中国物理B ›› 2018, Vol. 27 ›› Issue (5): 57702-057702.doi: 10.1088/1674-1056/27/5/057702

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇    下一篇

Effect of oxygen content on dielectric characteristics of Cr-doped LaTiOx

Ming Ma(马铭), Yan Chen(陈彦), Yi-Min Cui(崔益民)   

  1. 1 School of Aeronautic Science and Engineering, Beihang University, Beijing 100191, China;
    2 School of Physics, Beihang University, Beijing 100191, China
  • 收稿日期:2017-12-16 修回日期:2018-01-17 出版日期:2018-05-05 发布日期:2018-05-05
  • 通讯作者: Yan Chen E-mail:chenyan@buaa.edu.cn
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant No.51571006).

Effect of oxygen content on dielectric characteristics of Cr-doped LaTiOx

Ming Ma(马铭)1, Yan Chen(陈彦)2, Yi-Min Cui(崔益民)2   

  1. 1 School of Aeronautic Science and Engineering, Beihang University, Beijing 100191, China;
    2 School of Physics, Beihang University, Beijing 100191, China
  • Received:2017-12-16 Revised:2018-01-17 Online:2018-05-05 Published:2018-05-05
  • Contact: Yan Chen E-mail:chenyan@buaa.edu.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No.51571006).

摘要: The ceramics La0.85Cr0.15TiOx and La0.7Cr0.3TiOx are prepared by conventional solid-state reaction method. The dielectric properties of Cr-doped LaTiOx as a function of frequency (0.1 kHz ≤ f ≤ 1 MHz) and temperature (77 K ≤ T ≤ 360 K) are studied. The blocks are then annealed in a flowing O2 or Ar/H2 to convert their oxygen content and the tests mentioned above are performed. The highly oxygenated samples exhibit extremely high low-frequency dielectric constants at room temperature (~106). The results show that the oxygen stoichiometry could significantly influence the dielectric properties of Cr-doped LaTiOx.

关键词: oxygen content, dielectric characteristics, LaTiOx

Abstract: The ceramics La0.85Cr0.15TiOx and La0.7Cr0.3TiOx are prepared by conventional solid-state reaction method. The dielectric properties of Cr-doped LaTiOx as a function of frequency (0.1 kHz ≤ f ≤ 1 MHz) and temperature (77 K ≤ T ≤ 360 K) are studied. The blocks are then annealed in a flowing O2 or Ar/H2 to convert their oxygen content and the tests mentioned above are performed. The highly oxygenated samples exhibit extremely high low-frequency dielectric constants at room temperature (~106). The results show that the oxygen stoichiometry could significantly influence the dielectric properties of Cr-doped LaTiOx.

Key words: oxygen content, dielectric characteristics, LaTiOx

中图分类号:  (Elements, oxides, nitrides, borides, carbides, chalcogenides, etc.)

  • 77.84.Bw
77.22.Gm (Dielectric loss and relaxation) 61.72.-y (Defects and impurities in crystals; microstructure)