中国物理B ›› 2025, Vol. 34 ›› Issue (6): 67304-067304.doi: 10.1088/1674-1056/adc660

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Low leakage current β-Ga2O3 MOS capacitors with ALD deposited Al2O3 gate dielectric using ozone as precursor

Zheng-Yi Liao(廖正一)1, Pai-Wen Fang(方湃文)1, Xing Lu(卢星)1,†, Gang Wang(王钢)1, and Yan-Li Pei(裴艳丽)1,2,‡   

  1. 1 State Key Laboratory of Optoelectronic Materials and Technologies, School of Electronics and Information Technology, Sun Yat-Sen University, Guangzhou 510006, China;
    2 Foshan Institute of Sun Yat-Sen University, Foshan 528225, China
  • 收稿日期:2025-01-15 修回日期:2025-03-25 接受日期:2025-03-28 出版日期:2025-05-16 发布日期:2025-05-30
  • 通讯作者: Xing Lu, Yan-Li Pei E-mail:lux86@mail.sysu.edu.cn;peiyanli@mail.sysu.edu.cn
  • 基金资助:
    Project supported in part by the Science and Technology Development Plan Project of Jilin Province, China (Grant No. YDZJ202303CGZH022), the National Key Research and Development Program of China (Grant No. 2024YFE0205300), the National Natural Science Foundation of China (Grant No. 62471504), and the Open Fund of the State Key Laboratory of Optoelectronic Materials and Technologies (Sun Yat-Sen University) (Grant No. OEMT-2023- KF-05).

Low leakage current β-Ga2O3 MOS capacitors with ALD deposited Al2O3 gate dielectric using ozone as precursor

Zheng-Yi Liao(廖正一)1, Pai-Wen Fang(方湃文)1, Xing Lu(卢星)1,†, Gang Wang(王钢)1, and Yan-Li Pei(裴艳丽)1,2,‡   

  1. 1 State Key Laboratory of Optoelectronic Materials and Technologies, School of Electronics and Information Technology, Sun Yat-Sen University, Guangzhou 510006, China;
    2 Foshan Institute of Sun Yat-Sen University, Foshan 528225, China
  • Received:2025-01-15 Revised:2025-03-25 Accepted:2025-03-28 Online:2025-05-16 Published:2025-05-30
  • Contact: Xing Lu, Yan-Li Pei E-mail:lux86@mail.sysu.edu.cn;peiyanli@mail.sysu.edu.cn
  • Supported by:
    Project supported in part by the Science and Technology Development Plan Project of Jilin Province, China (Grant No. YDZJ202303CGZH022), the National Key Research and Development Program of China (Grant No. 2024YFE0205300), the National Natural Science Foundation of China (Grant No. 62471504), and the Open Fund of the State Key Laboratory of Optoelectronic Materials and Technologies (Sun Yat-Sen University) (Grant No. OEMT-2023- KF-05).

摘要: Metal-insulator-semiconductor (MOS) capacitor is a key structure for high performance MOS field transistors (MOSFETs), requiring low leakage current, high breakdown voltage, and low interface states. In this paper, $\beta $-Ga$_{2}$O$_{3}$ MOS capacitors were fabricated with ALD deposited Al$_{2}$O$_{3}$ using H$_{2}$O or ozone (O$_{3}$) as precursors. Compared with the Al$_{2}$O$_{3}$ gate dielectric with H$_{2}$O as ALD precursor, the leakage current for the O$_{3}$ precursor case is decreased by two orders of magnitude, while it keeps the same level at the fixed charges, interface state density, and border traps. The SIMS tests show that Al$_{2}$O$_{3}$ with O$_{3}$ as precursor contains more carbon impurities. The current transport mechanism analysis suggests that the C-H complex in Al$_{2}$O$_{3}$ with O$_{3}$ precursor serves as deep energy trap to reduce the leakage current. These results indicate that the Al$_{2}$O$_{3}/\beta $-Ga$_{2}$O$_{3}$ MOS capacitor using the O$_{3}$ precursor has a low leakage current and holds potential for application in $\beta $-Ga$_{2}$O$_{3}$ MOSFETs.

关键词: MOS capacitor, $\beta $-Ga$_{2}$O$_{3}$, ozone precursor, ALD Al$_{2}$O$_{3}$

Abstract: Metal-insulator-semiconductor (MOS) capacitor is a key structure for high performance MOS field transistors (MOSFETs), requiring low leakage current, high breakdown voltage, and low interface states. In this paper, $\beta $-Ga$_{2}$O$_{3}$ MOS capacitors were fabricated with ALD deposited Al$_{2}$O$_{3}$ using H$_{2}$O or ozone (O$_{3}$) as precursors. Compared with the Al$_{2}$O$_{3}$ gate dielectric with H$_{2}$O as ALD precursor, the leakage current for the O$_{3}$ precursor case is decreased by two orders of magnitude, while it keeps the same level at the fixed charges, interface state density, and border traps. The SIMS tests show that Al$_{2}$O$_{3}$ with O$_{3}$ as precursor contains more carbon impurities. The current transport mechanism analysis suggests that the C-H complex in Al$_{2}$O$_{3}$ with O$_{3}$ precursor serves as deep energy trap to reduce the leakage current. These results indicate that the Al$_{2}$O$_{3}/\beta $-Ga$_{2}$O$_{3}$ MOS capacitor using the O$_{3}$ precursor has a low leakage current and holds potential for application in $\beta $-Ga$_{2}$O$_{3}$ MOSFETs.

Key words: MOS capacitor, $\beta $-Ga$_{2}$O$_{3}$, ozone precursor, ALD Al$_{2}$O$_{3}$

中图分类号:  (Metal-insulator-semiconductor structures (including semiconductor-to-insulator))

  • 73.40.Qv
71.20.Nr (Semiconductor compounds) 81.15.-z (Methods of deposition of films and coatings; film growth and epitaxy)