Energy transfer relation of a novel Ce3+/Pr3+/Eu3+ co-doped Sr2.975-xLaxAlO4+xF1-x solid solution phosphor

doi:10.1088/1674-1056/23/10/107805

›› 2014, Vol. 23 ›› Issue (10): 107805-107805.doi: 10.1088/1674-1056/23/10/107805

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Energy transfer relation of a novel Ce³⁺/Pr³⁺/Eu³⁺ co-doped Sr_2.975-xLa_xAlO_4+xF_1-x solid solution phosphor

王延泽, 马健, 孙亮, 李蕊, 王达健

Institute of Materials Physics, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China

收稿日期:2014-03-07 修回日期:2014-04-22 出版日期:2014-10-15 发布日期:2014-10-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 21076161 and 50872091).

Energy transfer relation of a novel Ce³⁺/Pr³⁺/Eu³⁺ co-doped Sr_2.975-xLa_xAlO_4+xF_1-x solid solution phosphor

Wang Yan-Ze (王延泽), Ma Jian (马健), Sun Liang (孙亮), Li Rui (李蕊), Wang Da-Jian (王达健)

Institute of Materials Physics, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China

Received:2014-03-07 Revised:2014-04-22 Online:2014-10-15 Published:2014-10-15
Contact: Wang Da-Jian E-mail:djwang@tjut.edu.cn
About author:78.55.-m
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 21076161 and 50872091).

摘要/Abstract

摘要： The photoluminescence properties and energy transfer of a new Ce³⁺/Pr³⁺/Eu³⁺ co-doped solid-solution composition of Sr_2.975-xLa_xAlO_4+xF_1-x (LSAF) phosphor are investigated. Upon doping Pr³⁺ into lattices of LSAF:Ce host, a shoulder emission peak is observed at about 620 nm, owing to the transition of ¹D₂→³H₄. Addition of Eu³⁺ to LSAF:Ce³⁺, Pr³⁺ phosphor results in a sharp emission peaked at 675 nm for the ⁵D₀→⁷F₃ transition and an increase of the intensity of red emission for Pr³⁺ with increasing Eu³⁺ concentration. The pathways of energy transfer among Ce³⁺, Pr³⁺, and Eu³⁺ are proposed to be responsible for color addition of a red component to the primary yellow emission, enabling a potential adjustable color for blue excitable warm white.

关键词: energy transfer, solid solution, red emission, phosphor

Abstract: The photoluminescence properties and energy transfer of a new Ce³⁺/Pr³⁺/Eu³⁺ co-doped solid-solution composition of Sr_2.975-xLa_xAlO_4+xF_1-x (LSAF) phosphor are investigated. Upon doping Pr³⁺ into lattices of LSAF:Ce host, a shoulder emission peak is observed at about 620 nm, owing to the transition of ¹D₂→³H₄. Addition of Eu³⁺ to LSAF:Ce³⁺, Pr³⁺ phosphor results in a sharp emission peaked at 675 nm for the ⁵D₀→⁷F₃ transition and an increase of the intensity of red emission for Pr³⁺ with increasing Eu³⁺ concentration. The pathways of energy transfer among Ce³⁺, Pr³⁺, and Eu³⁺ are proposed to be responsible for color addition of a red component to the primary yellow emission, enabling a potential adjustable color for blue excitable warm white.

Key words: energy transfer, solid solution, red emission, phosphor

中图分类号: (Photoluminescence, properties and materials)

78.55.-m

王延泽, 马健, 孙亮, 李蕊, 王达健. Energy transfer relation of a novel Ce³⁺/Pr³⁺/Eu³⁺ co-doped Sr_2.975-xLa_xAlO_4+xF_1-x solid solution phosphor[J]. , 2014, 23(10): 107805-107805.

Wang Yan-Ze (王延泽), Ma Jian (马健), Sun Liang (孙亮), Li Rui (李蕊), Wang Da-Jian (王达健). Energy transfer relation of a novel Ce³⁺/Pr³⁺/Eu³⁺ co-doped Sr_2.975-xLa_xAlO_4+xF_1-x solid solution phosphor[J]. Chin. Phys. B, 2014, 23(10): 107805-107805.

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Energy transfer relation of a novel Ce³⁺/Pr³⁺/Eu³⁺ co-doped Sr_2.975-xLa_xAlO_4+xF_1-x solid solution phosphor

Energy transfer relation of a novel Ce³⁺/Pr³⁺/Eu³⁺ co-doped Sr_2.975-xLa_xAlO_4+xF_1-x solid solution phosphor

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