Nanosheet-structured B4C with high hardness up to 42 GPa

doi:10.1088/1674-1056/28/6/066201

中国物理B ›› 2019, Vol. 28 ›› Issue (6): 66201-066201.doi: 10.1088/1674-1056/28/6/066201

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Nanosheet-structured B₄C with high hardness up to 42 GPa

Chang-Chun Wang(王常春), Le-Le Song(宋乐乐)

1 College of Science, Jilin Institute of Chemical Technology, Jilin 132022, China;
2 Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012, China

收稿日期:2019-02-01 修回日期:2019-03-24 出版日期:2019-06-05 发布日期:2019-06-05
通讯作者: Chang-Chun Wang E-mail:onlywangsong@163.com
基金资助:
Project supported by the Scientific Research Fund of Jilin Provincial Education Department, China (Grant No. JJKH20190826KJ)

Nanosheet-structured B₄C with high hardness up to 42 GPa

Chang-Chun Wang(王常春)¹, Le-Le Song(宋乐乐)^1,2

1 College of Science, Jilin Institute of Chemical Technology, Jilin 132022, China;
2 Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012, China

Received:2019-02-01 Revised:2019-03-24 Online:2019-06-05 Published:2019-06-05
Contact: Chang-Chun Wang E-mail:onlywangsong@163.com
Supported by:
Project supported by the Scientific Research Fund of Jilin Provincial Education Department, China (Grant No. JJKH20190826KJ)

摘要/Abstract

摘要：

High-quality bulk boron carbide (B₄C) is successfully prepared at high pressure and high temperature (HPHT) by using B₄C powder as a precursor. The as-synthesized B₄C possesses a nanosheet structure with a thickness value of 15 nm and a length of several dozen micrometers. Its Vickers hardness value and fracture toughness value are 42.4 GPa and 4.51 MPa·m^1/2, respectively, which are superior to those of B₄C obtained from spark plasma sintering due to its high densification and nanosheet structure. Additionally, it shows good property of oxidation resistance. In air, its oxidation resistance temperature is 1100 ℃ which is higher than that of diamond under the same test condition.

关键词: boron carbide, hardness, fracture toughness, oxidation resistance

Abstract:

Key words: boron carbide, hardness, fracture toughness, oxidation resistance

中图分类号: (Structural classes of nanoscale systems)

62.23.-c

61.46.Hk (Nanocrystals) 61.66.Fn (Inorganic compounds) 62.20.-x (Mechanical properties of solids)

王常春, 宋乐乐. Nanosheet-structured B₄C with high hardness up to 42 GPa[J]. 中国物理B, 2019, 28(6): 66201-066201.

Chang-Chun Wang(王常春), Le-Le Song(宋乐乐). Nanosheet-structured B₄C with high hardness up to 42 GPa[J]. Chin. Phys. B, 2019, 28(6): 66201-066201.

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Nanosheet-structured B₄C with high hardness up to 42 GPa

Nanosheet-structured B₄C with high hardness up to 42 GPa

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