Exciton luminescence and many-body effect of monolayer WS2 at room temperature

doi:10.1088/1674-1056/ac380c

中国物理B ›› 2022, Vol. 31 ›› Issue (5): 57803-057803.doi: 10.1088/1674-1056/ac380c

Exciton luminescence and many-body effect of monolayer WS₂ at room temperature

Jian-Min Wu(吴建民)¹, Li-Hui Li(黎立辉)¹, Wei-Hao Zheng(郑玮豪)², Bi-Yuan Zheng(郑弼元)², Zhe-Yuan Xu(徐哲元)², Xue-Hong Zhang(张学红)², Chen-Guang Zhu(朱晨光)², Kun Wu(吴琨)¹, Chi Zhang(张弛)¹, Ying Jiang(蒋英)¹, Xiao-Li Zhu(朱小莉)¹, and Xiu-Juan Zhuang(庄秀娟)^1,†

1 Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronics, Hunan University, Changsha 410082, China;
2 College of Materials Science and Engineering, Hunan University, Changsha 410082, China

收稿日期:2021-06-23 修回日期:2021-11-05 发布日期:2022-04-09
通讯作者: Xiu-Juan Zhuang,E-mail:zhuangxj@hnu.edu.cn E-mail:zhuangxj@hnu.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos.61635001,52072117,and 51972105).

Exciton luminescence and many-body effect of monolayer WS₂ at room temperature

1 Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronics, Hunan University, Changsha 410082, China;
2 College of Materials Science and Engineering, Hunan University, Changsha 410082, China

Received:2021-06-23 Revised:2021-11-05 Published:2022-04-09
Contact: Xiu-Juan Zhuang,E-mail:zhuangxj@hnu.edu.cn E-mail:zhuangxj@hnu.edu.cn
About author:2021-11-10
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos.61635001,52072117,and 51972105).

1. 附件.pdf(859KB)

摘要/Abstract

摘要： Monolayer transition metal dichalcogenides favor the formation of a variety of excitonic quasiparticles, and can serve as an ideal material for exploring room-temperature many-body effects in two-dimensional systems. Here, using mechanically exfoliated monolayer WS₂ and photoluminescence (PL) spectroscopy, exciton emission peaks are confirmed through temperature-dependent and electric-field-tuned PL spectroscopy. The dependence of exciton concentration on the excitation power density at room temperature is quantitatively analyzed. Exciton concentrations covering four orders of magnitude are divided into three stages. Within the low carrier concentration stage, the system is dominated by excitons, with a small fraction of trions and localized excitons. At the high carrier concentration stage, the localized exciton emission from defects coincides with the emission peak position of trions, resulting in broad spectral characteristics at room temperature.

关键词: transition metal dichalcogenides, photoluminescence, localized exciton, exciton density

Abstract: Monolayer transition metal dichalcogenides favor the formation of a variety of excitonic quasiparticles, and can serve as an ideal material for exploring room-temperature many-body effects in two-dimensional systems. Here, using mechanically exfoliated monolayer WS₂ and photoluminescence (PL) spectroscopy, exciton emission peaks are confirmed through temperature-dependent and electric-field-tuned PL spectroscopy. The dependence of exciton concentration on the excitation power density at room temperature is quantitatively analyzed. Exciton concentrations covering four orders of magnitude are divided into three stages. Within the low carrier concentration stage, the system is dominated by excitons, with a small fraction of trions and localized excitons. At the high carrier concentration stage, the localized exciton emission from defects coincides with the emission peak position of trions, resulting in broad spectral characteristics at room temperature.

Key words: transition metal dichalcogenides, photoluminescence, localized exciton, exciton density

中图分类号: (Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures)

78.67.-n

78.55.-m (Photoluminescence, properties and materials) 52.70.Kz (Optical (ultraviolet, visible, infrared) measurements)

Jian-Min Wu(吴建民), Li-Hui Li(黎立辉), Wei-Hao Zheng(郑玮豪), Bi-Yuan Zheng(郑弼元), Zhe-Yuan Xu(徐哲元), Xue-Hong Zhang(张学红), Chen-Guang Zhu(朱晨光), Kun Wu(吴琨), Chi Zhang(张弛), Ying Jiang(蒋英),Xiao-Li Zhu(朱小莉), and Xiu-Juan Zhuang(庄秀娟). Exciton luminescence and many-body effect of monolayer WS₂ at room temperature[J]. 中国物理B, 2022, 31(5): 57803-057803.

参考文献

[1] Splendiani A, Sun L, Zhang Y, Li T, Kim J, Chim C Y, Galli G and Wang F 2010 Nano Lett. 10 1271
[2] Mak K F, Lee C, Hone J, Shan J and Heinz T F 2010 Phys. Rev. Lett. 105 136085
[3] Ramasubramaniam A 2012 Phys. Rev. B 86 115409
[4] Ross J S, Wu S, Yu H, Ghimire N J, Jones A M, Aivazian G, Yan J, Mandrus D G, Xiao D, Yao W and Xu X 2013 Nat. Commun. 4 1474
[5] Berkelbach T C, Hybertsen M S and Reichman D R 2013 Phys. Rev. B 88 045318
[6] You Y, Zhang X X, Berkelbach T C, Hybertsen M S, Reichman D R and Heinz T F 2015 Nat. Phys. 11 477
[7] He Z, Xu W, Zhou Y, Wang X, Sheng Y, Rong Y, Guo S, Zhang J, Smith J M and Warner J H 2016 ACS Nano 10 2176
[8] Singh A, Moody G, Wu S, Wu Y, Ghimire N J, Yan J, Mandrus D G, Xu X and Li X 2014 Phys. Rev. Lett. 112 216804
[9] Li L, Zheng W, Ma C, Zhao H, Jiang F, Ouyang Y, Zheng B, Fu X, Fan P, Zheng M, Li Y, Xiao Y, Cao W, Jiang Y, Zhu X, Zhuang X and Pan A 2020 Nano Lett. 20 3361
[10] Zhu B, Chen X and Cui X 2015 Sci. Rep. 5 9218
[11] Chernikov A, Berkelbach T C, Hill H M, Rigosi A, Li Y, Aslan O B, Reichman D R, Hybertsen M S and Heinz T F 2014 Phys. Rev. Lett. 113 076802
[12] He K, Kumar N, Zhao L, Wang Z, Mak K F, Zhao H and Shan J 2014 Phys. Rev. Lett. 113 026803
[13] Xiao K, Yan T, Liu Q, Yang S, Kan C, Duan R, Liu Z and Cui X 2021 J. Phys. Chem. Lett. 12 2555
[14] Lin T N, Santiago S R M, Caigas S P, Yuan C T, Lin T Y, Shen J L and Chen Y F 2019 npj 2D Mater. Appl. 3 46
[15] Carmiggelt J J, Borst M and van der Sar T 2020 Sci. Rep. 10 17389
[16] Feierabend M, Brem S, Ekman A and Malic E 2020 2D Mater. 8 015013
[17] Zhou Y, Scuri G, Wild D S, High A A, Dibos A, Jauregui L A, Shu C, De Greve K, Pistunova K, Joe A Y, Taniguchi T, Watanabe K, Kim P, Lukin M D and Park H 2017 Nat. Nanotech. 12 856
[18] Ye Z, Cao T, O'Brien K, Zhu H, Yin X, Wang Y, Louie S G and Zhang X 2014 Nature 513 214
[19] Selig M, Berghäuser G, Richter M, Bratschitsch R, Knorr A and Malic E 2018 2D Mater. 5 035017
[20] Chow P K, Jacobs-Gedrim R B, Gao J, Lu T M and Koratkar N 2015 ACS Nano 9 1520
[21] Ayari S, Smiri A, Hichri A, Jaziri S and Amand T 2018 Phys. Rev. B 98 205430
[22] Grim J Q, Christodoulou S, Di Stasio F, Krahne R, Cingolani R, Manna L and Moreels I 2014 Nat. Nanotech. 9 891
[23] Wen W, Wu L and Yu T 2020 ACS Mater. Lett. 2 1328
[24] Dwedari M, Brem S, Feierabend M and Malic E 2019 Phys. Rev. Mater. 3 074004
[25] Kim M S, Yun S J, Lee Y, Seo C, Han G H, Kim K K, Lee Y H and Kim J 2016 ACS Nano 10 2399
[26] Plechinger G, Nagler P, Kraus J, Paradiso N, Strunk C, Schüller C and Korn T 2015 Physica Status Solidi (RRL)-Rapid Research Letters 9 457
[27] Okada M, Miyauchi Y, Matsuda K, Taniguchi T, Watanabe K, Shinohara H and Kitaura R 2017 Sci. Rep. 7 322
[28] Barbone M, Montblanch A R, Kara D M, Palacios-Berraquero C, Cadore A R, De Fazio D, Pingault B, Mostaani E, Li H, Chen B, Watanabe K, Taniguchi T, Tongay S, Wang G, Ferrari A C and Atature M 2018 Nat. Commun. 9 3721
[29] Siviniant J, Scalbert D, Kavokin A V, Coquillat D and Lascaray J P 1999 Phys. Rev. B 59 1602
[30] Shang J, Shen X, Cong C, Peimyoo N, Cao B, Eginligil M and Yu T 2015 ACS Nano 9 647
[31] Mitioglu A A, Plochocka P, Jadczak J N, Escoffier W, Rikken G L J A, Kulyuk L and Maude D K 2013 Phys. Rev. B 88 245403
[32] Mak K F, He K, Lee C, Lee G H, Hone J, Heinz T F and Shan J 2013 Nat. Mater. 12 207
[33] Peimyoo N, Yang W, Shang J, Shen X, Wang Y and Yu T 2014 ACS Nano 8 11320
[34] Chernikov A, van der Zande A M, Hill H M, Rigosi A F, Velauthapillai A, Hone J and Heinz T F 2015 Phys. Rev. Lett. 115 126802
[35] Phillips R T, Lovering D J, Denton G J and Smith G W 1992 Phys. Rev. B 45 4308
[36] Vietmeyer F, Frantsuzov P A, Janko B and Kuno M 2011 Phys. Rev. B 83 115319
[37] Wei S, Lin M L, Tan Q H, Qiao X F and Tan P H 2016 2D Mater. 3 025016
[38] Zheng W, Zheng B, Jiang Y, Yan C, Chen S, Liu Y, Sun X, Zhu C, Qi Z, Yang T, Huang W, Fan P, Jiang F, Wang X, Zhuang X, Li D, Li Z, Xie W, Ji W, Wang X and Pan A 2019 Nano Lett. 19 7217
[39] Fan P, Zheng B Y, Sun X X, Zheng W H, Xu Z Y, Ge C H, Liu Y, Zhuang X J, Li D, Wang X, Zhu X L, Jiang Y and Pan A L 2019 J. Phys. Chem. Lett. 10 3763
[40] Mouri S, Miyauchi Y, Toh M, Zhao W, Eda G and Matsuda K 2014 Phys. Rev. B 90 155449
[41] Kumar N, Cui Q, Ceballos F, He D, Wang Y and Zhao H 2014 Phys. Rev. B 89 125427
[42] Salehzadeh O, Tran N H, Liu X, Shih I and Mi Z 2014 Nano Lett. 14 4125

Exciton luminescence and many-body effect of monolayer WS₂ at room temperature

Exciton luminescence and many-body effect of monolayer WS₂ at room temperature

RichHTML

PDF (PC)

赞

补充材料

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Yu-De Niu(牛毓德), Yu-Zhen Wang(汪玉珍), Kai-Ming Zhu(朱凯明), Wang-Gui Ye(叶王贵), Zhe Feng(冯喆), Hui Liu(柳挥), Xin Yi(易鑫), Yi-Huan Wang(王怡欢), and Xuan-Yi Yuan(袁轩一). Thermally enhanced photoluminescence and temperature sensing properties of Sc₂W₃O₁₂:Eu³⁺ phosphors[J]. 中国物理B, 2023, 32(2): 28703-028703.
[2]	Siwen You(游思雯), Ziyi Shao(邵子依), Xiao Guo(郭晓), Junjie Jiang(蒋俊杰), Jinxin Liu(刘金鑫), Kai Wang(王凯), Mingjun Li(李明君), Fangping Ouyang(欧阳方平), Chuyun Deng(邓楚芸), Fei Song(宋飞), Jiatao Sun(孙家涛), and Han Huang(黄寒). Growth behaviors and emission properties of Co-deposited MAPbI₃ ultrathin films on MoS₂[J]. 中国物理B, 2023, 32(1): 17901-017901.
[3]	Yu-Chun Liu(刘玉春), Xin Tan(谭欣), Tian-Ci Shen(沈天赐), and Fu-Xing Gu(谷付星). Enhanced photoluminescence of monolayer MoS₂ on stepped gold structure[J]. 中国物理B, 2022, 31(8): 87803-087803.
[4]	Zein K Heiba, Mohamed Bakr Mohamed, Noura M Farag, and Ali Badawi. Exploration of structural, optical, and photoluminescent properties of (1-x)NiCo₂O₄/xPbS nanocomposites for optoelectronic applications[J]. 中国物理B, 2022, 31(6): 67801-067801.
[5]	Ghfoor Muhammad, Imran Murtaza, Rehan Abid, and Naeem Ahmad. Effect of different catalysts and growth temperature on the photoluminescence properties of zinc silicate nanostructures grown via vapor-liquid-solid method[J]. 中国物理B, 2022, 31(5): 57801-057801.
[6]	Xian-Dong Li(李现东), Zuo-Dong Yu(余作东), Wei-Peng Chen(陈伟鹏), and Chang-De Gong(龚昌德). Topological superconductivity in Janus monolayer transition metal dichalcogenides[J]. 中国物理B, 2022, 31(11): 110304-110304.
[7]	Peng-Yu Zhou(周鹏宇), Xiu-Ming Dou(窦秀明), Bao-Quan Sun(孙宝权), Ren-Qin Dou(窦仁琴), Qing-Li Zhang(张庆礼), Bao Liu(刘鲍), Pu-Geng Hou(侯朴赓), Kai-Lin Chi(迟凯粼), and Kun Ding(丁琨). Pressure- and temperature-dependent luminescence from Tm³⁺ ions doped in GdYTaO₄[J]. 中国物理B, 2022, 31(1): 17101-017101.
[8]	Fu-Jian Ge(葛付建), Hui Peng(彭辉), Ye Tian(田野), Xiao-Yue Fan(范晓跃), Shuai Zhang(张帅), Xian-Xin Wu(吴宪欣), Xin-Feng Liu(刘新风), and Bing-Suo Zou(邹炳锁). Magnetic polaron-related optical properties in Ni(II)-doped CdS nanobelts: Implication for spin nanophotonic devices[J]. 中国物理B, 2022, 31(1): 17802-017802.
[9]	Wen Cui(崔雯), De-Jun Li(李德军), Jin-Liang Guo(郭金良), Lang-Huan Zhao(赵琅嬛), Bing-Bing Liu(刘冰冰), and Shi-Shuai Sun(孙士帅). Controllable preparation and disorder-dependent photoluminescence of morphologically different C₆₀ microcrystals[J]. 中国物理B, 2021, 30(8): 86101-086101.
[10]	Lijun Wu(吴莉君), Cuihuan Ge(葛翠环), Kai Braun, Mai He(贺迈), Siman Liu(刘思嫚), Qingjun Tong(童庆军), Xiao Wang(王笑), and Anlian Pan(潘安练). Polarized photoluminescence spectroscopy in WS₂, WSe₂ atomic layers and heterostructures by cylindrical vector beams[J]. 中国物理B, 2021, 30(8): 87802-087802.
[11]	Yanchong Zhao(赵岩翀), Tao Bo(薄涛), Luojun Du(杜罗军), Jinpeng Tian(田金朋), Xiaomei Li(李晓梅), Kenji Watanabe, Takashi Taniguchi, Rong Yang(杨蓉), Dongxia Shi(时东霞), Sheng Meng(孟胜), Wei Yang(杨威), and Guangyu Zhang(张广宇). Thermally induced band hybridization in bilayer-bilayer MoS₂/WS₂ heterostructure[J]. 中国物理B, 2021, 30(5): 57801-057801.
[12]	Yong Wang(王勇), Qing Liao(廖庆), Ming Liu(刘茗), Peng-Fei Zheng(郑鹏飞), Xinyu Gao(高新宇), Zheng Jia(贾政), Shuai Xu(徐帅), and Bing-Sheng Li(李炳生). Optical spectroscopy study of damage evolution in 6H-SiC by H$_{2}^{ + }$ implantation[J]. 中国物理B, 2021, 30(5): 56106-056106.
[13]	Zhe Wang(王喆) and Wenguang Zhu(朱文光). Metal substrates-induced phase transformation of monolayer transition metal dichalcogenides for hydrogen evolution catalysis[J]. 中国物理B, 2021, 30(11): 116401-116401.
[14]	董健生, 欧阳钢. Thickness-dependent structural stability and transition in molybdenum disulfide under hydrostatic pressure[J]. 中国物理B, 2020, 29(8): 86403-086403.
[15]	徐梦姣, 李素霞, 季辰辰, 雒晚霞, 王鲁香. Energy transfer, luminescence properties, and thermal stability of color tunable barium pyrophosphate phosphors[J]. 中国物理B, 2020, 29(6): 63301-063301.