Photoluminescence and persistent luminescence properties of non-doped and Ti4+-doped Mg2SnO4 phosphors

doi:10.1088/1674-1056/20/9/094211

中国物理B ›› 2011, Vol. 20 ›› Issue (9): 94211-094211.doi: 10.1088/1674-1056/20/9/094211

Photoluminescence and persistent luminescence properties of non-doped and Ti⁴⁺-doped Mg₂SnO₄ phosphors

张加驰, 秦青松, 于明汇, 周宏亮, 周美娇

Key Laboratory for Magnetism and Magnetic Materials, Ministry of Education, Lanzhou University, Lanzhou 730000, China

收稿日期:2011-03-02 修回日期:2011-04-30 出版日期:2011-09-15 发布日期:2011-09-15

Photoluminescence and persistent luminescence properties of non-doped and Ti⁴⁺-doped Mg₂SnO₄ phosphors

Zhang Jia-Chi(张加驰)^†, Qin Qing-Song(秦青松), Yu Ming-Hui(于明汇), Zhou Hong-Liang(周宏亮), and Zhou Mei-Jiao(周美娇)

Key Laboratory for Magnetism and Magnetic Materials, Ministry of Education, Lanzhou University, Lanzhou 730000, China

Received:2011-03-02 Revised:2011-04-30 Online:2011-09-15 Published:2011-09-15

摘要/Abstract

摘要： Mg₂SnO₄ exhibits green photoluminescence and persistent luminescence, which originate from oxygen vacancies. When Ti⁴⁺ ions were doped, an interesting Mg₂SnO₄:Ti⁴⁺ phosphor with bluish white photoluminescence under ultraviolet irradiation and with green persistent luminescence was first obtained. Our investigation reveals that two emission centres exist in Mg₂SnO₄:Ti⁴⁺. The centres responsible for the green emission are considered to be the F centres (oxygen vacancies) and the blue centres are the TiO₆ complex. Trap clusters in the band gap with different depths, such as [Sn_Mg^‥—O_i^″], [Sn_Mg^‥—V_O^·], [Sn_Mg^‥—V_O^×] and Mg_Sn^″, correspond to the components at 85 ℃, 146 ℃ and 213 ℃ of the thermoluminescence curve.

关键词: phosphor, Mg₂SnO₄, persistent luminescence, photoluminescence

Abstract: Mg₂SnO₄ exhibits green photoluminescence and persistent luminescence, which originate from oxygen vacancies. When Ti⁴⁺ions were doped, an interesting Mg₂SnO₄:Ti⁴⁺ phosphor with bluish white photoluminescence under ultraviolet irradiation and with green persistent luminescence was first obtained. Our investigation reveals that two emission centres exist in Mg₂SnO₄:Ti⁴⁺. The centres responsible for the green emission are considered to be the F centres (oxygen vacancies) and the blue centres are the TiO₆ complex. Trap clusters in the band gap with different depths, such as [Sn_Mg^‥—O_i^″], [Sn_Mg^‥—V_O^·], [Sn_Mg^‥—V_O^×] and Mg_Sn^″, correspond to the components at 85 ℃, 146 ℃ and 213 ℃ of the thermoluminescence curve.

Key words: phosphor, Mg₂SnO₄, persistent luminescence, photoluminescence

中图分类号: (Optical materials)

42.70.-a

张加驰, 秦青松, 于明汇, 周宏亮, 周美娇. Photoluminescence and persistent luminescence properties of non-doped and Ti⁴⁺-doped Mg₂SnO₄ phosphors[J]. 中国物理B, 2011, 20(9): 94211-094211.

Zhang Jia-Chi(张加驰), Qin Qing-Song(秦青松), Yu Ming-Hui(于明汇), Zhou Hong-Liang(周宏亮), and Zhou Mei-Jiao(周美娇) . Photoluminescence and persistent luminescence properties of non-doped and Ti⁴⁺-doped Mg₂SnO₄ phosphors[J]. Chin. Phys. B, 2011, 20(9): 94211-094211.

参考文献 23

[1]	Jiang Z Q, Wang Y H and Gong Y 2010 Chin. Phys. B 19 027801
[2]	Huang P, Cui C E and Wang S 2009 Chin. Phys. B 18 4524
[3]	Qiu J, Miura K, Inouye H, Fujiwara S, Mitsuyu T and Hirao K 1999 J. Non-Cryst. Solids 244 185
[4]	Matsuzawa T, Aoki Y, Takeuchi N and Murayama Y 1996 J. Electrochem. Soc. 143 2670
[5]	Lin Y, Tang Z, Zhang Z and Nan C 2003 J. Eur. Ceram. Soc. 23 175
[6]	Wang M, Wang D and Lu G 1998 Mater. Sci. Eng. B 57 18
[7]	Chen Y C, Chang Y H and Tsai B S 2004 Mater. Trans. 45 1684
[8]	Kim K N, Jung H K, Park H D and Kim D 2002 J. Lumin. 99 169
[9]	Popp R C 1991 Luminescence and the Solid State (Amsterdam: Elsevier) p. 291
[10]	Goodnenough J B and Loeb A L 1955 Phys. Rev. 98 39
[11]	Verwey E J W and Heilmann E L 1947 J. Chem. Phys. 15 174
[12]	Schweizer S 2001 Phys. Status. Solidi. A 187 335
[13]	Hölsä J, Jungner H, Lastusaari M and Niittykoski J 2001 J. Alloys. Compd. 323 326
[14]	Trojan-Piegza J, Niittykoski J, Hölsä J and Zych E 2008 Chem. Mater. 20 2252
[15]	Macke A J H and Blasse G 1976 J. Inorg. Nucl. Chem. 38 1407
[16]	Yan H, He R, Pham J and Yang P 2003 Adv. Mater. 15 402
[17]	Hu J Q, Bando Y and Golberg D 2003 Chem. Phys. Lett. 372 758
[18]	Li Y B, Bando Y, Sato T and Kurashima K 2002 Appl. Phys. Lett. 81 144
[19]	Emeline A V, Kataeva G V, Ryabchuk V K and Serpone N 1999 J. Phys. Chem. B 103 9190
[20]	Mitchell T E 1999 J. Am. Ceram. Soc. 12 3305
[21]	Jia D and Yen W M 2003 J. Lumin. 101 115
[22]	Zhang J C, Wang Y H, Zhang Z Y, Wang Z L and Liu B 2008 Mater. Lett. 62 202
[23]	Yamashita T and Ueda K 2007 J. Solid State Chem. 180 1410

Photoluminescence and persistent luminescence properties of non-doped and Ti⁴⁺-doped Mg₂SnO₄ phosphors

Photoluminescence and persistent luminescence properties of non-doped and Ti⁴⁺-doped Mg₂SnO₄ phosphors

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