›› 2014, Vol. 23 ›› Issue (11): 117702-117702.doi: 10.1088/1674-1056/23/11/117702

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇    下一篇

Analysis of flatband voltage shift of metal/high-k/SiO2/Si stack based on energy band alignment of entire gate stack

韩锴a, 王晓磊b, 徐永贵a, 杨红b, 王文武b   

  1. a Department of Physics and Electronic Science, Weifang University, Weifang 261061, China;
    b Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China
  • 收稿日期:2014-04-03 修回日期:2014-05-28 出版日期:2014-11-15 发布日期:2014-11-15
  • 基金资助:
    Project supported by the National Natural Science of China (Grant Nos. 61176091 and 50932001).

Analysis of flatband voltage shift of metal/high-k/SiO2/Si stack based on energy band alignment of entire gate stack

Han Kai (韩锴)a, Wang Xiao-Lei (王晓磊)b, Xu Yong-Gui (徐永贵)a, Yang Hong (杨红)b, Wang Wen-Wu (王文武)b   

  1. a Department of Physics and Electronic Science, Weifang University, Weifang 261061, China;
    b Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China
  • Received:2014-04-03 Revised:2014-05-28 Online:2014-11-15 Published:2014-11-15
  • Contact: Han Kai E-mail:hankai@wfu.edu.cn
  • Supported by:
    Project supported by the National Natural Science of China (Grant Nos. 61176091 and 50932001).

摘要: A theoretical model of flatband voltage (VFB) of metal/high-k/SiO2/Si stack is proposed based on band alignment of entire gate stack, i.e., the VFB is obtained by simultaneously considering band alignments of metal/high-k, high-k/SiO2 and SiO2/Si interfaces, and their interactions. Then the VFB of TiN/HfO2/SiO2/Si stack is experimentally obtained and theoretically investigated by this model. The theoretical calculations are in good agreement with the experimental results. Furthermore, both positive VFB shift of TiN/HfO2/SiO2/Si stack and Fermi level pinning are successfully interpreted and attributed to the dielectric contact induced gap states at TiN/HfO2 and HfO2/SiO2 interfaces.

关键词: metal gate, high-k dielectric, band alignment, Vfb shift

Abstract: A theoretical model of flatband voltage (VFB) of metal/high-k/SiO2/Si stack is proposed based on band alignment of entire gate stack, i.e., the VFB is obtained by simultaneously considering band alignments of metal/high-k, high-k/SiO2 and SiO2/Si interfaces, and their interactions. Then the VFB of TiN/HfO2/SiO2/Si stack is experimentally obtained and theoretically investigated by this model. The theoretical calculations are in good agreement with the experimental results. Furthermore, both positive VFB shift of TiN/HfO2/SiO2/Si stack and Fermi level pinning are successfully interpreted and attributed to the dielectric contact induced gap states at TiN/HfO2 and HfO2/SiO2 interfaces.

Key words: metal gate, high-k dielectric, band alignment, Vfb shift

中图分类号: 

  • 77.55.D-
73.40.Qv (Metal-insulator-semiconductor structures (including semiconductor-to-insulator)) 73.20.At (Surface states, band structure, electron density of states)