • Received:2015-07-11 Revised:2015-09-28 Online:2016-02-05 Published:2016-02-05
  • Contact: Ji-Bin Fan E-mail:jbfan@chd.edu.cn

摘要: High-κ/Ge gate stack has recently attracted a great deal of attention as a potential candidate to replace planar silicon transistors for sub-22 generation. However, the desorption and volatilization of GeO hamper the development of Ge-based devices. To cope with this challenge, various techniques have been proposed to improve the high-κ/Ge interface. However, these techniques have not been developed perfectly yet to control the interface. Therefore, in this paper, we propose an improved stress relieved pre-oxide (SRPO) method to improve the thermodynamic stability of the high-κ/Ge interface. The x-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) results indicate that the GeO volatilization of the high-κ/Ge gate stack is efficiently suppressed after 500 ℃ annealing, and the electrical characteristics are greatly improved.

关键词: high-κfilm, GeO volatilization, stress relieved pre-oxide, annealing

Abstract: High-κ/Ge gate stack has recently attracted a great deal of attention as a potential candidate to replace planar silicon transistors for sub-22 generation. However, the desorption and volatilization of GeO hamper the development of Ge-based devices. To cope with this challenge, various techniques have been proposed to improve the high-κ/Ge interface. However, these techniques have not been developed perfectly yet to control the interface. Therefore, in this paper, we propose an improved stress relieved pre-oxide (SRPO) method to improve the thermodynamic stability of the high-κ/Ge interface. The x-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) results indicate that the GeO volatilization of the high-κ/Ge gate stack is efficiently suppressed after 500 ℃ annealing, and the electrical characteristics are greatly improved.

Key words: high-κfilm, GeO volatilization, stress relieved pre-oxide, annealing

中图分类号: 

  • 77.55.D-
82.80.Pv (Electron spectroscopy (X-ray photoelectron (XPS), Auger electron spectroscopy (AES), etc.))