中国物理B ›› 2022, Vol. 31 ›› Issue (4): 47502-047502.doi: 10.1088/1674-1056/ac3399

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Enhancement of magnetic and dielectric properties of low temperature sintered NiCuZn ferrite by Bi2O3-CuO additives

Jie Li(李颉)1,†, Bing Lu(卢冰)1, Ying Zhang(张颖)1, Jian Wu(武剑)1, Yan Yang(杨燕)1,2, Xue-Ning Han(韩雪宁)1, Dan-Dan Wen(文丹丹)3, Zheng Liang(梁峥)1, and Huai-Wu Zhang(张怀武)1   

  1. 1 State Key Laboratory of Electronic Thin Film and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, China;
    2 College of Communication Engineering, Chengdu University of Information Technology, Chengdu 610225, China;
    3 Chongqing Engineering Research Center of Intelligent Sensing Technology and Microsystem, Chongqing University of Post and Telecommunications, Chongqing 400065, China
  • 收稿日期:2021-09-18 修回日期:2021-10-20 接受日期:2021-10-27 出版日期:2022-03-16 发布日期:2022-03-29
  • 通讯作者: Jie Li E-mail:lijie@uestc.edu.cn
  • 基金资助:
    Project supported by the National Key Research and Development Program of China (Grant No. 2018YFE0115500), the National Natural Science Foundation of China (Grant Nos. 52003256 and 51902037), and the Natural Science Foundation of Shanxi Province, China (Grant No. 201901D211259).

Enhancement of magnetic and dielectric properties of low temperature sintered NiCuZn ferrite by Bi2O3-CuO additives

Jie Li(李颉)1,†, Bing Lu(卢冰)1, Ying Zhang(张颖)1, Jian Wu(武剑)1, Yan Yang(杨燕)1,2, Xue-Ning Han(韩雪宁)1, Dan-Dan Wen(文丹丹)3, Zheng Liang(梁峥)1, and Huai-Wu Zhang(张怀武)1   

  1. 1 State Key Laboratory of Electronic Thin Film and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, China;
    2 College of Communication Engineering, Chengdu University of Information Technology, Chengdu 610225, China;
    3 Chongqing Engineering Research Center of Intelligent Sensing Technology and Microsystem, Chongqing University of Post and Telecommunications, Chongqing 400065, China
  • Received:2021-09-18 Revised:2021-10-20 Accepted:2021-10-27 Online:2022-03-16 Published:2022-03-29
  • Contact: Jie Li E-mail:lijie@uestc.edu.cn
  • Supported by:
    Project supported by the National Key Research and Development Program of China (Grant No. 2018YFE0115500), the National Natural Science Foundation of China (Grant Nos. 52003256 and 51902037), and the Natural Science Foundation of Shanxi Province, China (Grant No. 201901D211259).

摘要: With a series of 1.0 wt%Bi$_{2}$O$_{3}$-$x$ wt% CuO ($x =0.0$, 0.2, 0.4, 0.6, and 0.8) serving as sintering additives, Ni$_{0.23}$Cu$_{0.32}$Zn$_{0.45}$Fe$_{2}$O$_{4}$ ferrites are successfully synthesized at a low temperature (900 $^\circ$C) by using the solid state reaction method. The effects of the additives on the phase formation, magnetic and dielectric properties as well as the structural and gyromagnetic properties are investigated. The x-ray diffraction (XRD) results indicate that the added Bi$_{2}$O$_{3}$-CuO can lower the synthesis temperature significantly without the appearing of the second phase. The scanning electron microscope (SEM) images confirm that Bi$_{2}$O$_{3}$ is an important factor that determines the sintering behaviors, while CuO affects the grain size and densification. With CuO content $x=0.4$ or 0.6, the sample shows high saturation magnetization, low coercivity, high real part of magnetic permeability, dielectric permittivity, and small ferromagnetic resonance linewidth ($\Delta H$). The NiCuZn ferrites are a promising new generation of high-performance microwave devices, such as phase shifters and isolators.

关键词: NiCuZn ferrite, Bi2O3-CuO additive, magnetic properties, dielectric properties, ferromagnetic resonance (FMR) linewidth

Abstract: With a series of 1.0 wt%Bi$_{2}$O$_{3}$-$x$ wt% CuO ($x =0.0$, 0.2, 0.4, 0.6, and 0.8) serving as sintering additives, Ni$_{0.23}$Cu$_{0.32}$Zn$_{0.45}$Fe$_{2}$O$_{4}$ ferrites are successfully synthesized at a low temperature (900 $^\circ$C) by using the solid state reaction method. The effects of the additives on the phase formation, magnetic and dielectric properties as well as the structural and gyromagnetic properties are investigated. The x-ray diffraction (XRD) results indicate that the added Bi$_{2}$O$_{3}$-CuO can lower the synthesis temperature significantly without the appearing of the second phase. The scanning electron microscope (SEM) images confirm that Bi$_{2}$O$_{3}$ is an important factor that determines the sintering behaviors, while CuO affects the grain size and densification. With CuO content $x=0.4$ or 0.6, the sample shows high saturation magnetization, low coercivity, high real part of magnetic permeability, dielectric permittivity, and small ferromagnetic resonance linewidth ($\Delta H$). The NiCuZn ferrites are a promising new generation of high-performance microwave devices, such as phase shifters and isolators.

Key words: NiCuZn ferrite, Bi2O3-CuO additive, magnetic properties, dielectric properties, ferromagnetic resonance (FMR) linewidth

中图分类号:  (Ferrimagnetics)

  • 75.50.Gg
75.47.Lx (Magnetic oxides) 75.60.Ej (Magnetization curves, hysteresis, Barkhausen and related effects) 75.75.Lf (Electronic structure of magnetic nanoparticles)