Infrared light-emitting diodes based on colloidal PbSe/PbS core/shell nanocrystals

doi:10.1088/1674-1056/ab5fb7

中国物理B ›› 2020, Vol. 29 ›› Issue (1): 18503-018503.doi: 10.1088/1674-1056/ab5fb7

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

Infrared light-emitting diodes based on colloidal PbSe/PbS core/shell nanocrystals

Byung-Ryool Hyun, Mikita Marus, Huaying Zhong(钟华英), Depeng Li(李德鹏), Haochen Liu(刘皓宸), Yue Xie(谢阅), Weon-kyu Koh, Bing Xu(徐冰), Yanjun Liu(刘言军), Xiao Wei Sun(孙小卫)

1 Guangdong University Key Laboratory for Advanced Quantum Dot Displays and Lighting, Shenzhen Key Laboratory for Advanced Quantum Dot Displays and Lighting, Department of Electrical&Electronic Engineering, Southern University of Science and Technology, Shenzhen 518055, China;
2 School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore;
3 Shenzhen Planck Innovation Technologies Co. Ltd, Shenzhen 518112, China

收稿日期:2019-10-16 修回日期:2019-11-26 出版日期:2020-01-05 发布日期:2020-01-05
通讯作者: Xiao Wei Sun E-mail:sunxw@sustech.edu.cn
基金资助:
Project supported by the National Key Research and Development Program of China (Grant No. 2016YFB0401702), the National Natural Science Foundation of China (Grant Nos. 61674074 and 61405089), Development and Reform Commission of Shenzhen Project, China (Grant No. [2017]1395), Shenzhen Peacock Team Project, China (Grant No. KQTD2016030111203005), Shenzhen Key Laboratory for Advanced Quantum Dot Displays and Lighting, China (Grant No. ZDSYS201707281632549), Guangdong Province's Key R&D Program: Micro-LED Display and Ultra-high Brightness Micro-display Technology, China (Grant No. 2019B010925001), Guangdong University Key Laboratory for Advanced Quantum Dot Displays and Lighting, China (Grant No. 2017KSYS007), and Distinguished Young Scholar of National Natural Science Foundation of Guangdong, China (Grant No. 2017B030306010). We thank the start-up fund from Southern University of Science and Technology, Shenzhen, China.

Infrared light-emitting diodes based on colloidal PbSe/PbS core/shell nanocrystals

Byung-Ryool Hyun¹, Mikita Marus¹, Huaying Zhong(钟华英)¹, Depeng Li(李德鹏)¹, Haochen Liu(刘皓宸)¹, Yue Xie(谢阅)¹, Weon-kyu Koh², Bing Xu(徐冰)^1,3, Yanjun Liu(刘言军)¹, Xiao Wei Sun(孙小卫)^1,3

1 Guangdong University Key Laboratory for Advanced Quantum Dot Displays and Lighting, Shenzhen Key Laboratory for Advanced Quantum Dot Displays and Lighting, Department of Electrical&Electronic Engineering, Southern University of Science and Technology, Shenzhen 518055, China;
2 School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore;
3 Shenzhen Planck Innovation Technologies Co. Ltd, Shenzhen 518112, China

Received:2019-10-16 Revised:2019-11-26 Online:2020-01-05 Published:2020-01-05
Contact: Xiao Wei Sun E-mail:sunxw@sustech.edu.cn
Supported by:
Project supported by the National Key Research and Development Program of China (Grant No. 2016YFB0401702), the National Natural Science Foundation of China (Grant Nos. 61674074 and 61405089), Development and Reform Commission of Shenzhen Project, China (Grant No. [2017]1395), Shenzhen Peacock Team Project, China (Grant No. KQTD2016030111203005), Shenzhen Key Laboratory for Advanced Quantum Dot Displays and Lighting, China (Grant No. ZDSYS201707281632549), Guangdong Province's Key R&D Program: Micro-LED Display and Ultra-high Brightness Micro-display Technology, China (Grant No. 2019B010925001), Guangdong University Key Laboratory for Advanced Quantum Dot Displays and Lighting, China (Grant No. 2017KSYS007), and Distinguished Young Scholar of National Natural Science Foundation of Guangdong, China (Grant No. 2017B030306010). We thank the start-up fund from Southern University of Science and Technology, Shenzhen, China.

摘要/Abstract

摘要： Colloidal PbSe nanocrystals (NCs) have gained considerable attention due to their efficient carrier multiplication and emissions across near-infrared and short-wavelength infrared spectral ranges. However, the fast degradation of colloidal PbSe NCs in ambient conditions hampers their widespread applications in infrared optoelectronics. It is well-known that the inorganic thick-shell over core improves the stability of NCs. Here, we present the synthesis of PbSe/PbS core/shell NCs showing wide spectral tunability, in which the molar ratio of lead (Pb) and sulfur (S) precursors, and the concentration of sulfur and PbSe NCs in solvent have a significant effect on the efficient PbS shell growth. The infrared light-emitting diodes (IR-LEDs) fabricated with the PbSe/PbS core/shell NCs exhibit an external quantum efficiency (EQE) of 1.3% at 1280 nm. The ligand exchange to optimize the distance between NCs and chloride treatment are important processes for achieving high performance on PbSe/PbS NC-LEDs. Our results provide evidence for the promising potential of PbSe/PbS NCs over the wide range of infrared optoelectronic applications.

关键词: PbSe/PbS core/shell nanocrystal, ligand exchange, infrared light-emitting diodes, external quantum efficiency

Abstract: Colloidal PbSe nanocrystals (NCs) have gained considerable attention due to their efficient carrier multiplication and emissions across near-infrared and short-wavelength infrared spectral ranges. However, the fast degradation of colloidal PbSe NCs in ambient conditions hampers their widespread applications in infrared optoelectronics. It is well-known that the inorganic thick-shell over core improves the stability of NCs. Here, we present the synthesis of PbSe/PbS core/shell NCs showing wide spectral tunability, in which the molar ratio of lead (Pb) and sulfur (S) precursors, and the concentration of sulfur and PbSe NCs in solvent have a significant effect on the efficient PbS shell growth. The infrared light-emitting diodes (IR-LEDs) fabricated with the PbSe/PbS core/shell NCs exhibit an external quantum efficiency (EQE) of 1.3% at 1280 nm. The ligand exchange to optimize the distance between NCs and chloride treatment are important processes for achieving high performance on PbSe/PbS NC-LEDs. Our results provide evidence for the promising potential of PbSe/PbS NCs over the wide range of infrared optoelectronic applications.

Key words: PbSe/PbS core/shell nanocrystal, ligand exchange, infrared light-emitting diodes, external quantum efficiency

中图分类号: (Light-emitting devices)

85.60.Jb

85.60.Bt (Optoelectronic device characterization, design, and modeling) 61.46.Df (Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots)) 61.46.Hk (Nanocrystals)

Byung-Ryool Hyun, Mikita Marus, 钟华英, 李德鹏, 刘皓宸, 谢阅, Weon-kyu Koh, 徐冰, 刘言军, 孙小卫. Infrared light-emitting diodes based on colloidal PbSe/PbS core/shell nanocrystals[J]. 中国物理B, 2020, 29(1): 18503-018503.

Byung-Ryool Hyun, Mikita Marus, Huaying Zhong(钟华英), Depeng Li(李德鹏), Haochen Liu(刘皓宸), Yue Xie(谢阅), Weon-kyu Koh, Bing Xu(徐冰), Yanjun Liu(刘言军), Xiao Wei Sun(孙小卫). Infrared light-emitting diodes based on colloidal PbSe/PbS core/shell nanocrystals[J]. Chin. Phys. B, 2020, 29(1): 18503-018503.

参考文献 70

[1]	Agis F G, Heide S V D, Okonkwo C, Tangidongga E and Koonen T 2017 43th European Conference on Optical Communication, September 17-21, 2017, Gothenburg, Sweden, p. 1
[2]	Sousa E, Vardasca R, Teixeira S, Seixas A, Mendes J and Costa-Ferreira A 2017 Phys. Technol. 85 315 doi: 10.1016/j.infrared.2017.07.020
[3]	Willer U, Saraji M, Khorsandi A, Geiser P and Schade W 2006 Opt. Lasers Eng. 44 699 doi: 10.1016/j.optlaseng.2005.04.015
[4]	Ionescu B, Suse V, Gadea C, Solomon B, Ionescu D, Islam S and Cordea M 2014 IEEE Lat. Am. Trans. 12 520 doi: 10.1109/TLA.2014.6827882
[5]	Thakur R 2018 Recent Development in Optoelectronic Devices (Rijeka: IntechOpen) ED1-Ruby Srivastava 2018, (Rijeka: IntechOpen) pp. 81-83
[6]	Lee W O, Lee H C, Cho C W, Gwon S Y, Park K R, Lee H and Cha J 2012 Opt. Express 51 1
[7]	Wise F W 2000 Acc. Chem. Res. 33 773 doi: 10.1021/ar970220q
[8]	Sun L, Choi J J, Stachnik D, Bartnik A C, Hyun B R, Malliaras G G, Hanrath T and Wise F W 2012 Nat. Nanotechnol. 7 369 doi: 10.1038/nnano.2012.63
[9]	Konstantatos G, Howard I, Fischer A, Hoogland S, Clifford J, Klem E, Levina L and Sargent E H 2006 Nature 442 180 doi: 10.1038/nature04855
[10]	Rauch T, Böberl M, Tedde S F, Fürst J, Kovalenko M V, Hesser G, Lemmer U, Heiss W and Hayden O 2009 Nat. Photon. 3 332 doi: 10.1038/nphoton.2009.72
[11]	Murray C, Sun S, Gaschler W, Doyle H, Betley T and Kagan C 2001 IBM J. Res. Dev. 45 47 doi: 10.1147/rd.451.0047
[12]	Hines M A and Scholes G D 2003 Adv. Mater. 15 1844 doi: 10.1002/adma.200305395
[13]	Pietryga J M, Schaller R D, Werder D, Stewart M H, Klimov V I and Hollingsworth J A 2004 J. Am. Chem. Soc. 126 11752 doi: 10.1021/ja047659f
[14]	Weidman M C, Beck M E, Hoffman R S, Prins F and Tisdale W A 2014 ACS Nano 8 6363 doi: 10.1021/nn5018654
[15]	Lee J W, Kim D Y, Baek S, Yu H and So F 2016 Small 12 1328 doi: 10.1002/smll.201503244
[16]	Campos M P, Hendricks M P, Beecher A N, Walravens W, Swain R A, Cleveland G T, Hens Z, Sfeir M Y and Owen J S 2017 J. Am. Chem. Soc. 139 2296 doi: 10.1021/jacs.6b11021
[17]	Čapek R K, Yanover D and Lifshitz E 2015 Nanoscale 7 5299 doi: 10.1039/C5NR00028A
[18]	Choi J J, Lim Y F, Santiago-Berrios M B, Oh M, Hyun B R, Sun L, Bartnik A C, Goedhart A, Malliaras G G, Abruña H D, Wise F W and Hanrath T 2009 Nano Lett. 9 3749 doi: 10.1021/nl901930g
[19]	Hyun B R, Zhong Y-Wu, Bartnik A C, Sun L, Abruña H D, Wise F W, Goodreau J D, Matthews J R, Leslie T M and Borrelli N F 2008 ACS Nano 2 2206 doi: 10.1021/nn800336b
[20]	Hyun B R, Choi J J, Seyler K L, Hanrath T and Wise F W 2013 ACS Nano 7 10938 doi: 10.1021/nn404457c
[21]	Kim G H, García de Arquer F P, Yoon Y J, Lan X, Liu M, Voznyy O, Yang Z, Fan F, Ip A H, Kanjanaboos P, Hoogland S, Kim J Y and Sargent E H 2015 Nano Lett. 15 7691 doi: 10.1021/acs.nanolett.5b03677
[22]	Supran G J, Song K W, Hwang G W, Correa R E, Scherer J, Dauler E A, Shirasaki Y, Bawendi M G and Bulović V 2015 Adv. Mater. 27 1437 doi: 10.1002/adma.201404636
[23]	Gong X, Yang Z, Walters G, Comin R, Ning Z, Beauregard E, Adinolfi V, Voznyy O and Sargent E H 2016 Nat. Photon. 10 253 doi: 10.1038/nphoton.2016.11
[24]	Yang X, Ren F, Wang Y, Ding T, Sun H, Ma D and Sun X W 2017 Sci. Rep. 7 14741 doi: 10.1038/s41598-017-15244-5
[25]	Pradhan S, Di Stasio F, Bi Y, Gupta S, Christodoulou S, Stavrinadis A and Konstantatos G 2019 Nat. Nanotechnol. 14 72 doi: 10.1038/s41565-018-0312-y
[26]	Dai Q, Wang Y, Zhang Y, Li X, Li R, Zou B, Seo J, Wang Y, Liu M and Yu W W 2009 Langmuir 25 12320 doi: 10.1021/la9015614
[27]	Leschkies K S, Kang M S, Aydil E S and Norris D J 2010 J. Phys. Chem. C 114 9988 doi: 10.1021/jp101695s
[28]	Chappell H E, Hughes B K, Beard M C, Nozik A J and Johnson J C 2011 J. Phys. Chem. Lett. 2 889 doi: 10.1021/jz2001979
[29]	Pietryga J M, Werder D J, Williams D J, Casson J L, Schaller R D, Klimov V I and Hollingsworth J A 2008 J. Am. Chem. Soc. 130 4879 doi: 10.1021/ja710437r
[30]	Brumer M, Kigel A, Amirav L, Sashchiuk A, Solomesch O, Tessler N and Lifshitz E 2005 Adv. Funct. Mater. 15 1111 doi: 10.1002/adfm.200400620
[31]	Jasieniak J, Califano M and Watkins S E 2011 ACS Nano 5 5888 doi: 10.1021/nn201681s
[32]	Kim S, Fisher B, Eisler H J and Bawendi M 2003 J. Am. Chem. Soc. 125 11466 doi: 10.1021/ja0361749
[33]	Bartnik A C, Wise F W, Kigel A and Lifshitz E 2007 Phys. Rev. B 75 245424 doi: 10.1103/PhysRevB.75.245424
[34]	Hyun B R, Zhong Y W, Bartnik A C, Sun L, Abruña H D, Wise F W, Goodreau J D, Matthews J R, Leslie T M and Borrelli N F 2008 ACS Nano 2 2206 doi: 10.1021/nn800336b
[35]	Lifshitz E, Vaxenburg R, Maikov G I, Yanover D, Brusilovski A, Tilchin J and Sashchiuk A 2011 (Cambridge: Elsevier) p. 181
[36]	García-Santamaría F, Chen Y, Vela J, Schaller R D, Hollingsworth J A and Klimov V I 2009 Nano Lett. 9 3482 doi: 10.1021/nl901681d
[37]	Chen Y, Vela J, Htoon H, Casson J L, Werder D J, Bussian D A, Klimov V I and Hollingsworth J A 2008 J. Am. Chem. Soc. 130 5026 doi: 10.1021/ja711379k
[38]	Anikeeva P O, Madigan C F, Halpert J E, Bawendi M G and Bulovic V 2008 Phys. Rev. B 78 085434 doi: 10.1103/PhysRevB.78.085434
[39]	Bae W K, Park Y S, Lim J, Lee D, Padilha L A, McDaniel H, Robel I, Lee C, Pietryga J M and Klimov V I 2013 Nat. Commun. 4 2661 doi: 10.1038/ncomms3661
[40]	Lim J, Park Y S and Klimov V I 2018 Nat. Mater. 17 42 doi: 10.1038/nmat5011
[41]	Shapiro A, Jang Y, Rubin-Brusilovski A, Budniak A K, Horani F, Sashchiuk A and Lifshitz E 2016 Chem. Mater. 28 6409 doi: 10.1021/acs.chemmater.6b02917
[42]	Pal B N, Ghosh Y, Brovelli S, Laocharoensuk R, Klimov V I, Hollingsworth J A and Htoon H 2012 Nano Lett. 12 331 doi: 10.1021/nl203620f
[43]	Lin Q, Makarov N S, Koh W, Velizhanin K A, Cirloganu C M, Luo H, Klimov V I and Pietryga J M 2015 ACS Nano 9 539 doi: 10.1021/nn505793y
[44]	Delin A, Ravindran P, Eriksson O and Wills J M 1998 Int. J. Quantum. Chem. 69 349 doi: 10.1002/(SICI)1097-461X(1998)69:3<349::AID-QUA13>3.0.CO;2-Y
[45]	Chen O, Zhao J, Chauhan V P, Cui J, Wong C, Harris D K, Wei H, Han H S, Fukumura D, Jain R K and Bawendi M G 2013 Nat. Mater. 12 445 doi: 10.1038/nmat3539
[46]	Moreels I, Lambert K, De Muynck D, Vanhaecke F, Poelman D, Martins J C, Allan G and Hens Z 2007 Chem. Mater. 19 6101 doi: 10.1021/cm071410q
[47]	Bartnik A C 2011 The Dependence Of Lead-Salt Nanocrystal Properties On Morphology And Dielectric Environment (Ph.D. Dissertation) (Ithaca: Cornell University)
[48]	Sashchiuk A, Yanover D, Rubin-Brusilovski A, Maikov G I, Čapek R K, Vaxenburg R, Tilchin J, Zaiats G and Lifshitz E 2013 Nanoscale 5 7724 doi: 10.1039/c3nr02141f
[49]	Jang Y, Shapiro A, Isarov M, Rubin-Brusilovski A, Safran A, Budniak A K, Horani F, Dehnel J, Sashchiuk A and Lifshitz E 2017 Chem. Commun. 53 1002 doi: 10.1039/C6CC08742F
[50]	Wehrenberg B L, Wang C and Guyot-Sionnest P 2002 J. Phys. Chem. B 106 10634 doi: 10.1021/jp021187e
[51]	Liu H and Guyot-Sionnest P 2010 J. Phys. Chem. C 114 14860
[52]	Semonin O E, Johnson J C, Luther J M, Midgett A G, Nozik A J and Beard M C 2010 J. Phys. Chem. Lett. 1 2445 doi: 10.1021/jz100830r
[53]	Lifshitz E 2015 J. Phys. Chem. Lett. 6 4336 doi: 10.1021/acs.jpclett.5b01567
[54]	Guyot-Sionnest P, Wehrenberg B and Yu D 2005 J. Chem. Phys. 123 074709 doi: 10.1063/1.2004818
[55]	Aharoni A, Oron D, Banin U, Rabani E and Jortner J 2008 Phys. Rev. Lett. 100 057404 doi: 10.1103/PhysRevLett.100.057404
[56]	Nanda J, Ivanov S A, Achermann M, Bezel I, Piryatinski A and Klimov V I 2007 J. Phys. Chem. C 111 15382 doi: 10.1021/jp0738659
[57]	Hatami F, Grundmann M, Ledentsov N N, Heinrichsdorff F, Heitz R, Böhrer J, Bimberg D, Ruvimov S S, Werner P, Ustinov V M, Kop'ev P S and Alferov Zh I 1998 Phys. Rev. B 57 4635 doi: 10.1103/PhysRevB.57.4635
[58]	Dennis A M, Mangum B D, Piryatinski A, Park Y S, Hannah D C, Casson J L, Williams D J, Schaller R D, Htoon H and Hollingsworth J A 2012 Nano Lett. 12 5545 doi: 10.1021/nl302453x
[59]	Yanover D, Vaxenburg R, Tilchin J, Rubin-Brusilovski A, Zaiats G, Čapek R K, Sashchiuk A and Lifshitz E 2014 J. Phys. Chem. C 118 17001 doi: 10.1021/jp500471s
[60]	Bae W K, Joo J, Padilha L A, Won J, Lee D C, Lin Q, Koh W, Luo H, Klimov V I and Pietryga J M 2012 J. Am. Chem. Soc. 134 20160 doi: 10.1021/ja309783v
[61]	Zhang J, Gao J, Church C P, Miller E M, Luther J M, Klimov V I and Beard M C 2014 Nano Lett. 14 6010 doi: 10.1021/nl503085v
[62]	Marshall A R, Young M R, Nozik A J, Beard M C and Luther J M 2015 J. Phys. Chem. Lett. 6 2892 doi: 10.1021/acs.jpclett.5b01214
[63]	Wang Z B, Helander M G, Qiu J, Liu Z W, Greiner M T and Lu Z H 2010 J. Appl. Phys. 108 024510 doi: 10.1063/1.3456513
[64]	Wang Z B, Helander M G, Qiu J, Puzzo D P, Greiner M T, Hudson Z M, Wang S, Liu Z W and Lu Z H 2011 Nat. Photon. 5 753 doi: 10.1038/nphoton.2011.259
[65]	Caram J R, Bertram S N, Utzat H, Hess W R, Carr J A, Bischof T S, Beyler A P, Wilson M W B and Bawendi M G 2016 Nano Lett. 16 6070 doi: 10.1021/acs.nanolett.6b02147
[66]	Mott N F and Gurney R W 1940 Electronic Processes in Ionic Crystals (New York: Oxford University Press) p. 1142
[67]	Rose A 1955 Phys. Rev. 97 1538 doi: 10.1103/PhysRev.97.1538
[68]	Hikmet R A M, Talapin D V and Weller H 2003 J. Appl. Phys. 93 3509 doi: 10.1063/1.1542940
[69]	Steckel J S, Coe-Sullivan S, Bulović V and Bawendi M G 2003 Adv. Mater. 15 1862 doi: 10.1002/adma.200305449
[70]	Choudhury K R, Song D W and So F 2010 Org. Electron. 11 23 doi: 10.1016/j.orgel.2009.09.017

Infrared light-emitting diodes based on colloidal PbSe/PbS core/shell nanocrystals

Infrared light-emitting diodes based on colloidal PbSe/PbS core/shell nanocrystals

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