中国物理B ›› 2004, Vol. 13 ›› Issue (1): 82-84.doi: 10.1088/1009-1963/13/1/015

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Effect of nonstoichiometry on Raman scattering of VO2 films

冯克成1, 李超1, 袁宏韬2, 王学进3, 何琛娟3, 聂玉昕3   

  1. (1)Changchun University of Science and Technology, Changchun 130022, China; (2)Changchun University of Science and Technology, Changchun 130022, China; Institute of Physics ,Chinese Academy of Sciences, Beijing 100080, China; (3)Institute of Physics ,Chinese Academy of Sciences, Beijing 100080, China
  • 收稿日期:2003-06-04 修回日期:2003-09-11 出版日期:2004-01-22 发布日期:2007-03-22
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant No 50072045), and the Foundation of Center for Condensed Matter Physics.

Effect of nonstoichiometry on Raman scattering of VO2 films

Yuan Hong-Tao (袁宏韬)ab, Feng Ke-Cheng (冯克成)a, Wang Xue-Jin (王学进)b, Li Chao (李超)a, He Chen-Juan (何琛娟)b, Nie Yu-Xin (聂玉昕)b   

  1. a Changchun University of Science and Technology, Changchun 130022, China; b Institute of Physics ,Chinese Academy of Sciences, Beijing 100080, China
  • Received:2003-06-04 Revised:2003-09-11 Online:2004-01-22 Published:2007-03-22
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No 50072045), and the Foundation of Center for Condensed Matter Physics.

摘要: We report on Raman scattering of VO_2 films prepared by radio frequency magnetron sputtering under different conditions. Our investigations revealed that the dominated Raman peaks shift towards high frequency for both V-rich and O-rich VO_2 films, compared with the stoichiometry VO_2 films. The experimental evidence is presented and the cause for nonstoichiometry dependence of Raman spectra of VO_2 films is discussed.

关键词: vanadium dioxide thin films, Raman spectra, nonstoichiometry, RF magnetron sputtering

Abstract: We report on Raman scattering of VO$_2$ films prepared by radio frequency magnetron sputtering under different conditions. Our investigations revealed that the dominated Raman peaks shift towards high frequency for both V-rich and O-rich VO$_2$ films, compared with the stoichiometry VO$_2$ films. The experimental evidence is presented and the cause for nonstoichiometry dependence of Raman spectra of VO$_2$ films is discussed.

Key words: vanadium dioxide thin films, Raman spectra, nonstoichiometry, RF magnetron sputtering

中图分类号:  (Other semiconductors)

  • 78.66.Li
78.30.Hv (Other nonmetallic inorganics) 68.55.Nq (Composition and phase identification)