中国物理B ›› 2010, Vol. 19 ›› Issue (1): 17702-017702.doi: 10.1088/1674-1056/19/1/017702

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Temperature-frequency dependence and mechanism of dielectric properties for γ-Y2Si2O7

袁杰1, 曹茂盛2, 宋维力2, 侯志灵3   

  1. (1)School of Information Engineering, Central University for Nationalities, Beijing 100081, China; (2)School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China; (3)School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;School of Science, Beijing University of Chemical Technology, Beijing 100029, China
  • 收稿日期:2008-12-31 修回日期:2009-06-05 出版日期:2010-01-15 发布日期:2010-01-15
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant No. 50872159) and the National Defense Pre-research Foundation of China (Grant Nos. 513180303 and A2220061080).

Temperature-frequency dependence and mechanism of dielectric properties for $\gamma$-Y2Si2O7

Hou Zhi-Ling(侯志灵)a)b), Cao Mao-Sheng(曹茂盛) a)†, Yuan Jie(袁杰)c)‡, and Song Wei-Li(宋维力)a)   

  1. a School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China; b School of Science, Beijing University of Chemical Technology, Beijing 100029, China; c School of Information Engineering, Central University for Nationalities, Beijing 100081, China 
  • Received:2008-12-31 Revised:2009-06-05 Online:2010-01-15 Published:2010-01-15
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No. 50872159) and the National Defense Pre-research Foundation of China (Grant Nos. 513180303 and A2220061080).

摘要: This paper reports that single-phase γ -Y2Si2O7 is prepared via a sufficient blending and cold-pressed sintering technique from Y2O3 powder and SiO2 nanopowder. It studies the dielectric properties of γ -Y2Si2O7 as a function of the temperature and frequency. The γ -Y2Si2O7 exhibits low dielectric loss and non-Debye relaxation behaviour from 25 to 1400~℃C in the range of 7.3--18~GHz. The mechanism for polarization relaxation of the as-prepared γ -Y2Si2O7 differing from that of SiO2 is explained. Such particular dielectric properties could potentially make specific attraction for extensive practical applications.

Abstract: This paper reports that single-phase $\gamma$ -Y2Si2O7 is prepared via a sufficient blending and cold-pressed sintering technique from Y2O3 powder and SiO2 nanopowder. It studies the dielectric properties of $\gamma$ -Y2Si2O7 as a function of the temperature and frequency. The $\gamma$ -Y2Si2O7 exhibits low dielectric loss and non-Debye relaxation behaviour from 25 to 1400 ℃ in the range of 7.3--18 GHz. The mechanism for polarization relaxation of the as-prepared $\gamma$ -Y2Si2O7 differing from that of SiO2 is explained. Such particular dielectric properties could potentially make specific attraction for extensive practical applications.

Key words: $\gamma$-Y2Si2O7, dielectric properties, structural relaxation polarization, low dielectric loss

中图分类号:  (Dielectric loss and relaxation)

  • 77.22.Gm
77.22.Ej (Polarization and depolarization) 81.20.Fw (Sol-gel processing, precipitation)