中国物理B ›› 2023, Vol. 32 ›› Issue (8): 87106-087106.doi: 10.1088/1674-1056/acd5c3

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Saturation thickness of stacked SiO2 in atomic-layer-deposited Al2O3 gate on 4H-SiC

Zewei Shao(邵泽伟)1,2,†, Hongyi Xu(徐弘毅)1,2,†, Hengyu Wang(王珩宇)1,‡, Na Ren(任娜)1,2, and Kuang Sheng(盛况)1   

  1. 1. College of Electrical Engineering, Zhejiang University, Hangzhou 310063, China;
    2. Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311215, China
  • 收稿日期:2023-02-25 修回日期:2023-05-11 出版日期:2023-07-14 发布日期:2023-07-24
  • 通讯作者: Hengyu Wang E-mail:wanghengyu@zju.edu.cn
  • 基金资助:
    Project supported by the Key Area Research and Development Program of Guangdong Province of China (Grant No.2021B0101300005) and the National Key Research and Development Program of China (Grant No.2021YFB3401603).

Saturation thickness of stacked SiO2 in atomic-layer-deposited Al2O3 gate on 4H-SiC

Zewei Shao(邵泽伟)1,2,†, Hongyi Xu(徐弘毅)1,2,†, Hengyu Wang(王珩宇)1,‡, Na Ren(任娜)1,2, and Kuang Sheng(盛况)1   

  1. 1. College of Electrical Engineering, Zhejiang University, Hangzhou 310063, China;
    2. Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311215, China
  • Received:2023-02-25 Revised:2023-05-11 Online:2023-07-14 Published:2023-07-24
  • Supported by:
    Project supported by the Key Area Research and Development Program of Guangdong Province of China (Grant No.2021B0101300005) and the National Key Research and Development Program of China (Grant No.2021YFB3401603).

摘要: High-k materials as an alternative dielectric layer for SiC power devices have the potential to reduce interfacial state defects and improve MOS channel conduction capability. Besides, under identical conditions of gate oxide thickness and gate voltage, the high-k dielectric enables a greater charge accumulation in the channel region, resulting in a larger number of free electrons available for conduction. However, the lower energy band gap of high-k materials leads to significant leakage currents at the interface with SiC, which greatly affects device reliability. By inserting a layer of SiO2 between the high-k material and SiC, the interfacial barrier can be effectively widened and hence the leakage current will be reduced. In this study, the optimal thickness of the intercalated SiO2 was determined by investigating and analyzing the gate dielectric breakdown voltage and interfacial defects of a dielectric stack composed of atomic-layer-deposited Al2O3 layer and thermally nitride SiO2. Current-voltage and high-frequency capacitance-voltage measurements were performed on metal-oxide-semiconductor test structures with 35 nm thick Al2O3 stacked on 1 nm, 2 nm, 3 nm, 6 nm, or 9 nm thick nitride SiO2. Measurement results indicated that the current conducted through the oxides was affected by the thickness of the nitride oxide and the applied electric field. Finally, a saturation thickness of stacked SiO2 that contributed to dielectric breakdown and interfacial band offsets was identified. The findings in this paper provide a guideline for the SiC gate dielectric stack design with the breakdown strength and the interfacial state defects considered.

关键词: 4H-SiC, SiO2/Al2O3 stacks, saturation thickness, dielectric breakdown

Abstract: High-k materials as an alternative dielectric layer for SiC power devices have the potential to reduce interfacial state defects and improve MOS channel conduction capability. Besides, under identical conditions of gate oxide thickness and gate voltage, the high-k dielectric enables a greater charge accumulation in the channel region, resulting in a larger number of free electrons available for conduction. However, the lower energy band gap of high-k materials leads to significant leakage currents at the interface with SiC, which greatly affects device reliability. By inserting a layer of SiO2 between the high-k material and SiC, the interfacial barrier can be effectively widened and hence the leakage current will be reduced. In this study, the optimal thickness of the intercalated SiO2 was determined by investigating and analyzing the gate dielectric breakdown voltage and interfacial defects of a dielectric stack composed of atomic-layer-deposited Al2O3 layer and thermally nitride SiO2. Current-voltage and high-frequency capacitance-voltage measurements were performed on metal-oxide-semiconductor test structures with 35 nm thick Al2O3 stacked on 1 nm, 2 nm, 3 nm, 6 nm, or 9 nm thick nitride SiO2. Measurement results indicated that the current conducted through the oxides was affected by the thickness of the nitride oxide and the applied electric field. Finally, a saturation thickness of stacked SiO2 that contributed to dielectric breakdown and interfacial band offsets was identified. The findings in this paper provide a guideline for the SiC gate dielectric stack design with the breakdown strength and the interfacial state defects considered.

Key words: 4H-SiC, SiO2/Al2O3 stacks, saturation thickness, dielectric breakdown

中图分类号:  (II-VI semiconductors)

  • 71.55.Gs
68.55.jd (Thickness) 77.22.Jp (Dielectric breakdown and space-charge effects)