中国物理B ›› 2002, Vol. 11 ›› Issue (3): 272-276.doi: 10.1088/1009-1963/11/3/314

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Phase transition and pitting corrosion behaviour for Mo-implanted aluminium

刘培英1, 张通和2, 吴瑜光2, 钱卫东2   

  1. (1)Department of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics; (2)Key Laboratory in University for Radiation Beam Technology and Material Modification, Institute of Low Energy Nuclear Physics, Beijing Normal University, Beijing 100875, China
  • 收稿日期:2001-06-29 修回日期:2001-10-17 出版日期:2002-03-13 发布日期:2005-06-13
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant Nos 59671051 and 59871003), and by the National High Technology Development Programme of China (Grant No 863-715-023-02-01).

Phase transition and pitting corrosion behaviour for Mo-implanted aluminium

 Zhang Tong-He (张通和)a, Wu Yu-Guang (吴瑜光)a, Liu Pei-Ying (刘培英)b, Qian Wei-Dong (钱卫东)a   

  1. a Key Laboratory in University for Radiation Beam Technology and Material Modification, Institute of Low Energy Nuclear Physics, Beijing Normal University, Beijing 100875, China; b Department of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics
  • Received:2001-06-29 Revised:2001-10-17 Online:2002-03-13 Published:2005-06-13
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant Nos 59671051 and 59871003), and by the National High Technology Development Programme of China (Grant No 863-715-023-02-01).

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摘要： Molybdenum ions are implanted into aluminium with high ion flux and high dose at elevated temperatures of 200℃, 400℃ and 500℃. Due to the high temperature and high flux of vacancies and interstitial atoms, the atom diffusion and chemical effects are enhanced during the ion implantation. The effects increase with increasing ion flux and dose, so that new phase formation and phase transition emerge noticeably. X-ray diffraction analysis shows that when the aluminium is implanted with Mo ions at a low ion flux (25μA/cm2), the Al5Mo alloy is formed. The atomic ratio of Mo/Al of the Al5Mo phase is close to 20%. When the aluminium is implanted with Mo ions at a high ion flux (50μA/cm2), the phase transition from Al5Mo to Al12Mo appears, and the latter is dominant, which is determined to be the final phase. The ratio of Mo/Al in Al12Mo is 7.7%. Rutherford backscattering spectroscopy indicates also that the Mo/Al atom ratio is ～7% to ～8% in Mo-implanted aluminium. The atomic ratios of the constituents in Al5Mo and Al12Mo are of stoichiometric composition for these alloys. The thicknesses of the Al12Mo alloy layers for Mo-implanted Al with ion doses of 3×1017/cm2 and 1×1018/cm2 are 550nm and 2000nm, respectively. The pitting corrosion potential Vp increases obviously. It is clear that due to the formation of Al12Mo alloy layer, the pitting corrosion resistance is enhanced.

Abstract: Molybdenum ions are implanted into aluminium with high ion flux and high dose at elevated temperatures of 200℃, 400℃ and 500℃. Due to the high temperature and high flux of vacancies and interstitial atoms, the atom diffusion and chemical effects are enhanced during the ion implantation. The effects increase with increasing ion flux and dose, so that new phase formation and phase transition emerge noticeably. X-ray diffraction analysis shows that when the aluminium is implanted with Mo ions at a low ion flux (25μA/cm2), the Al5Mo alloy is formed. The atomic ratio of Mo/Al of the Al5Mo phase is close to 20%. When the aluminium is implanted with Mo ions at a high ion flux (50μA/cm2), the phase transition from Al5Mo to Al12Mo appears, and the latter is dominant, which is determined to be the final phase. The ratio of Mo/Al in Al12Mo is 7.7%. Rutherford backscattering spectroscopy indicates also that the Mo/Al atom ratio is ～7% to ～8% in Mo-implanted aluminium. The atomic ratios of the constituents in Al5Mo and Al12Mo are of stoichiometric composition for these alloys. The thicknesses of the Al12Mo alloy layers for Mo-implanted Al with ion doses of 3×1017/cm2 and 1×1018/cm2 are 550nm and 2000nm, respectively. The pitting corrosion potential Vp increases obviously. It is clear that due to the formation of Al12Mo alloy layer, the pitting corrosion resistance is enhanced.

Key words: Mo-implanted Al, MoAl alloy, phase transition, pitting corrosion resistance

中图分类号:  (Other materials)

  • 61.72.up
66.30.-h (Diffusion in solids) 64.60.-i (General studies of phase transitions) 82.80.Yc (Rutherford backscattering (RBS), and other methods ofchemical analysis) 61.50.Nw (Crystal stoichiometry)