中国物理B ›› 2004, Vol. 13 ›› Issue (12): 2169-2173.doi: 10.1088/1009-1963/13/12/034

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇    下一篇

Raman properties of GaSb nanoparticles embedded in SiO2 films

刘发民1, 王天民1, 张立德2   

  1. (1)Department of Applied Physics, Centre of Materials Physics and Chemistry, School of Science, Beijing University of Aeronautics & Astronautics, Beijing 100083, China; (2)Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China
  • 收稿日期:2004-03-04 修回日期:2004-06-23 出版日期:2004-12-20 发布日期:2004-12-20
  • 基金资助:
    Project supported by the Aeronautics Science Foundation of China (Grant No 03G51069).

Raman properties of GaSb nanoparticles embedded in SiO2 films

Liu Fa-Min (刘发民)a, Wang Tian-Min (王天民)a, Zhang Li-De (张立德)b   

  1. a Department of Applied Physics, Centre of Materials Physics and Chemistry, School of Science, Beijing University of Aeronautics & Astronautics, Beijing 100083, China; b Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China
  • Received:2004-03-04 Revised:2004-06-23 Online:2004-12-20 Published:2004-12-20
  • Supported by:
    Project supported by the Aeronautics Science Foundation of China (Grant No 03G51069).

摘要: The Raman shifts of nanocrystalline GaSb excited by an Ar^{+} ion laser at wavelengths 514.5, 496.5, 488.0, 476.5, and 457.9nm are studied by an SPEX-1403 laser Raman spectrometer respectively, and they are explained by phonon confinement, tensile stress, resonant Raman scattering and quantum size effects. The Stokes and anti-Stokes Raman spectra of GaSb nanocrystals strongly support the Raman feature of GaSb nanocrystals. The calculated optical spectra compare well with experimental data on Raman scattering GaSb nanocrystals.

Abstract: The Raman shifts of nanocrystalline GaSb excited by an Ar^{+} ion laser at wavelengths 514.5, 496.5, 488.0, 476.5, and 457.9nm are studied by an SPEX-1403 laser Raman spectrometer respectively, and they are explained by phonon confinement, tensile stress, resonant Raman scattering and quantum size effects. The Stokes and anti-Stokes Raman spectra of GaSb nanocrystals strongly support the Raman feature of GaSb nanocrystals. The calculated optical spectra compare well with experimental data on Raman scattering GaSb nanocrystals.

Key words: GaSb nanocrystals, novel Raman properties, phonon confinement and tensile stress effects

中图分类号:  (III-V and II-VI semiconductors)

  • 78.30.Fs
78.67.Bf (Nanocrystals, nanoparticles, and nanoclusters) 78.66.Fd (III-V semiconductors)