Effects of bismuth on structural and dielectric properties of cobalt-cadmium spinel ferrites fabricated via micro-emulsion route

doi:10.1088/1674-1056/28/8/088701

中国物理B ›› 2019, Vol. 28 ›› Issue (8): 88701-088701.doi: 10.1088/1674-1056/28/8/088701

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

Effects of bismuth on structural and dielectric properties of cobalt-cadmium spinel ferrites fabricated via micro-emulsion route

Furhaj Ahmed Sheikh, Muhammad Khalid, Muhammad Shahzad Shifa, H M Noor ul Huda Khan Asghar, Sameen Aslam, Ayesha Perveen, Jalil ur Rehman, Muhammad Azhar Khan, Zaheer Abbas Gilani

1 Department of Physics, Balochistan University of Information Technology, Engineering & Management Sciences, Quetta 87300, Pakistan;
2 Department of Physics, Government College University, Faisalabad 38000, Pakistan;
3 Department of Physics, The Islamia University of Bahawalpur 63100, Pakistan

收稿日期:2019-03-22 修回日期:2019-06-12 出版日期:2019-08-05 发布日期:2019-08-05
通讯作者: Zaheer Abbas Gilani E-mail:zagilani2002@yahoo.com,zaheer.abbas@buitms.edu.pk

Effects of bismuth on structural and dielectric properties of cobalt-cadmium spinel ferrites fabricated via micro-emulsion route

Furhaj Ahmed Sheikh¹, Muhammad Khalid¹, Muhammad Shahzad Shifa², H M Noor ul Huda Khan Asghar¹, Sameen Aslam¹, Ayesha Perveen¹, Jalil ur Rehman¹, Muhammad Azhar Khan³, Zaheer Abbas Gilani¹

1 Department of Physics, Balochistan University of Information Technology, Engineering & Management Sciences, Quetta 87300, Pakistan;
2 Department of Physics, Government College University, Faisalabad 38000, Pakistan;
3 Department of Physics, The Islamia University of Bahawalpur 63100, Pakistan

Received:2019-03-22 Revised:2019-06-12 Online:2019-08-05 Published:2019-08-05
Contact: Zaheer Abbas Gilani E-mail:zagilani2002@yahoo.com,zaheer.abbas@buitms.edu.pk

摘要/Abstract

摘要： Spinel ferrites have a significant role in high-tech applications. In the present work nano-crystalline ferrites having general formula Co_0.5Cd_0.5Bi_xFe_2-xO₄ with (x=0.0, 0.05, 0.1, 0.15, 0.2, and 0.25) are synthesized via micro-emulsion route. Powder x-ray diffraction (XRD) studies discover the FCC spinel structure. Crystalline size is calculated in a range of 11 nm-15 nm. Lattice parameter calculations are reduced due to its substitution which leads to the exchange of large ionic radius of Fe³⁺ for small ionic radius of Bi³⁺. The x-ray density is analyzed to increase with doping. Fourier transform infrared spectroscopy (FTIR) is performed to analyze absorption band spectra. The two absorption bands are observed in a range of 400 cm^-1-600 cm^-1, and they are the characteristic feature of spinel structure. Thermo-gravimetric analysis (TGA) reveals the total weight loss of nearly 1.98%. Dielectric analysis is carried out by impedance analyzer in a frequency span from 1 MHz to 3 GHz by using the Maxwell Wagner model. Dielectric studies reveal the decrease of dielectric parameters. The alternating current (AC) conductivity exhibits a plane behavior in a low frequency range and it increases with the applied frequency increasing. This is attributed to the grain effects in a high frequency range or may be due to the reduction of porosity. Real and imaginary part of impedance show the decreasing trend which corresponds to the grain boundary action. The imaginary modulus shows the occurrence of peak that helps to understand the interfacial polarization. Cole-Cole graph shows a single semicircle which confirms that the conduction mechanism is due to the grain boundaries at low frequency. Dielectric studies reveal the applicability of these ferrites in high frequency equipment, microwave applications, high storage media, and semiconductor devices.

关键词: Co-ferrite, nanocrystalline ferrites, XRD, microemulsion, dielectric properties

Abstract: Spinel ferrites have a significant role in high-tech applications. In the present work nano-crystalline ferrites having general formula Co_0.5Cd_0.5Bi_xFe_2-xO₄ with (x=0.0, 0.05, 0.1, 0.15, 0.2, and 0.25) are synthesized via micro-emulsion route. Powder x-ray diffraction (XRD) studies discover the FCC spinel structure. Crystalline size is calculated in a range of 11 nm-15 nm. Lattice parameter calculations are reduced due to its substitution which leads to the exchange of large ionic radius of Fe³⁺ for small ionic radius of Bi³⁺. The x-ray density is analyzed to increase with doping. Fourier transform infrared spectroscopy (FTIR) is performed to analyze absorption band spectra. The two absorption bands are observed in a range of 400 cm^-1-600 cm^-1, and they are the characteristic feature of spinel structure. Thermo-gravimetric analysis (TGA) reveals the total weight loss of nearly 1.98%. Dielectric analysis is carried out by impedance analyzer in a frequency span from 1 MHz to 3 GHz by using the Maxwell Wagner model. Dielectric studies reveal the decrease of dielectric parameters. The alternating current (AC) conductivity exhibits a plane behavior in a low frequency range and it increases with the applied frequency increasing. This is attributed to the grain effects in a high frequency range or may be due to the reduction of porosity. Real and imaginary part of impedance show the decreasing trend which corresponds to the grain boundary action. The imaginary modulus shows the occurrence of peak that helps to understand the interfacial polarization. Cole-Cole graph shows a single semicircle which confirms that the conduction mechanism is due to the grain boundaries at low frequency. Dielectric studies reveal the applicability of these ferrites in high frequency equipment, microwave applications, high storage media, and semiconductor devices.

Key words: Co-ferrite, nanocrystalline ferrites, XRD, microemulsion, dielectric properties

中图分类号: (Dielectric properties)

87.19.rf

72.20.-i (Conductivity phenomena in semiconductors and insulators) 77.84.-s (Dielectric, piezoelectric, ferroelectric, and antiferroelectric materials) 47.54.Jk (Materials science applications)

Furhaj Ahmed Sheikh, Muhammad Khalid, Muhammad Shahzad Shifa, H M Noor ul Huda Khan Asghar, Sameen Aslam, Ayesha Perveen, Jalil ur Rehman, Muhammad Azhar Khan, Zaheer Abbas Gilani. Effects of bismuth on structural and dielectric properties of cobalt-cadmium spinel ferrites fabricated via micro-emulsion route[J]. 中国物理B, 2019, 28(8): 88701-088701.

参考文献 50

[37]	Brightlin B and Balamurugan S 2016 Appl. Nanosci. 6 1199 doi: 10.1007/s13204-016-0531-1
[1]	Iqbal M A, Islam M U, Ali I, Khan M A, Sadiq I and Ali Ihsan 2014 J. Alloys Compd. 586 404 doi: 10.1016/j.jallcom.2013.10.066
[38]	Ghasemi A and Mousavinia M 2014 Ceram. Int. 40 2825 doi: 10.1016/j.ceramint.2013.10.031
[2]	Yafet Y and Kittel C 1952 Phys. Rev. 87 290 doi: 10.1103/PhysRev.87.290
[39]	Karimi Z, Mohammadifar Y, Shokrollahi H, et al. 2014 J. Magn. Magn. Mater. 361 150 doi: 10.1016/j.jmmm.2014.01.016
[3]	Jiang J, Yang J M and Li L C 2007 Physica B: Condens. Matter 399 105 doi: 10.1016/j.physb.2007.05.035
[40]	Hemeda O 2004 Turkish J. Phys. 28 121
[4]	Wang Z, Jiang W, Li S X and Tong J S 2016 Nucl. Instrum. Methods Phys. Res. B 366 1 doi: 10.1016/j.nimb.2015.10.005
[41]	Orak I, Kocyigit A and Alindal Ş 2017 Chin. Phys. B 26 028102 doi: 10.1088/1674-1056/26/2/028102
[5]	Wang K, Si N, Zhang Y L, Guo A B and Jiang W 2019 Vacuum 165 105 doi: 10.1016/j.vacuum.2019.04.009
[6]	Wang K, Jiang W, Chen J N and Huang J Q 2016 Superlattices and Microstructures 97 116 doi: 10.1016/j.spmi.2016.06.011
[42]	Khan M A, Sabir M, Mahmood A, et al. 2014 J. Magn. Magn. Mater. 360 188 doi: 10.1016/j.jmmm.2014.02.059
[7]	Li M J, Xu Z P, Li Z B, Chen Y, Guo J W, Huo H M, Zhou H Y, Huangfu H C, Cao Z H and Wang H Y 2016 Crystal Research and Technology 51 696 doi: 10.1002/crat.201600073
[43]	Singh N, Agarwal A and Sanghi S 2011 Curr. Appl. Phys. 11 783 doi: 10.1016/j.cap.2010.11.073
[8]	Fu Y P, Hung D S and Yao Y D 2009 Ceram. Int. 35 2179 doi: 10.1016/j.ceramint.2008.11.027
[44]	Shkir M, Ganesh V, AlFaify S, Yahia I S and Anis M 2018 Chin. Phys. B 27 054216 doi: 10.1088/1674-1056/27/5/054216
[9]	Al-Hilli M F, Li S and Kassim K S 2012 J. Magn. Magn. Mater. 324 873 doi: 10.1016/j.jmmm.2011.10.005
[45]	Jalaiah K, Babub K V, Babu K R, et al. 2018 Chin. J. Phys. 56 2039 doi: 10.1016/j.cjph.2018.09.017
[10]	Singh R P and Venkataraju C 2018 Chin. J. Phys. 56 2218 doi: 10.1016/j.cjph.2018.07.005
[46]	Yadav R S, Kuřitka I, Vilcakova J, et al. 2017 Adv. Nat. Sci. 8 045002
[11]	Zi Z F, Sun Y P, Zhu X B, Yang Z R, Dai J M and Song W H 2009 J. Magn. Magne. Mater. 321 1251 doi: 10.1016/j.jmmm.2008.11.004
[47]	Costa M M, Pires G F M Jr, Terezo A J, Graça M P F and Sombra A S B 2011 J. Appl. Phys. 110 034107 doi: 10.1063/1.3615935
[12]	Grigorova M, Blythe H J, Blaskov V, et al. 1998 J. Magn. Magn. Mater. 183 163 doi: 10.1016/S0304-8853(97)01031-7
[48]	Joshi J H, Kanchan D K, Joshi M J, Jethva H O and Parikh K D 2017 Mater. Res. Bull. 93 63 doi: 10.1016/j.materresbull.2017.04.013
[13]	Shenker H 1957 Phys. Rev. 107 1246 doi: 10.1103/PhysRev.107.1246
[49]	Rodrigues H O, Junior G F M P, Sales A J M, et al. 2011 Physica B: Condens. Matter 406 2532 doi: 10.1016/j.physb.2011.03.050
[14]	Reddy C V, Prabhakar Vattikuti S V, Ravikumar R V S S, et al. 2015 J. Magn. Magn. Mater. 394 70 doi: 10.1016/j.jmmm.2015.06.054
[50]	Sujatha C, Reddy K V, Babu K S, et al. 2013 J. Phys. Chem. Solids 74 917 doi: 10.1016/j.jpcs.2013.02.005
[15]	Salunkhe A B, Khot V M, Phadatare M R and Pawar S H 2012 J. Alloys Compd. 514 91 doi: 10.1016/j.jallcom.2011.10.094
[16]	Maaz K, Mumtaz A, Hasanain S K and Ceylan A 2007 J. Magn. Magn. Mater. 308 289 doi: 10.1016/j.jmmm.2006.06.003
[17]	Naidek K P, Bianconi F, da Rocha T C R, et al. 2011 J. Colloid Interf. Sci. 358 39 doi: 10.1016/j.jcis.2011.03.001
[18]	Cedeño-Mattei Y and Perales-Pérez O 2009 Microelectron. J. 40 673 doi: 10.1016/j.mejo.2008.07.040
[19]	Fannin P C, Marin C N, Malaescu I, et al. 2011 Mater. Design 32 1600 doi: 10.1016/j.matdes.2010.08.053
[20]	Zhang Y, Yang Z, Yin D, Liu Y, Fei C L, Xiong R, Shi J and Yan G L 2010 J. Magn. Magn. Mater. 322 3470 doi: 10.1016/j.jmmm.2010.06.047
[21]	Sajjia M, Oubaha M, Prescott T and Olabi A G 2010 J. Alloys Compd. 506 400 doi: 10.1016/j.jallcom.2010.07.015
[22]	Singhal S, Jauhar S, Lakshmi N and Bansal S 2013 J. Mol. Struct. 1038 45 doi: 10.1016/j.molstruc.2013.01.020
[23]	Prabhakar Vattikuti S V, Byon C, Shim J, et al. 2015 J. Magn. Magn. Mater. 393 132 doi: 10.1016/j.jmmm.2015.05.057
[24]	Junaid M, Khan M A, Iqbal F, et al. 2016 J. Magn. Magn. Mater. 419 338 doi: 10.1016/j.jmmm.2016.06.043
[25]	Mohanty V, Cheruku R, Vijayan L and Govindaraj G 2014 J. Mater. Sci. Technol. 30 335 doi: 10.1016/j.jmst.2013.10.028
[26]	Gilani Z A, Warsi M F, Khan M A, et al. 2015 Physica E 73 169 doi: 10.1016/j.physe.2015.06.001
[27]	Sun C and Sun K 2007 Physica B: Condens. Matter 391 335 doi: 10.1016/j.physb.2006.10.016
[28]	Motavallian P, Abashtb B, Mirzaeea O and Abdollah-Pour H 2019 Chin. J. Phys. 57 6 doi: 10.1016/j.cjph.2018.12.018
[29]	Wang J P, Chen Q D, Li S L, Ji Y J, Mu W Y, Feng W W, Zeng G J, Liu Y W and Liang E J 2018 Chin. Phys. B 27 066501 doi: 10.1088/1674-1056/27/6/066501
[30]	Ali R, Mahmood A, Khan M A, et al. 2014 J. Alloys Compd. 584 363 doi: 10.1016/j.jallcom.2013.08.114
[31]	Lodhi M Y, Mahmood K, Mahmood A, et al. 2014 Curr. Appl. Phys. 14 716 doi: 10.1016/j.cap.2014.02.021
[32]	Gowreesan S and Kumar A R 2018 Chin. J. Phys. 56 1262 doi: 10.1016/j.cjph.2018.02.014
[33]	Iqbal M A, Islam M, Ashiq M N, et al. 2013 J. Alloys Compd. 579 181 doi: 10.1016/j.jallcom.2013.06.033
[34]	Anjum S, Sehar F, Bashir F, Awan M S and Mustafa Z 2015 Mater. Today 2 5182
[35]	Chavan P, Naik L R, Belavi P B, Chavan G N and Kotnala R K 2017 J. Alloys Compd. 694 607 doi: 10.1016/j.jallcom.2016.10.034
[36]	Chandrasekaran G, Selvanandan S and Manivannane K 2004 J. Mater. Sci. 15 15
[37]	Brightlin B and Balamurugan S 2016 Appl. Nanosci. 6 1199 doi: 10.1007/s13204-016-0531-1
[38]	Ghasemi A and Mousavinia M 2014 Ceram. Int. 40 2825 doi: 10.1016/j.ceramint.2013.10.031
[39]	Karimi Z, Mohammadifar Y, Shokrollahi H, et al. 2014 J. Magn. Magn. Mater. 361 150 doi: 10.1016/j.jmmm.2014.01.016
[40]	Hemeda O 2004 Turkish J. Phys. 28 121
[41]	Orak I, Kocyigit A and Alindal Ş 2017 Chin. Phys. B 26 028102 doi: 10.1088/1674-1056/26/2/028102
[42]	Khan M A, Sabir M, Mahmood A, et al. 2014 J. Magn. Magn. Mater. 360 188 doi: 10.1016/j.jmmm.2014.02.059
[43]	Singh N, Agarwal A and Sanghi S 2011 Curr. Appl. Phys. 11 783 doi: 10.1016/j.cap.2010.11.073
[44]	Shkir M, Ganesh V, AlFaify S, Yahia I S and Anis M 2018 Chin. Phys. B 27 054216 doi: 10.1088/1674-1056/27/5/054216
[45]	Jalaiah K, Babub K V, Babu K R, et al. 2018 Chin. J. Phys. 56 2039 doi: 10.1016/j.cjph.2018.09.017
[46]	Yadav R S, Kuřitka I, Vilcakova J, et al. 2017 Adv. Nat. Sci. 8 045002
[47]	Costa M M, Pires G F M Jr, Terezo A J, Graça M P F and Sombra A S B 2011 J. Appl. Phys. 110 034107 doi: 10.1063/1.3615935
[48]	Joshi J H, Kanchan D K, Joshi M J, Jethva H O and Parikh K D 2017 Mater. Res. Bull. 93 63 doi: 10.1016/j.materresbull.2017.04.013
[49]	Rodrigues H O, Junior G F M P, Sales A J M, et al. 2011 Physica B: Condens. Matter 406 2532 doi: 10.1016/j.physb.2011.03.050
[50]	Sujatha C, Reddy K V, Babu K S, et al. 2013 J. Phys. Chem. Solids 74 917 doi: 10.1016/j.jpcs.2013.02.005

Effects of bismuth on structural and dielectric properties of cobalt-cadmium spinel ferrites fabricated via micro-emulsion route

Effects of bismuth on structural and dielectric properties of cobalt-cadmium spinel ferrites fabricated via micro-emulsion route

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