Performance of n-type silicon/silver composite anode material in lithium ion batteries: A study on effect of work function matching degree

doi:10.1088/1674-1056/27/10/108201

中国物理B ›› 2018, Vol. 27 ›› Issue (10): 108201-108201.doi: 10.1088/1674-1056/27/10/108201

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

Performance of n-type silicon/silver composite anode material in lithium ion batteries: A study on effect of work function matching degree

Guo-Jun Xu(徐国军), Chen-Xin Jin(金晨鑫), Kai-Jie Kong(孔凯捷), Xi-Xi Yang(杨西西), Zhi-Hao Yue(岳之浩), Xiao-Min Li(李晓敏), Fu-Gen Sun(孙福根), Hai-Bin Huang(黄海宾), Lang Zhou(周浪)

Institute of Photovoltaics, Nanchang University, Nanchang 330031, China

收稿日期:2018-06-26 修回日期:2018-07-23 出版日期:2018-10-05 发布日期:2018-10-05
通讯作者: Zhi-Hao Yue E-mail:yuezhihao@ncu.edu.cn
基金资助:
Project supported by the China Postdoctoral Science Foundation (Grant No. 2016M592115), the Jiangxi Postdoctoral Foundation, China (Grant No. 2015KY12), the Fund from the Jiangxi Provincial Education Department, China (Grant No. 150184), and the Fund from Nanchang University, China (Grant No. CX2017006).

Performance of n-type silicon/silver composite anode material in lithium ion batteries: A study on effect of work function matching degree

Institute of Photovoltaics, Nanchang University, Nanchang 330031, China

Received:2018-06-26 Revised:2018-07-23 Online:2018-10-05 Published:2018-10-05
Contact: Zhi-Hao Yue E-mail:yuezhihao@ncu.edu.cn
Supported by:
Project supported by the China Postdoctoral Science Foundation (Grant No. 2016M592115), the Jiangxi Postdoctoral Foundation, China (Grant No. 2015KY12), the Fund from the Jiangxi Provincial Education Department, China (Grant No. 150184), and the Fund from Nanchang University, China (Grant No. CX2017006).

摘要/Abstract

摘要：

In this paper, two types of silicon (Si) particles ball-milled from n-type Si wafers, respectively, with resistivity values of 1 Ω·cm and 0.001 Ω·cm are deposited with silver (Ag). The Ag-deposited n-type 1-Ω·cm Si particles (n1-Ag) and Ag-deposited n-type 0.001-Ω·cm Si particles (n0.001-Ag) are separately used as an anode material to assemble coin cells, of which the electrochemical performances are investigated. For the matching of work function between n-type 1-Ω·cm Si (n1) and Ag, n1-Ag shows discharge specific capacity of up to 683 mAh·g^-1 at a current density of 8.4 A·g^-1, which is 40% higher than that of n0.001-Ag. Furthermore, the resistivity of n1-Ag is lower than half that of n0.001-Ag. Due to the mismatch of work function between n-type 0.001-Ω·cm Si (n0.001) and Ag, the discharge specific capacity of n0.001-Ag is 250.2 mAh·g^-1 lower than that of n1-Ag after 100 cycles.

关键词: lithium ion battery, silicon anode materials, work function matching, contacts

Abstract:

Key words: lithium ion battery, silicon anode materials, work function matching, contacts

中图分类号: (Lithium-ion batteries)

82.47.Aa

82.45.Fk (Electrodes) 65.40.gh (Work functions) 73.40.Cg (Contact resistance, contact potential)

徐国军, 金晨鑫, 孔凯捷, 杨西西, 岳之浩, 李晓敏, 孙福根, 黄海宾, 周浪. Performance of n-type silicon/silver composite anode material in lithium ion batteries: A study on effect of work function matching degree[J]. 中国物理B, 2018, 27(10): 108201-108201.

Guo-Jun Xu(徐国军), Chen-Xin Jin(金晨鑫), Kai-Jie Kong(孔凯捷), Xi-Xi Yang(杨西西), Zhi-Hao Yue(岳之浩), Xiao-Min Li(李晓敏), Fu-Gen Sun(孙福根), Hai-Bin Huang(黄海宾), Lang Zhou(周浪). Performance of n-type silicon/silver composite anode material in lithium ion batteries: A study on effect of work function matching degree[J]. Chin. Phys. B, 2018, 27(10): 108201-108201.

参考文献 26

[1]	Zuo X, Zhu J, Müller-Buschbaum P and Cheng Y J 2017 Nano Energy 31 113 doi: 10.1016/j.nanoen.2016.11.013
[2]	Pang H 2017 Acta Phys. Sin. 66 238801 (in Chinese)
[3]	Wu M, Xu B and Ouyang C 2016 Chin. Phys. B 25 018206 doi: 10.1088/1674-1056/25/1/018206
[4]	Y H, Ai L, Jia M, Cheng Y, Du S L and Li S G 2017 Acta Phys. Sin. 66 118202 (in Chinese)
[5]	Yamaguchi K, Domi Y, Usui H, Shimizu M, Matsumoto K, Nokami T, Itoh T and Sakaguchi H 2017 J. Power Sources 338 103 doi: 10.1016/j.jpowsour.2016.10.111
[6]	Peng Y, Li Y, Zheng B, Zhang K and Xu Y 2018 Acta Phys. Sin. 67 070203 (in Chinese)
[7]	Assresahegn B D and Bélanger D 2017 J. Power Sources 345 190 doi: 10.1016/j.jpowsour.2017.01.135
[8]	Guo Y, Cao J and Xu B 2016 Chin. Phys. B 25 017101 doi: 10.1088/1674-1056/25/1/017101
[9]	Memarzadeh E L, Kalisvaart W P, Kohandehghan A, Zahiri B, Holt C M B and Mitlin D 2012 J. Mater. Chem. 22 6655 doi: 10.1039/c2jm16167b
[10]	Murugesan S, Harris J T, Korgel B A and Stevenson K J 2012 Chem. Mater. 24 1306 doi: 10.1021/cm2037475
[11]	Yang Z, Wang D, Li F, Yue H, Liu D, Li X, Qiao L and He D 2014 Mater. Lett. 117 58 doi: 10.1016/j.matlet.2013.12.001
[12]	Huang X H, Zhang P, Wu J B, Lin Y and Guo R Q 2016 Mater. Res. Bull. 80 30 doi: 10.1016/j.materresbull.2016.03.021
[13]	Halim M, Kim J S, Nguyen S H, Jeon B J and Lee J K 2015 J. Nanosci. Nanotechnol. 15 8222 doi: 10.1166/jnn.2015.11435
[14]	Baek S H, Park J S, Jeong Y M and Kim J H 2016 J. Alloys Compd. 660 387 doi: 10.1016/j.jallcom.2015.11.131
[15]	Yao W, Cui Y, Zhan L, Chen F, Zhang Y, Wang Y and Song Y 2017 Appl. Surf. Sci. 425 614 doi: 10.1016/j.apsusc.2017.06.031
[16]	Talla G, Guduru R K, Li B Q and Mohanty P S 2015 Solid State Ionics 269 8 doi: 10.1016/j.ssi.2014.09.021
[17]	Hao Q, Zhao D, Duan H, Zhou Q and Xu C 2015 Nanoscale 7 5320 doi: 10.1039/C4NR07384C
[18]	Kwon E, Lim H S, Sun Y K and Suh K D 2013 Solid State Ionics 237 28 doi: 10.1016/j.ssi.2013.02.008
[19]	Gu M, Ko S, Yoo S, Lee E, Min S H, Park S and Kim B S 2015 J. Power Sources 300 351 doi: 10.1016/j.jpowsour.2015.09.083
[20]	Yoo S, Lee J I, Ko S and Park S 2013 Nano Energy 2 1271 doi: 10.1016/j.nanoen.2013.06.006
[21]	Wang Q, Han L, Zhang X, Li J, Zhou X and Lei Z 2016 Mater. Lett. 185 558 doi: 10.1016/j.matlet.2016.09.059
[22]	Sze S M and Ng K K 2006 Physics of Semiconductor Devices, 3rd edn. (Hoboken:John Willey and Sons)
[23]	Wolf H F 1971 Semiconductors (New York:John Willey and Sons)
[24]	Harrison W A, Goebel A and Clifton P A 2013 Appl. Phys. Lett. 103 138
[25]	Xu G, Jin C, Liu L, Lan Y, Yue Z, Li X, Sun F, Huang H and Zhou L 2017 Appl. Phys. A 123 752 doi: 10.1007/s00339-017-1384-5
[26]	Yue Z, Zhou L, Jin C, Liu L, Xu G, Tang H, Huang H, Yuan J and Gao C 2017 Mater. Lett. 186 217 doi: 10.1016/j.matlet.2016.09.123

Performance of n-type silicon/silver composite anode material in lithium ion batteries: A study on effect of work function matching degree

Performance of n-type silicon/silver composite anode material in lithium ion batteries: A study on effect of work function matching degree

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 26

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Jingshu Guo(郭静姝), Jiejie Zhu(祝杰杰), Siyu Liu(刘思雨), Jielong Liu(刘捷龙), Jiahao Xu(徐佳豪), Weiwei Chen(陈伟伟), Yuwei Zhou(周雨威), Xu Zhao(赵旭), Minhan Mi(宓珉瀚), Mei Yang(杨眉), Xiaohua Ma(马晓华), and Yue Hao(郝跃). Low-resistance ohmic contacts on InAlN/GaN heterostructures with MOCVD-regrown n⁺-InGaN and mask-free regrowth process[J]. 中国物理B, 2023, 32(3): 37303-037303.
[2]	Baohe Yuan(袁保合), Xiang Yuan(袁祥), Binger Zhang(张冰儿), Zheng An(安政), Shijun Luo(罗世钧), and Lulu Chen(陈露露). Lithium ion batteries cathode material: V₂O₅[J]. 中国物理B, 2022, 31(3): 38203-038203.
[3]	Mingchen Hou(侯明辰), Gang Xie(谢刚), Qing Guo(郭清), and Kuang Sheng(盛况). Protection of isolated and active regions in AlGaN/GaN HEMTs using selective laser annealing[J]. 中国物理B, 2021, 30(9): 97302-097302.
[4]	Qun-Si Yang(羊群思), Qing Liu(刘清), Dong Zhou(周东), Wei-Zong Xu(徐尉宗), Yi-Wang Wang(王宜望), Fang-Fang Ren(任芳芳), and Hai Lu(陆海). Alpha particle detector with planar double Schottky contacts directly fabricated on semi-insulating GaN:Fe template[J]. 中国物理B, 2021, 30(11): 117303-117303.
[5]	侯明辰, 谢刚, 盛况. Mechanism of Ti/Al/Ni/Au ohmic contacts to AlGaN/GaN heterostructures via laser annealing[J]. 中国物理B, 2019, 28(3): 37302-037302.
[6]	李文俊, 李泉, 黄杰, 彭佳悦, 褚赓, 陆雅翔, 郑杰允, 李泓. Gas treatment protection of metallic lithium anode[J]. 中国物理B, 2017, 26(8): 88202-088202.
[7]	褚赓, 刘柏男, 罗飞, 李文俊, 陆浩, 陈立泉, 李泓. Conductivity and applications of Li-biphenyl-1, 2-dimethoxyethane solution for lithium ion batteries[J]. 中国物理B, 2017, 26(7): 78201-078201.
[8]	谢应涛, 欧阳世宏, 王东平, 朱大龙, 许鑫, 谭特, 方汉铿. Performance improvement in polymeric thin film transistors using chemically modified both silver bottom contacts and dielectric surfaces[J]. 中国物理B, 2015, 24(9): 96803-096803.
[9]	张舒, 李文俊, 凌仕刚, 李泓, 周志彬, 陈立泉. Instability of lithium bis(fluorosulfonyl)imide (LiFSI)–potassium bis(fluorosulfonyl)imide (KFSI) system with LiCoO₂ at high voltage[J]. 中国物理B, 2015, 24(7): 78201-078201.
[10]	武玫, 郑大勇, 王媛, 陈伟伟, 张凯, 马晓华, 张进成, 郝跃. Schottky forward current transport mechanisms in AlGaN/GaN HEMTs over a wide temperature range[J]. , 2014, 23(9): 97307-097307.
[11]	刘芳, 秦志新, 许福军, 赵胜, 康香宁, 沈波, 张国义. Thermal stability of tungsten and tungsten nitride Schottky contacts to AlGaN/GaN[J]. 中国物理B, 2011, 20(6): 67303-067303.
[12]	朱亚彬, 胡伟, 纳杰, 何帆, 周岳亮, 陈聪. PEDOT:PSS Schottky contacts on annealed ZnO films[J]. 中国物理B, 2011, 20(4): 47301-047301.
[13]	黄钊文, 胡社军, 侯贤华, 赵灵智, 汝强, 李伟善, 张志文. First-principle study on phase Al_0.8Ni₃Sn_0.2 in Sn-Ni-Al alloy as anode for lithium ion battery[J]. 中国物理B, 2010, 19(11): 117101-117102.
[14]	王向红, 沈瑜, 章林溪. Structural statistical properties of knotted proteins[J]. 中国物理B, 2009, 18(4): 1684-1690.
[15]	侯贤华, 胡社军, 李伟善, 汝强, 余洪文, 黄钊文. First-principles study of interphase Ni₃Sn in Sn--Ni alloy for anode of lithium ion battery[J]. 中国物理B, 2008, 17(9): 3422-3427.