Effect of chloride introduction on the optical properties in Eu3+-doped fluorozirconate glasses

doi:10.1088/1674-1056/25/10/103201

中国物理B ›› 2016, Vol. 25 ›› Issue (10): 103201-103201.doi: 10.1088/1674-1056/25/10/103201

• ATOMIC AND MOLECULAR PHYSICS • 上一篇下一篇

Effect of chloride introduction on the optical properties in Eu³⁺-doped fluorozirconate glasses

Han Jin(金含), Zhao-Jun Mo(莫兆军), Xiao-Song Zhang(张晓松), Lin-Lin Yuan(苑琳琳), Ming Yan(晏明), Lan Li(李岚)

Institute of Material Physics, Key Laboratory for Optoelectronic Materials and Devices of Tianjin, Key Laboratory of Display Materials and Photoelectric Devices of Ministry of Education, Tianjin University of Technology, Tianjin 300384, China

收稿日期:2016-02-04 修回日期:2016-05-23 出版日期:2016-10-05 发布日期:2016-10-05
通讯作者: Zhao-Jun Mo, Lan Li E-mail:mzjmzj163@163.com;lilan@tjut.edu.cn
基金资助:
Project supported by the National High Technology Research and Development Program of China (Grant No. 2013AA014201), the Natural Science Foundation of Tianjin, China (Grant Nos. 14JCZDJC31200, 15JCYBJC16700, and 15JCYBJC16800), the National Key Foundation for Exploring Scientific Instrument of China (Grant No. 2014YQ120351), and the International Cooperation Program from Science and Technology of Tianjin, China (Grant No. 14RCGHGX00872).

Effect of chloride introduction on the optical properties in Eu³⁺-doped fluorozirconate glasses

Han Jin(金含), Zhao-Jun Mo(莫兆军), Xiao-Song Zhang(张晓松), Lin-Lin Yuan(苑琳琳), Ming Yan(晏明), Lan Li(李岚)

Institute of Material Physics, Key Laboratory for Optoelectronic Materials and Devices of Tianjin, Key Laboratory of Display Materials and Photoelectric Devices of Ministry of Education, Tianjin University of Technology, Tianjin 300384, China

Received:2016-02-04 Revised:2016-05-23 Online:2016-10-05 Published:2016-10-05
Contact: Zhao-Jun Mo, Lan Li E-mail:mzjmzj163@163.com;lilan@tjut.edu.cn
Supported by:
Project supported by the National High Technology Research and Development Program of China (Grant No. 2013AA014201), the Natural Science Foundation of Tianjin, China (Grant Nos. 14JCZDJC31200, 15JCYBJC16700, and 15JCYBJC16800), the National Key Foundation for Exploring Scientific Instrument of China (Grant No. 2014YQ120351), and the International Cooperation Program from Science and Technology of Tianjin, China (Grant No. 14RCGHGX00872).

摘要/Abstract

摘要： Fluorozirconate glass containing Eu³⁺ ions and chloride ions are prepared by a meltquenching method. The luminescence behavior of Eu³⁺ affected by Cl ions is investigated. With increasing Cl ion concentration, the luminous intensity of Eu³⁺ is significantly enhanced and the quantum efficiency of fluorozirconate glass is improved. Meanwhile, the intensity parameter Ω₂ increases according to the Judd-Ofelt calculation, which indicates the decrease of local symmetry. The average lifetime of Eu³⁺ increases by introducing the Cl ions. Moreover, we find two kinds of sites for Eu³⁺ ions in a glass network by analyzing the fluorescence decay. The distribution of Eu³⁺ ions changes with increasing Cl ion concentration. In addition, the excessive Cl ions lead to the separation of the glass phase and the formation of the crystal phase, thus reducing the transmittance dramatically.

关键词: photoluminescence, fluorescence decay, Judd-Ofelt theory, quantum efficiency

Abstract: Fluorozirconate glass containing Eu³⁺ ions and chloride ions are prepared by a meltquenching method. The luminescence behavior of Eu³⁺ affected by Cl ions is investigated. With increasing Cl ion concentration, the luminous intensity of Eu³⁺ is significantly enhanced and the quantum efficiency of fluorozirconate glass is improved. Meanwhile, the intensity parameter Ω₂ increases according to the Judd-Ofelt calculation, which indicates the decrease of local symmetry. The average lifetime of Eu³⁺ increases by introducing the Cl ions. Moreover, we find two kinds of sites for Eu³⁺ ions in a glass network by analyzing the fluorescence decay. The distribution of Eu³⁺ ions changes with increasing Cl ion concentration. In addition, the excessive Cl ions lead to the separation of the glass phase and the formation of the crystal phase, thus reducing the transmittance dramatically.

Key words: photoluminescence, fluorescence decay, Judd-Ofelt theory, quantum efficiency

中图分类号: (Fluorescence, phosphorescence (including quenching))

32.50.+d

66.30.hh (Glasses)

金含, 莫兆军, 张晓松, 苑琳琳, 晏明, 李岚. Effect of chloride introduction on the optical properties in Eu³⁺-doped fluorozirconate glasses[J]. 中国物理B, 2016, 25(10): 103201-103201.

Han Jin(金含), Zhao-Jun Mo(莫兆军), Xiao-Song Zhang(张晓松), Lin-Lin Yuan(苑琳琳), Ming Yan(晏明), Lan Li(李岚). Effect of chloride introduction on the optical properties in Eu³⁺-doped fluorozirconate glasses[J]. Chin. Phys. B, 2016, 25(10): 103201-103201.

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Effect of chloride introduction on the optical properties in Eu³⁺-doped fluorozirconate glasses

Effect of chloride introduction on the optical properties in Eu³⁺-doped fluorozirconate glasses

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