ALSS: Apparatus for the loading of sublimable systems

doi:10.1088/1674-1056/ae60f2

中国物理B ›› 2026, Vol. 35 ›› Issue (7): 70703-070703.doi: 10.1088/1674-1056/ae60f2

ALSS: Apparatus for the loading of sublimable systems

Yuchen Ye(叶育辰)¹, Huixin Hu(胡蕙昕)¹, Jin Zhang(张锦)¹, Francesco Capitani², Mario Santoro^3,4,†, Federico Gorelli^1,5,3,4,‡, and Philip Dalladay-Simpson^1,§

1 Center for High Pressure Science Technology Advanced Research, Shanghai 201203, China;
2 SOLEIL, L'Orme des Mérisiers, Departementale 128, 91192 Saint-Aubin, France;
3 Instituto Nazionale di Ottica, Consiglio Nazionale delle Ricerche (CNR-INO), 50019 Sesto Fiorentino, Italy;
4 European Laboratory for Non Linear Spectroscopy (LENS), 50019 Sesto Fiorentino, Italy;
5 Shanghai Advanced Research in Physical Sciences (SHARPS), Shanghai 201210, China

收稿日期:2026-03-23 修回日期:2026-04-15 接受日期:2026-04-17 发布日期:2026-07-10
通讯作者: Mario Santoro, Federico Gorelli, Philip Dalladay-Simpson E-mail:santoro@lens.unifi.it;federico.gorelli@hpstar.ac.cn;philip.dalladay-simpson@hpstar.ac.cn
基金资助:
The authors acknowledge SOLEIL synchrotron and the SMIS beamline for their support during the experiments conducted under proposal 20240376. P. D-S. acknowledges the support of the National Natural Science Foundation of China (Grant No. W2532012).

ALSS: Apparatus for the loading of sublimable systems

Yuchen Ye(叶育辰)¹, Huixin Hu(胡蕙昕)¹, Jin Zhang(张锦)¹, Francesco Capitani², Mario Santoro^3,4,†, Federico Gorelli^1,5,3,4,‡, and Philip Dalladay-Simpson^1,§

1 Center for High Pressure Science Technology Advanced Research, Shanghai 201203, China;
2 SOLEIL, L'Orme des Mérisiers, Departementale 128, 91192 Saint-Aubin, France;
3 Instituto Nazionale di Ottica, Consiglio Nazionale delle Ricerche (CNR-INO), 50019 Sesto Fiorentino, Italy;
4 European Laboratory for Non Linear Spectroscopy (LENS), 50019 Sesto Fiorentino, Italy;
5 Shanghai Advanced Research in Physical Sciences (SHARPS), Shanghai 201210, China

Received:2026-03-23 Revised:2026-04-15 Accepted:2026-04-17 Published:2026-07-10
Contact: Mario Santoro, Federico Gorelli, Philip Dalladay-Simpson E-mail:santoro@lens.unifi.it;federico.gorelli@hpstar.ac.cn;philip.dalladay-simpson@hpstar.ac.cn
Supported by:
The authors acknowledge SOLEIL synchrotron and the SMIS beamline for their support during the experiments conducted under proposal 20240376. P. D-S. acknowledges the support of the National Natural Science Foundation of China (Grant No. W2532012).

摘要/Abstract

摘要： A system for the loading of sublimable systems at 0 ℃ into a versatile membrane/screw-actuated symmetric diamond anvil cell (DAC) has been developed. This system, known as the Apparatus for the Loading of Sublimable Systems (ALSS), has the unique incorporation of an internal membrane, which acts against the clamping force of the screws. Through the inflation/deflation of the internal membrane, it is possible to open and close the cell under a pressurized environment without the need to maintain pressure differentials and/or high-pressure mechanical feedthroughs. Here, we present an overview of ALSS and its application in loading sulfur hexafluoride (SF₆) and carbon dioxide (CO₂), including the first infrared absorption measurements of SF₆ up to 50 GPa.

关键词: diamond anvil cell (DAC), apparatus for the loading of sublimable systems (ALSS)

Abstract: A system for the loading of sublimable systems at 0 ℃ into a versatile membrane/screw-actuated symmetric diamond anvil cell (DAC) has been developed. This system, known as the Apparatus for the Loading of Sublimable Systems (ALSS), has the unique incorporation of an internal membrane, which acts against the clamping force of the screws. Through the inflation/deflation of the internal membrane, it is possible to open and close the cell under a pressurized environment without the need to maintain pressure differentials and/or high-pressure mechanical feedthroughs. Here, we present an overview of ALSS and its application in loading sulfur hexafluoride (SF₆) and carbon dioxide (CO₂), including the first infrared absorption measurements of SF₆ up to 50 GPa.

Key words: diamond anvil cell (DAC), apparatus for the loading of sublimable systems (ALSS)

中图分类号: (High-pressure apparatus; shock tubes; diamond anvil cells)

07.35.+k

91.60.Gf (High-pressure behavior) 92.60.hv (Pressure, density, and temperature) 62.50.-p (High-pressure effects in solids and liquids)

Yuchen Ye(叶育辰), Huixin Hu(胡蕙昕), Jin Zhang(张锦), Francesco Capitani, Mario Santoro, Federico Gorelli, and Philip Dalladay-Simpson. ALSS: Apparatus for the loading of sublimable systems[J]. 中国物理B, 2026, 35(7): 70703-070703.

参考文献

[1] Dalladay-Simpson P, Monserrat B, Zhang L and Gorelli F 2024 Matter and Radiation at Extremes 9 028401
[2] Dalladay-Simpson P, Binns J, Pena-Alvarez M, Donnelly M E, Green- berg E, Prakapenka V, Chen X J, Gregoryanz E and Howie R T 2019 Nat. Commun. 10 1134
[3] Binns J, Hermann A, Pena-Alvarez M, Donnelly M E, Wang M, Kawaguchi S I, Gregoryanz E, Howie R T and Dalladay-Simpson P 2021 Sci. Adv. 7
[4] Ma Y, Eremets M, Oganov A R, Xie Y, Trojan I, Medvedev S, Lyakhov A O, Valle M and Prakapenka V 2009 Nature 458 182
[5] Gorelli F A, Dalladay-Simpson P, Garbarino G, Mezouar M, Haines J and Santoro M 2025 Phys. Rev. Lett. 135 076101
[6] Zhang H, Dalladay-simpson P, Santoro M, Gorelli F A, Capitani F, Ji C and Zhang L 2025 Commun. Chem. 8 374
[7] Dalladay-Simpson P, Howie R T and Gregoryanz E 2016 Nature 529 63
[8] Santoro M, Gorelli F A, Bini R, Ruocco G, Scandolo S and Crichton W A 2006 Nature 441 857
[9] Ashcroft N W 2004 Phys. Rev. Lett. 92 187002
[10] Drozdov A P, Kong P P, Minkov V S, Besedin S P, Kuzovnikov M A, Mozaffari S, Balicas L, Balakirev F F, Graf D E, Prakapenka V B, Greenberg E, Knyazev D A, Tkacz M and Eremets M I 2019 Nature 569 528
[11] Drozdov A P, Eremets M I, Troyan I A, Ksenofontov V and Shylin S I 2015 Nature 525 73
[12] Dewaele A, Loubeyre P, Occelli F, Marie O and Mezouar M 2018 Nat. Commun. 9 2913
[13] Dalladay-Simpson P, Capitani F and Gorelli F A 2025 Phys. Rev. B 112 014102
[14] Rivers M, Prakapenka V B, Kubo A, Pullins C, Holl C M and Jacobsen S D 2008 High Pressure Research 28 273
[15] Kurnosov A, Kantor I, Boffa-Ballaran T, Lindhardt S, Dubrovinsky L, Kuznetsov A and Zehnder B H 2008 Rev. Sci. Instrum. 79 045110
[16] Edmund E, Dalsaniya M H, Howie R T, Greenberg E, Prakapenka V B, Pena Alvarez M, Hanfland M, Dalladay-Simpson P, Kurzydłowski D and Hermann A 2025 Phys. Rev. B 112 134101
[17] Scelta D, Ceppatelli M, Ballerini R, Hajeb A, Peruzzini M and Bini R 2018 Rev. Sci. Instrum. 89
[18] Baggen M, Manuputy R, Scheltema R and Lagendijk A 1988 Rev. Sci. Instrum. 59 2592
[19] An M, Prinn R G, Western L M, Zhao X, Yao B, Hu J, Ganesan A L, Muhle J, Weiss R F, Krummel P B, O’Doherty S, Young D and Rigby M 2024 Nat. Commun. 15 1
[20] Hurly J J, Defibaugh D R and Moldover M R 2000 International Journal of Thermophysics 21 739
[21] Kovacs T, Feng W, Totterdill A, Plane J M, Dhomse S, G omez-Mart ín J C, Stiller G P, Haenel F J, Smith C, Forster P M, García R R, Marsh D R and Chipperfield M P 2017 Atmospheric Chemistry and Physics 17 883
[22] Frost M, Kuzovnikov M A, Dalladay-simpson P, Howie R T, Loveday J S, Ranieri U and Gregoryanz E 2025 Commun. Chem. 8 128
[23] Letoullec R, Pinceaux J P and Loubeyre P 1988 High Pressure Research 1 77
[24] Shen G, Wang Y, Dewaele A, Wu C, Fratanduono D E, Eggert J, Klotz S, Dziubek K F, Loubeyre P, Fat’yanov O V, Asimow P D, Mashimo T and Wentzcovitch R M 2020 High Pressure Research 40 299
[25] Datchi F, Dewaele A, Loubeyre P, Letoullec R, Le Godec Y and Canny B 2007 High Pressure Research 27 447
[26] Akahama Y and Kawamura H 2006 J. Appl. Phys. 100
[27] Goncharov A F, Bykova E, Bykov M, Edmund E, Smith J S, Chariton S and Prakapenka V B 2023 Phys. Rev. Mater. 7 053604
[28] Sode O, Keçeli M, Yagi K and Hirata S 2013 J. Chem. Phys. 138 074501
[29] Span R and Wagner W 1996 Journal of Physical and Chemical Reference Data 25 1509
[30] Li J, Chen Y, Ke T, Jin Y, Fan R, Xu G, Yang L, Zhang Z, Bao Z, Ren Q and Yang Q 2025 Nat. Commun. 16 632
[31] Dyadin Y A, Larionov E G, Manakov A Y, Kurnosov A V, Zhurko F V, Aladko E Y, Ancharov A I, Tolochko B P and Sheromov M A 2002 Journal of Inclusion Phenomena 42 213
[32] Cockcroft J K and Fitch A N 1988 Zeitschrift fur Kristallographie - Crystalline Materials 184 123
[33] Stewart J W 1962 J. Chem. Phys. 36 400
[34] Sasaki S, Tomida Y and Shimizu H 1992 J. Phys. Soc. Jpn. 61 514
[35] Rademacher N, Friedrich A, Morgenroth W, Bayarjargal L, Milman V and Winkler B 2015 Journal of Physics and Chemistry of Solids 80 11

ALSS: Apparatus for the loading of sublimable systems

ALSS: Apparatus for the loading of sublimable systems

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Yadong Li(李亚东), Minghui Jin(金明辉), Lang Xie(谢浪), Wenjing Huang(黄文静), Qing Zhang(张庆), Liangchao Chen(陈良超), Chao Fang(房超), Rui Wang(王睿), and Chunlei Du(杜春雷). Influence mechanism of temperature fluctuation on the growth of adjunct diamond under HPHT conditions[J]. 中国物理B, 2026, 35(6): 68101-068101.
[2]	Hanyu Wang(王瀚宇), Shujuan Xu(许淑娟), Xinyao Wang(汪心瑶), Kai Zhang (张凯), Liangjian Zou(邹良剑), and Fuhai Su(苏付海). Ultrafast photocarrier dynamics of black phosphorus under pressure[J]. 中国物理B, 2026, 35(5): 56301-056301.
[3]	Liyan Wang(汪礼艳), Di Peng(彭帝), Yuchen Cui(崔雨晨), Yiming Wang(王弈铭), Jingxin Gao(高景鑫), Tao Luo(罗涛), Zhikai Zhu(朱智凯), Kejun Bu(卜克军), Yuzhu Wang(王玉柱), Sibo Zhan(展思博), Jikun Chen(陈吉堃), Huaqing Xie(谢华清), Zihua Wu(吴子华), Hongliang Dong(董洪亮), and Zhidan Zeng(曾徵丹). Structure and transport properties of HoNiO₃ under high pressure[J]. 中国物理B, 2026, 35(5): 57103-057103.
[4]	Lun Xiong(熊伦), Mingquan Jiang(江明全), Jinxia Zhu(竹锦霞), Lin Xia(夏林), Hao Wang(王毫), Shenghan Zhang(张升瀚), Pengfei Tang(汤鹏飞), Zhiqiang Chen(陈志强), Sheng Jiang(蒋升), and Hongliang Dong(董洪亮). Physical properties of Cr₂S₃ at high pressure[J]. 中国物理B, 2026, 35(3): 36103-036103.
[5]	Mengqiong Pu(蒲梦琼), Jiacheng Zhang(张家诚), Xinyang Li(李新阳), Xiaomei Yuan(苑晓美), Xue Zhang(张雪), Shuo Gao(高硕), Chenlu Wang(王晨璐), Liang Li(李亮), Fangfei Li(李芳菲), and Qiang Zhou(周强). Elasticity of quasi-bcc ammonia hemihydrate at high pressures[J]. 中国物理B, 2026, 35(3): 36101-036101.
[6]	Guoshuai Du(杜国帅), Yubing Du(杜玉冰), Jiaxin Ming(明嘉欣), Zhixi Zhu(朱芷希), Jiaohui Yan(闫皎辉), Jiayin Li(李嘉荫), Tiansong Zhang(张天颂), Lina Yang(杨哩娜), Ke Jin(靳柯), and Yabin Chen(陈亚彬). Tunable thermal conductivity and mechanical properties of metastable silicon by phase engineering[J]. 中国物理B, 2025, 34(9): 96401-096401.
[7]	Boyang Fu(符博洋), Wenfeng Zhou(周文风), Fuyang Liu(刘扶阳), Luhong Wang(王鲁红), Haozhe Liu(刘浩哲), Sheng-Ping Guo(郭胜平), and Weizhao Cai(蔡伟照). Structural evolution and bandgap modification of a robust mixed-valence compound Eu₉MgS₂B₂₀O₄₁ under pressure[J]. 中国物理B, 2025, 34(8): 86102-086102.
[8]	Chaofan Lv(吕超凡), Kai Ma(马凯), Feihu Lei(雷飞虎), Yidan Qu(屈怡丹), Qilong Wu(吴琦隆), Wuyou Zhang(张吾优), Yingjie Zhang(张英杰), Huihui Yu(余辉辉), Xuanming Shen(申炫铭), Yuan Zhang(张元), Xigui Yang(杨西贵), and Chongxin Shan(单崇新). Pressure distribution imaging through wide-field optical detected magnetic resonance[J]. 中国物理B, 2025, 34(8): 87601-087601.
[9]	Xiangjiang Dong(董祥江), Bowen Zhang(张博文), Xubin Ye(叶旭斌), Peng Wei(魏鹏), Lei Lian(廉磊), Ning Sun(孙宁), Youwen Long(龙有文), Shangjie Tian(田尚杰), Shouguo Wang(王守国), Hechang Lei(雷和畅), and Runze Yu(于润泽). High pressure growth of transition-metal monosilicide RhGe single crystals[J]. 中国物理B, 2025, 34(8): 88101-088101.
[10]	Jian Zhu(朱健), Dengman Feng(冯登满), Liangyu Wang(王亮予), Liang Li(李亮), Fangfei Li(李芳菲), Qiang Zhou(周强), and Yalan Yan(闫雅兰). Layer-dependent structural stability and electronic properties of CrPS₄ under high pressure[J]. 中国物理B, 2025, 34(6): 66102-066102.
[11]	Minghao Du(杜明浩) and Duanwei He(贺端威). Gas encapsulation technology for large volume press[J]. 中国物理B, 2024, 33(11): 110701-110701.
[12]	Jiajun Chen(陈佳骏), Xindeng Lv(吕心邓), Simin Li(李思敏), Yaqian Dan(但雅倩), Yanping Huang(黄艳萍), and Tian Cui(崔田). Unveiling the pressure-driven metal-semiconductor-metal transition in the doped TiS₂[J]. 中国物理B, 2024, 33(6): 67104-067104.
[13]	Guofeng Huang(黄国锋), Liangchao Chen(陈良超), and Chao Fang(房超). Synthesis and nitrogen content regulation of diamond in a high-pressure hydrogen-rich environment[J]. 中国物理B, 2024, 33(6): 68102-068102.
[14]	Yunfeng Wang(王云峰), Shujuan Xu(许淑娟), Jin Yang(杨金), and Fuhai Su(苏付海). Probing photocarrier dynamics of pressurized graphene using time-resolved terahertz spectroscopy[J]. 中国物理B, 2023, 32(6): 67802-067802.
[15]	Lun Xiong(熊伦), Bin Li(李斌), Fang Miao(苗芳), Qiang Li (李强), Guangping Chen(陈光平), Jinxia Zhu(竹锦霞), Yingchun Ding(丁迎春), and Duanwei He(贺端威). Equal compressibility structural phase transition of molybdenum at high pressure[J]. 中国物理B, 2022, 31(11): 116102-116102.