Progress in functional studies of transition metal borides

doi:10.1088/1674-1056/ac1925

中国物理B ›› 2021, Vol. 30 ›› Issue (10): 108103-108103.doi: 10.1088/1674-1056/ac1925

Progress in functional studies of transition metal borides

Teng Ma(马腾)^1,2, Pinwen Zhu(朱品文)^1,†, and Xiaohui Yu(于晓辉)^2,‡

1 State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China;
2 Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

收稿日期:2021-05-19 修回日期:2021-07-20 接受日期:2021-07-30 发布日期:2021-10-08
通讯作者: Pinwen Zhu, Xiaohui Yu E-mail:zhupw@jlu.edu.cn;yuxh@iphy.ac.cn
基金资助:
Project supported by the National Key Research and Development Program of China (Grant Nos. 2016YFA0401503 and 2018YFA0305700), the National Natural Science Foundation of China (Grant No. 11575288), the Strategic Priority Research Program and Key Research Program of Frontier Sciences of the Chinese Academy of Sciences (Grant Nos. XDB33000000, XDB25000000, and QYZDBSSW-SLH013), and the Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant No. Y202003).

Progress in functional studies of transition metal borides

Teng Ma(马腾)^1,2, Pinwen Zhu(朱品文)^1,†, and Xiaohui Yu(于晓辉)^2,‡

1 State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China;
2 Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Received:2021-05-19 Revised:2021-07-20 Accepted:2021-07-30 Published:2021-10-08
Contact: Pinwen Zhu, Xiaohui Yu E-mail:zhupw@jlu.edu.cn;yuxh@iphy.ac.cn
Supported by:
Project supported by the National Key Research and Development Program of China (Grant Nos. 2016YFA0401503 and 2018YFA0305700), the National Natural Science Foundation of China (Grant No. 11575288), the Strategic Priority Research Program and Key Research Program of Frontier Sciences of the Chinese Academy of Sciences (Grant Nos. XDB33000000, XDB25000000, and QYZDBSSW-SLH013), and the Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant No. Y202003).

摘要/Abstract

摘要： In recent years, transition metal borides (TMBs) have attracted much attention because they are considered as potential superhard materials and have more abundant crystal structures compared with traditional superhard materials. So far, however, no superhard materials have been found in TMBs. A large number of structures and potential new properties in TMBs are induced by the various hybridization ways of boron atoms and the high valence electrons of transition metals, which provide many possibilities for its application. And most TMBs have layered structures, which make TMBs have the potential to be a two-dimensional (2D) material. The 2D materials have novel properties, but the research on 2D TMBs is still nearly blank. In this paper, the research progress of TMBs is summarized involving structure, mechanical properties, and multifunctional properties. The strong covalent bonds of boron atoms in TMBs can form one-dimensional, two-dimensional, and three-dimensional substructures, and the multiple electron transfer between transition metal and boron leads to a variety of chemical bonds in TMBs, which are the keys to obtain high hardness and multifunctional properties of TMBs. Further research on the multifunctional properties of TMBs, such as superconductors, catalysts, and high hardness ferromagnetic materials, is of great significance to the discovery of new multifunctional hard materials.

关键词: transition metal borides, crystal structure, hardness, multifunctional properties

Abstract: In recent years, transition metal borides (TMBs) have attracted much attention because they are considered as potential superhard materials and have more abundant crystal structures compared with traditional superhard materials. So far, however, no superhard materials have been found in TMBs. A large number of structures and potential new properties in TMBs are induced by the various hybridization ways of boron atoms and the high valence electrons of transition metals, which provide many possibilities for its application. And most TMBs have layered structures, which make TMBs have the potential to be a two-dimensional (2D) material. The 2D materials have novel properties, but the research on 2D TMBs is still nearly blank. In this paper, the research progress of TMBs is summarized involving structure, mechanical properties, and multifunctional properties. The strong covalent bonds of boron atoms in TMBs can form one-dimensional, two-dimensional, and three-dimensional substructures, and the multiple electron transfer between transition metal and boron leads to a variety of chemical bonds in TMBs, which are the keys to obtain high hardness and multifunctional properties of TMBs. Further research on the multifunctional properties of TMBs, such as superconductors, catalysts, and high hardness ferromagnetic materials, is of great significance to the discovery of new multifunctional hard materials.

Key words: transition metal borides, crystal structure, hardness, multifunctional properties

中图分类号: (Ceramics and refractories (including borides, carbides, hydrides, nitrides, oxides, and silicides))

81.05.Je

71.20.Be (Transition metals and alloys) 91.60.Ed (Crystal structure and defects, microstructure) 62.20.-x (Mechanical properties of solids)

Teng Ma(马腾), Pinwen Zhu(朱品文), and Xiaohui Yu(于晓辉). Progress in functional studies of transition metal borides[J]. 中国物理B, 2021, 30(10): 108103-108103.

Teng Ma(马腾), Pinwen Zhu(朱品文), and Xiaohui Yu(于晓辉). Progress in functional studies of transition metal borides[J]. Chin. Phys. B, 2021, 30(10): 108103-108103.

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Progress in functional studies of transition metal borides

Progress in functional studies of transition metal borides

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