Measurement scheme to detect α relaxation time of glass-forming liquid

doi:10.1088/1674-1056/28/8/086601

中国物理B ›› 2019, Vol. 28 ›› Issue (8): 86601-086601.doi: 10.1088/1674-1056/28/8/086601

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Measurement scheme to detect α relaxation time of glass-forming liquid

Xing-Yu Zhao(赵兴宇), Li-Na Wang(王丽娜), Hong-Mei Yin(尹红梅), Heng-Wei Zhou(周恒为), Yi-Neng Huang(黄以能)

1 National Laboratory of Solid State Microstructures, School of Physics, Nanjing University, Nanjing 210093, China;
2 Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining 835000, China

收稿日期:2019-04-25 修回日期:2019-05-18 出版日期:2019-08-05 发布日期:2019-08-05
通讯作者: Yi-Neng Huang E-mail:ynhuang@nju.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 11664042).

Measurement scheme to detect α relaxation time of glass-forming liquid

Xing-Yu Zhao(赵兴宇)^1,2, Li-Na Wang(王丽娜)^1,2, Hong-Mei Yin(尹红梅)^1,2, Heng-Wei Zhou(周恒为)², Yi-Neng Huang(黄以能)^1,2

1 National Laboratory of Solid State Microstructures, School of Physics, Nanjing University, Nanjing 210093, China;
2 Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining 835000, China

Received:2019-04-25 Revised:2019-05-18 Online:2019-08-05 Published:2019-08-05
Contact: Yi-Neng Huang E-mail:ynhuang@nju.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 11664042).

摘要/Abstract

摘要： A measurement scheme for detecting the α relaxation time (τ) of glass-forming liquid is proposed, which is based on the measured ionic conductivity of the liquid doped with probing ions by low- and middle-frequency dielectric spectroscopy and according to the Nernst-Einstein, Stokes-Einstein, and Maxwell equations. The obtained τ values of glycerol and propylene carbonate by the scheme are consistent with those obtained by traditional dielectric spectroscopy, which confirms its reliability and accuracy. Moreover, the τ of 1,2-propanediol in a larger temperature range is compared with existing data.

关键词: α relaxation, ionic conductivity, glass-forming liquid, dielectric spectroscopy

Abstract: A measurement scheme for detecting the α relaxation time (τ) of glass-forming liquid is proposed, which is based on the measured ionic conductivity of the liquid doped with probing ions by low- and middle-frequency dielectric spectroscopy and according to the Nernst-Einstein, Stokes-Einstein, and Maxwell equations. The obtained τ values of glycerol and propylene carbonate by the scheme are consistent with those obtained by traditional dielectric spectroscopy, which confirms its reliability and accuracy. Moreover, the τ of 1,2-propanediol in a larger temperature range is compared with existing data.

Key words: α relaxation, ionic conductivity, glass-forming liquid, dielectric spectroscopy

中图分类号: (Diffusion and ionic conduction in liquids)

66.10.-x

77.22.Gm (Dielectric loss and relaxation) 64.70.P- (Glass transitions of specific systems) 82.56.Na (Relaxation)

赵兴宇, 王丽娜, 尹红梅, 周恒为, 黄以能. Measurement scheme to detect α relaxation time of glass-forming liquid[J]. 中国物理B, 2019, 28(8): 86601-086601.

Xing-Yu Zhao(赵兴宇), Li-Na Wang(王丽娜), Hong-Mei Yin(尹红梅), Heng-Wei Zhou(周恒为), Yi-Neng Huang(黄以能). Measurement scheme to detect α relaxation time of glass-forming liquid[J]. Chin. Phys. B, 2019, 28(8): 86601-086601.

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Measurement scheme to detect α relaxation time of glass-forming liquid

Measurement scheme to detect α relaxation time of glass-forming liquid

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