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Growth temperature dependent evolutions of microstructural, optical and magnetic properties of Zn0.75Co0.25O films
邱东江, 冯春木, 冯爱明, 吴惠桢
2008 (2):
690-696.
doi: 10.1088/1674-1056/17/2/055
摘要
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Zn0.75Co0.25O films are fabricated via reactive electron
beam evaporation. The influence of growth temperature on the
microstructural, optical and magnetic properties of
Zn0.75Co0.25O films is investigated by using x-ray
diffraction, selected area electron diffraction, field emission
scanning electron microscope, high resolution transmitting electron
microscope, photoluminescence (PL), field dependent and temperature
dependent DC magnetization, and x-ray photoelectron spectroscopy
(XPS). It is shown that Zn0.75Co0.25OO films grown at low
temperatures (250--350\du) are of single-phase wurtzite structure.
Films synthesized at 300 or 350\du\ reveal room temperature (RT)
ferromagnetism (FM), while superparamagnetism for 250\du\ fabricated
films is found above 56K. PL and XPS investigations show favour
towards the perspective that the O-vacancy induced spin-split
impurity band mechanism is responsible for the formation of RT FM of
Zn0.75Co0.25O film, while the superparamagnetism of
250\du\ fabricated film is attributed to the small size effect of
nanoparticles in Zn0.75Co0.25O film.
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